Frictional behavior of talc-calcite mixtures

Faults involving phyllosilicates appear weak when compared to the laboratory-derived strength of most crustal rocks. Among phyllosilicates, talc, with very low friction, is one of the weakest minerals involved in various tectonic settings. As the presence of talc has been recently documented in carbonate faults, we performed laboratory friction experiments to better constrain how various amounts of talc could alter these fault’s frictional properties. We used a biaxial apparatus to systematically shear different mixtures of talc and calcite as powdered gouge at room temperature, normal stresses up to 50 MPa and under different pore fluid saturated conditions, i.e., CaCO3-equilibrated water and silicone oil. We performed slide-hold-slide tests, 1–3000 s, to measure the amount of frictional healing and velocity-stepping tests, 0.1–1000 μm/s, to evaluate frictional stability. We then analyzed microstructures developed during our experiments. Our results show that with the addition of 20% talc the calcite gouge undergoes a 70% reduction in steady state frictional strength, a complete reduction of frictional healing and a transition from velocity-weakening to velocity-strengthening behavior. Microstructural analysis shows that with increasing talc content, deformation mechanisms evolve from distributed cataclastic flow of the granular calcite to localized sliding along talc-rich shear planes, resulting in a fully interconnected network of talc lamellae from 20% talc onward. Our observations indicate that in faults where talc and calcite are present, a low concentration of talc is enough to strongly modify the gouge’s frictional properties and specifically to weaken the fault, reduce its ability to sustain future stress drops, and stabilize slip

The role of fluid pressure in induced vs. triggered seismicity. Insights from rock deformation experiments on carbonates

Fluid overpressure is one of the primary mechanisms for tectonic fault slip, because fluids lubricate the fault and fluid pressure reduces the effective normal stress that holds the fault in place. However, current models of earthquake nucleation, based on rate- and state- friction laws, imply that stable sliding is favoured by the increase of pore fluid pressure. Despite this controversy, currently, there are only a few studies on the role of fluid pressure under controlled, laboratory conditions. Here, we use laboratory experiments, to show that the rate- and state- friction parameters do change with increasing fluid pressure. We tested carbonate gouges from sub hydrostatic to near lithostatic fluid pressure conditions, and show that the friction rate parameter (a−b) evolves from velocity strengthening to velocity neutral behaviour. Furthermore, the critical slip distance, Dc, decreases from about 90 to 10μm. Our data suggest that fluid overpressure plays an important role in controlling the mode of fault slip. Since fault rheology and fault stability parameters change with fluid pressure, we suggest that a comprehensive characterization of these parameters is fundamental for better assessing the role of fluid pressure in natural and human induced earthquakes

The influence of normal stress and sliding velocity on the frictional behaviour of calcite at room temperature. Insights from laboratory experiments and microstructural observations

The presence of calcite in and near faults, as the dominant material, cement, or vein fill, indicates that the mechanical behaviour of carbonate-dominated material likely plays an important role in shallow- and mid-crustal faulting. To better understand the behaviour of calcite, under loading conditions relevant to earthquake nucleation, we sheared powdered gouge of Carrara Marble, >98 per cent CaCO3, at constant normal stresses between 1 and 100 MPa under water-saturated conditions at room temperature. We performed slide-hold-slide tests, 1–3000 s, to measure the amount of static frictional strengthening and creep relaxation, and velocity-stepping tests, 0.1–1000 µm s–1, to evaluate frictional stability. We observe that the rates of frictional strengthening and creep relaxation decrease with increasing normal stress and diverge as shear velocity is increased from 1 to 3000 µm s–1 during slide-hold-slide experiments. We also observe complex frictional stability behaviour that depends on both normal stress and shearing velocity. At normal stresses less than 20 MPa, we observe predominantly velocity-neutral friction behaviour. Above 20 MPa, we observe strong velocity-strengthening frictional behaviour at low velocities, which then evolves towards velocity-weakening friction behaviour at high velocities. Microstructural analyses of recovered samples highlight a variety of deformation mechanisms including grain size reduction and localization, folding of calcite grains and fluid-assisted diffusion mass transfer processes promoting the development of calcite nanograins in the highly deformed portions of the experimental fault. Our combined analyses indicate that calcite fault gouge transitions from brittle to semi-brittle behaviour at high normal stress and slow sliding velocities. This transition has important implications for earthquake nucleation and propagation on faults in carbonate-dominated lithologies

On the evolution of elastic properties during laboratory stick-slip experiments spanning the transition from slow slip to dynamic rupture

The physical mechanisms governing slow earthquakes remain unknown, as does the relationship between slow and regular earthquakes. To investigate the mechanism(s) of slow earthquakes and related quasi-dynamic modes of fault slip we performed laboratory experiments on simulated fault gouge in the double direct shear configuration. We reproduced the full spectrum of slip behavior, from slow to fast stick slip, by altering the elastic stiffness of the loading apparatus (k) to match the critical rheologic stiffness of fault gouge (kc). Our experiments show an evolution from stable sliding, when k>kc, to quasi-dynamic transients when k ~ kc, to dynamic instabilities when k<kc. To evaluate the microphysical processes of fault weakening we monitored variations of elastic properties. We find systematic changes in P wave velocity (Vp) for laboratory seismic cycles. During the coseismic stress drop, seismic velocity drops abruptly, consistent with observations on natural faults. In the preparatory phase preceding failure, we find that accelerated fault creep causes a Vp reduction for the complete spectrum of slip behaviors. Our results suggest that the mechanics of slow and fast ruptures share key features and that they can occur on same faults, depending on frictional properties. In agreement with seismic surveys on tectonic faults our data show that their state of stress can be monitored by Vp changes during the seismic cycle. The observed reduction in Vp during the earthquake preparatory phase suggests that if similar mechanisms are confirmed in nature high-resolution monitoring of fault zone properties may be a promising avenue for reliable detection of earthquake precursors

Contrast-Enhanced Magnetic Resonance Angiography Using a Novel Elastin-Specific Molecular Probe in an Experimental Animal Model

Objectives. The aim of this study was to test the potential of a new elastin-specific molecular agent for the performance of contrast-enhanced first-pass and 3D magnetic resonance angiography (MRA), compared to a clinically used extravascular contrast agent (gadobutrol) and based on clinical MR sequences. Materials and Methods. Eight C57BL/6J mice (BL6, male, aged 10 weeks) underwent a contrast-enhanced first-pass and 3D MR angiography (MRA) of the aorta and its main branches. All examinations were on a clinical 3 Tesla MR system (Siemens Healthcare, Erlangen, Germany). The clinical dose of 0.1 mmol/kg was administered in both probes. First, a time-resolved MRA (TWIST) was acquired during the first-pass to assess the arrival and washout of the contrast agent bolus. Subsequently, a high-resolution 3D MRA sequence (3D T1 FLASH) was acquired. Signal-to-noise ratios (SNRs) and contrast-to-noise ratios (CNRs) were calculated for all sequences. Results. The elastin-specific MR probe and the extravascular imaging agent (gadobutrol) enable high-quality MR angiograms in all animals. During the first-pass, the probes demonstrated a comparable peak enhancement (300.6 +/- 32.9 vs. 288.5 +/- 33.1, p > 0.05). Following the bolus phase, both agents showed a comparable intravascular enhancement (SNR: 106.7 +/- 11 vs. 102.3 +/- 5.3; CNR 64.5 +/- 7.4 vs. 61.1 +/- 7.2, p > 0.05). Both agents resulted in a high image quality with no statistical difference (p > 0.05). Conclusion. The novel elastin-specific molecular probe enables the performance of first-pass and late 3D MR angiography with an intravascular contrast enhancement and image quality comparable to a clinically used extravascular contrast agent