Strontium isotope compositions of river waters as records of lithology-dependent mass transfers : the Garonne river and its tributaries (SW France)

The relation of lithology in the drainage basin to the dissolved load of the Garonne river and its main tributaries, in southwestern France, was evaluated by determining 87Sr/86Sr ratios, and concentrations of major and trace elements during a 2-year-long survey. In the upper drainage basin, the Garonne river waters were isotopically varied at two observation points: 0.71131+/−0.00030 (2σ) for 84+/−18 ppb (2σ) and 0.71272+/−0.00044 for 86+/−10 ppb, respectively. In the lower drainage basin, the Garonne river waters were isotopically identical at three observation points at 0.71020+/−0.00024 for 125+/−22 ppb. By contrast, the tributaries (Lot, Truyère, Aveyron, Arriège, Gers and Salat) are widely varied in their 87Sr/86Sr ratios and Sr concentrations from 0.70836+/−0.00049 to 0.71058+/−0.00057, and from 18+/−8 to 280+/−116 ppb. The Sr isotope ratios and concentrations suggest a dominant supply of two reservoirs of Sr, one of which is with low 87Sr/86Sr ratios and high Sr contents that is typically characteristic of carbonate rocks, and the other with high 87Sr/86Sr ratios and low Sr concentrations that is characteristic of felsic rocks. Locally as in the Lot waters draining the Massif Central and within the Pyrénées mountains, a third source of Sr from mafic rocks may be involved. Mass-balance calculations based on the mean 87Sr/86Sr ratios and contents of the dissolved Sr, and on the mean discharges integrating the 2-year survey, suggest that contribution of the silicate reservoir amounts 3–8% of the total dissolved Sr flux. Mass-balance calculations also suggest that variation in the supply of Sr from either of the two major reservoirs does not exceed the analytical uncertainty at about +/−5%. The 87Sr/86Sr ratios of HCl and NH4Cl leachates of suspended loads of the Garonne river are different from that of the associated dissolved Sr. This leaching-related supplementary Sr represents less than 10% of the total amount of Sr transported by the Garonne waters. The Sr isotope characteristics of the leachates are probably records of an intermediate pedogenic episode in the weathering-erosion process occurring in the Garonne drainage basin

The role of grain size and shape in the strengthening of dispersion hardened nickel alloys

Thermomechanical processing was used to develop various microsstructures in Ni, Ni-2ThO2, Ni-20Cr, Ni-20CR-2ThO2, Ni-20Cr-10W-and Ni-20Cr-10W-2ThO2. The yield strength at 25 C increased with substructure refinement according to the Hall-Petch relation, and substructure refinement was a much more potent means of strengthening than was dispersion hardening. At elevated temperature (1093 C), the most important microstructural feature affecting strength was the grain aspect ratio (grain length, L, divided by grain width, 1. The yield strength and creep strength increased linearly with increasing L/1

High temperature deformation of dispersion strengthened nickel alloys. 1 - The influence of initial structure on tensile and creep deformation of TD nickel. 2 - The effect of matrix stacking fault energy on creep of Ni-Cr-ThO2 alloys Final report, 9 Feb. 1967 - 9 Feb. 1968

High temperature creep studies on unaltered, and recrystallized nickel alloy

Dynamics-A explorer RIMS data analysis

Activities of the RIMS instrument during the extended mission are planned. The modes of operation for RIMS to achieve the science requirements utilizing the new and exciting information on the composition and dynamics of the low energy (0-50eV) ions in the Earth's ionosphere and magnetosphere are determined. The specific science problems and the required RIMS operational modes needed to acquire the desired data are identified. The analysis was performed on the RIMS data to achieve the science results and this new information was used in determining RIMS operations during the latter part of the mission. Necessary sensitivity tests of RIMS operating modes and instrument performance was suggested. The inflight results was compared with theoretical models

Impact of nitrogen fertilizers on the natural weathering-erosion processes and fluvial transport in the Garonne basin

Knowledge of the impact of N-fertilizers on the weathering-erosion processes of soils in intensively cultivated regions is of prime importance. Nitrification of NH4− fertilizers produces HNO3 in the basin of the Garonne river, enhancing soil degradation. Their influence on the weathering rates was determined by calculating the consumption rate of atmospheric/soil CO2 by soil weathering and erosion, and its contribution to the total dissolved riverine HCO3−. This contribution was found to be less than 50% which corresponds normally to a complete carbonate dissolution by carbonic acid, suggesting that part of the alkalinity in the river waters is due to carbonate dissolution by an acid other than carbonic acid, probably HNO3

A statistical study of magnetic dipolarization for sawtooth events and isolated substorms at geosynchronous orbit with GOES data

We investigate whether the dipolarization process during sawtooth events is global or not through an examination of the local time distribution of the magnetic tilt angle (i.e. the angle between the <i><b>B</b></i> vector and the equatorial plane in dipole <i>VDH</i> coordinates) at geostationary orbit. From the statistical analysis of 207 individual teeth and 212 isolated substorms, we find that individual teeth follow a dipolarization pattern similar to that observed for isolated substorms. The dipolarization for individual teeth initiates in the sector between 22:00 magnetic local time (MLT) and 00:00 MLT. Then the dipolarization expands both eastward and westward. However, relative to isolated substorms, we find that the nightside magnetosphere is much more stretched prior to the onset, and the change of the tilt angle during the dipolarization process is much larger during individual teeth. The magnetic dipolarization is seen over a wider local time sector during individual teeth than during isolated substorms. However, the magnetic dipolarization is rarely observed near local noon during individual teeth. This suggests that the magnetic dipolarization process during individual teeth is still confined primarily to the nightside

Chemical and mineralogical effects of saline water movement through a soil during evaporation

Cet article illustre les résultats d'une expérience menée dans le but d'étudier les effets de l'évaporation dans un sol homogène reconstitué. Les conditions expérimentales sont celles qui caractérisent les zones de polders du lac Tchad. Les données obtenues montrent que les phénomènes de capillarité déterminent un transfert des ions en solution vers la surface du sol. Puisque l'évaporation se réalise dans cette zone, les concentrations ioniques des solutions deviennent très élevées. Les simulations et les calculs théoriques montrent que dans ce milieu et sous ces conditions des argiles magnésiennes précipitent : ceci est confirmé par leurs observations au microscope électronique à transmissio

Development in laser peening of advanced ceramic

Laser peening is a well-known process applicable to surface treat metals and alloys in various industrial sectors. Research in the area of laser peening of ceramics is still scarce and a complete laser-ceramic interaction is still unreported. This paper focuses on laser peening of SiC ceramics employed for cutting tools, armor plating, dental and biomedical implants, with a view to elucidate the unreported work. A detailed investigation was conducted with 1064nm Nd:YAG ns pulse laser to first understand the surface effects, namely: the topography, hardness, KIc and the microstructure of SiC advanced ceramics. The results showed changes in surface roughness and microstructural modification after laser peening. An increase in surface hardness was found by almost 2 folds, as the diamond footprints and its flaws sizes were considerably reduced, thus, enhancing the resistance of SiC to better withstand mechanical impact. This inherently led to an enhancement in the KIc by about 42%. This is attributed to an induction of compressive residual stress and phase transformation. This work is a first-step towards the development of a 3-dimensional laser peening technique to surface treat many advanced ceramic components. This work has shown that upon tailoring the laser peening parameters may directly control ceramic topography, microstructure, hardness and the KIc. This is useful for increasing the performance of ceramics used for demanding applications particularly where it matters such as in military. Upon successful peening of bullet proof vests could result to higher ballistic strength and resistance against higher sonic velocity, which would not only prevent serious injuries, but could also help to save lives of soldiers on the battle fields