369 research outputs found

    Influence of the substrate-induced strain and irradiation disorder on the Peierls transition in TTF-TCNQ microdomains

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    The influence of the combined effects of substrate-induced strain, finite size and electron irradiation-induced defects have been studied on individual micron-sized domains of the organic charge transfer compound tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) by temperature-dependent conductivity and current-voltage measurements. The individual domains have been isolated by focused ion beam etching and electrically contacted by focused ion and electron beam induced deposition of metallic contacts. The temperature-dependent conductivity follows a variable range hopping behavior which shows a crossover of the exponent as the Peierls transition is approached. The low temperature behavior is analyzed within the segmented rod model of Fogler, Teber and Shklowskii, as originally developed for a charge-ordered quasi one-dimensional electron crystal. The results are compared with data obtained on as-grown and electron irradiated epitaxial TTF-TCNQ thin films of the two-domain type

    Direct observation of active material concentration gradients and crystallinity breakdown in LiFePO4 electrodes during charge/discharge cycling of lithium batteries

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    The phase changes that occur during discharge of an electrode comprised of LiFePO4, carbon, and PTFE binder have been studied in lithium half cells by using X-ray diffraction measurements in reflection geometry. Differences in the state of charge between the front and the back of LiFePO4 electrodes have been visualized. By modifying the X-ray incident angle the depth of penetration of the X-ray beam into the electrode was altered, allowing for the examination of any concentration gradients that were present within the electrode. At high rates of discharge the electrode side facing the current collector underwent limited lithium insertion while the electrode as a whole underwent greater than 50% of discharge. This behavior is consistent with depletion at high rate of the lithium content of the electrolyte contained in the electrode pores. Increases in the diffraction peak widths indicated a breakdown of crystallinity within the active material during cycling even during the relatively short duration of these experiments, which can also be linked to cycling at high rate

    Localized instabilities of the Wigner equation as a model for the emergence of Rogue Waves

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    In this paper, we model Rogue Waves as localized instabilities emerging from homogeneous and stationary background wavefields, under NLS dynamics. This is achieved in two steps: given any background Fourier spectrum P(k), we use the Wigner transform and Penrose’s method to recover spatially periodic unstable modes, which we call unstable Penrose modes. These can be seen as generalized Benjamin–Feir modes, and their parameters are obtained by resolving the Penrose condition, a system of nonlinear equations involving P(k). Moreover, we show how the superposition of unstable Penrose modes can result in the appearance of localized unstable modes. By interpreting the appearance of an unstable mode localized in an area not larger than a reference wavelength λ0 as the emergence of a Rogue Wave, a criterion for the emergence of Rogue Waves is formulated. Our methodology is applied to δ spectra, where the standard Benjamin–Feir instability is recovered, and to more general spectra. In that context, we present a scheme for the numerical resolution of the Penrose condition and estimate the sharpest possible localization of unstable modes. Keywords: Rogue Waves; Wigner equation; Nonlinear Schrodinger equation; Penrose modes; Penrose conditio

    Control of Neural Daughter Cell Proliferation by Multi-level Notch/Su(H)/E(spl)-HLH Signaling

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    The Notch pathway controls proliferation during development and in adulthood, and is frequently affected in many disorders. However, the genetic sensitivity and multi-layered transcriptional properties of the Notch pathway has made its molecular decoding challenging. Here, we address the complexity of Notch signaling with respect to proliferation, using the developing Drosophila CNS as model. We find that a Notch/Su(H)/E(spl)-HLH cascade specifically controls daughter, but not progenitor proliferation. Additionally, we find that different E(spl)-HLH genes are required in different neuroblast lineages. The Notch/Su(H)/E(spl)-HLH cascade alters daughter proliferation by regulating four key cell cycle factors: Cyclin E, String/Cdc25, E2f and Dacapo (mammalian p21CIP1/p27KIP1/p57Kip2). ChIP and DamID analysis of Su(H) and E(spl)-HLH indicates direct transcriptional regulation of the cell cycle genes, and of the Notch pathway itself. These results point to a multi-level signaling model and may help shed light on the dichotomous proliferative role of Notch signaling in many other systems

    Model-based exploration of linking between vowel articulatory space and acoustic space

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    While the acoustic vowel space has been extensively studied in previous research, little is known about the high-dimensional articulatory space of vowels. The articulatory imaging techniques are limited to tracking only a few key articulators, leaving the rest of the articulators unmonitored. In the present study, we attempted to develop a detailed articulatory space obtained by training a 3D articulatory synthesizer to learn eleven British English vowels. An analysis-by-synthesis strategy was used to acoustically optimize vocal tract parameters that represent twenty articulatory dimensions. The results show that tongue height and retraction, larynx location and lip roundness are the most perceptually distinctive articulatory dimensions. Yet, even for these dimensions, there is a fair amount of articulatory overlap between vowels, unlike the fine-grained acoustic space. This method opens up the possibility of using modelling to investigate the link between speech production and perception
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