Vibrational density of states of silicon nanoparticles

The vibrational density of states of silicon nanoparticles in the range from 2.3 to 10.3 nm is studied with the help of molecular-dynamics simulations. From these simulations the vibrational density of states and frequencies of bulk-like vibrational modes at high-symmetry points of the Brillouin-zone have been derived. The results show an increase of the density of states at low frequencies and a transfer of modes from the high-frequency end of the spectrum to the intermediate range. At the same time the peak of transverse optical modes is shifted to higher frequencies. These observations are in line with previous simulation studies of metallic nanoparticles and they provide an explanation for a previously observed discrepancy between experimental and theoretical data [C. Meier et al., Physica E, 32, 155 (2006)].Comment: 7 pages, 5 figure; accepted for publication in Phys. Rev.

Exact thermodynamic Casimir forces for an interacting three-dimensional model system in film geometry with free surfaces

The limit n to infinity of the classical O(n) phi^4 model on a 3d film with free surfaces is studied. Its exact solution involves a self-consistent 1d Schr\"odinger equation, which is solved numerically for a partially discretized as well as for a fully discrete lattice model. Numerically exact results are obtained for the scaled Casimir force at all temperatures. Obtained via a single framework, they exhibit all relevant qualitative features of the thermodynamic Casimir force known from wetting experiments on Helium-4 and Monte Carlo simulations, including a pronounced minimum below the bulk critical point.Comment: 5 pages, 2 figure

Breaking Boundaries: An Ethnographic Study of Women in Management

Women have succeeded in management positions for over a generation. These positions have conventionally been understood as male and thus difficult for women to be in. On the basis of a qualitative study this thesis investigates the everyday practices and positions of women in management. Material has been collected from ethnographic methods primarily based on participant observations and interviews. Drawing on findings with a cultural analysis perspective and using feminist Bourdieuian concepts of field and gender capital I examine how these women do management and whether they wield gender capital to maintain their careers. An intersectional perspective is also applied to understand how these women experience and do management. I argue gender capital may be a resource by which women develop and maintain their careers with, whilst also recognising the problem of gender labelling management. Thus in understanding these practices and positionings, the convention of understanding management, as male, does not account for the complexity and variation seen in this study. This study suggests that it is necessary to appreciate these complexities and variation in management, and gender capital offers an explanatory means for furthering understandings of management practices. This study also suggests femininity is gaining currency in the field of management. Further, actionable insights are provided into how these understandings of the women in management practices can be beneficial to gender and organisational change

Critical Casimir amplitudes for nn-component ϕ4\phi^4 models with O(n)-symmetry breaking quadratic boundary terms

Euclidean $n$-component $\phi^4$ theories whose Hamiltonians are O(n) symmetric except for quadratic symmetry breaking boundary terms are studied in films of thickness $L$. The boundary terms imply the Robin boundary conditions $\partial_n\phi_\alpha =\mathring{c}^{(j)}_\alpha \phi_\alpha$ at the boundary planes $\mathfrak{B}_{j=1,2}$ at $z=0$ and $z=L$. Particular attention is paid to the cases in which $m_j$ of the $n$ variables $\mathring{c}^{(j)}_\alpha$ take the special value $\mathring{c}_{m_j\text{-sp}}$ corresponding to critical enhancement while the remaining ones are subcritically enhanced. Under these conditions, the semi-infinite system bounded by $\mathfrak{B}_j$ has a multicritical point, called $m_j$-special, at which an $O(m_j)$ symmetric critical surface phase coexists with the O(n) symmetric bulk phase, provided $d$ is sufficiently large. The $L$-dependent part of the reduced free energy per area behaves as $\Delta_C/L^{d-1}$ as $L\to\infty$ at the bulk critical point. The Casimir amplitudes $\Delta_C$ are determined for small $\epsilon=4-d$ in the general case where $m_{c,c}$ components $\phi_\alpha$ are critically enhanced at both boundary planes, $m_{c,D} + m_{D,c}$ components are enhanced at one plane but satisfy asymptotic Dirichlet boundary conditions at the respective other, and the remaining $m_{D,D}$ components satisfy asymptotic Dirichlet boundary conditions at both $\mathfrak{B}_j$. Whenever $m_{c,c}>0$, these expansions involve integer and fractional powers $\epsilon^{k/2}$ with $k\ge 3$ (mod logarithms). Results to $O(\epsilon^{3/2})$ for general values of $m_{c,c}$, $m_{c,D}+m_{D,c}$, and $m_{D,D}$ are used to estimate the $\Delta_C$ of 3D Heisenberg systems with surface spin anisotropies when $(m_{c,c}, m_{c,D}+ m_{D,c}) = (1,0)$, $(0,1)$, and $(1,1)$.Comment: Latex source file with 5 eps files; version with minor amendments and corrected typo

O-GlcNAcase:promiscuous hexosaminidase or key regulator of O-GlcNAc signalling?

O-GlcNAc signaling is regulated by an opposing pair of enzymes: O-GlcNAc transferase installs and O-GlcNAcase (OGA) removes the modification from proteins. The dynamics and regulation of this process are only beginning to be understood as the physiological functions of both enzymes are being probed using genetic and pharmacological approaches. This minireview charts the discovery and functional and structural analysis of OGA and summarizes the insights gained from recent studies using OGA inhibition, gene knock-out, and overexpression. We identify several areas of “known unknowns” that would benefit from future research, such as the enigmatic C-terminal domain of OGA

Critical Casimir forces and adsorption profiles in the presence of a chemically structured substrate

Motivated by recent experiments with confined binary liquid mixtures near demixing, we study the universal critical properties of a system, which belongs to the Ising universality class, in the film geometry. We employ periodic boundary conditions in the two lateral directions and fixed boundary conditions on the two confining surfaces, such that one of them has a spatially homogeneous adsorption preference while the other one exhibits a laterally alternating adsorption preference, resembling locally a single chemical step. By means of Monte Carlo simulations of an improved Hamiltonian, so that the leading scaling corrections are suppressed, numerical integration, and finite-size scaling analysis we determine the critical Casimir force and its universal scaling function for various values of the aspect ratio of the film. In the limit of a vanishing aspect ratio the critical Casimir force of this system reduces to the mean value of the critical Casimir force for laterally homogeneous ++ and +- boundary conditions, corresponding to the surface spins on the two surfaces being fixed to equal and opposite values, respectively. We show that the universal scaling function of the critical Casimir force for small but finite aspect ratios displays a linear dependence on the aspect ratio which is solely due to the presence of the lateral inhomogeneity. We also analyze the order-parameter profiles at criticality and their universal scaling function which allows us to probe theoretical predictions and to compare with experimental data.Comment: revised version, section 5.2 expanded; 53 pages, 12 figures, iopart clas

Wissensordnung als Kritik : die Ordnung der menschlichen Kenntnisse nach Jean d'Alembert

Der Beitrag arbeitet d’Alemberts Absicht heraus, durch eine mathematisch begründete Wissensordnung, die einen universellen Geltungsanspruch erhebt, die Dogmatik des religiösen Glaubens genauso wie die Autoritätshörigkeit der ständischen Gesellschaft zu diskreditieren und somit die bestehenden Machtverhältnisse zu destabilisieren. Mit der universalistischen Wissensordnung der Enzyklopädie soll schließlich auch eine neue normative Ordnung etabliert werden. Dabei ist die Rolle der Enzyklopädisten als Aufklärer der unaufgeklärten Gesellschaft Teil der universalistischen Wissensordnung. Obwohl sich die beanspruchte emanzipative Wirkung des enzyklopädischen Universalismus im historischen Kontext von Dogmatismus und Despotismus nachvollziehen lässt, stellt sich die Frage, inwieweit dieser universalistische Anspruch tatsächlich eine ‚kritischen Haltung’, wie sie von Foucault anhand Kants Schrift „Was ist Aufklärung?“ definiert wird, genügt oder doch nur eine ‚Wissenskritik’ bleibt. Die Haltungsfrage verweist auf d’Alemberts ambivalentes Verhältnis zu den politischen Autoritäten seiner Zeit