Electrically detected magnetic resonance of carbon dangling bonds at the Si-face 4H-SiC/SiO2_2 interface

SiC based metal-oxide-semiconductor field-effect transistors (MOSFETs) have gained a significant importance in power electronics applications. However, electrically active defects at the SiC/SiO$_2$ interface degrade the ideal behavior of the devices. The relevant microscopic defects can be identified by electron paramagnetic resonance (EPR) or electrically detected magnetic resonance (EDMR). This helps to decide which changes to the fabrication process will likely lead to further increases of device performance and reliability. EDMR measurements have shown very similar dominant hyperfine (HF) spectra in differently processed MOSFETs although some discrepancies were observed in the measured $g$-factors. Here, the HF spectra measured of different SiC MOSFETs are compared and it is argued that the same dominant defect is present in all devices. A comparison of the data with simulated spectra of the C dangling bond (P$_\textrm{bC}$) center and the silicon vacancy (V$_\textrm{Si}$) demonstrates that the P$_\textrm{bC}$ center is a more suitable candidate to explain the observed HF spectra.Comment: Accepted for publication in the Journal of Applied Physic

CFD modeling and performance evaluation of multipass solar air heaters

This article investigates the impacts of flow configurations on the thermal performance of a solar heater system. Recycled aluminum cans (RACs) have been utilized as turbulators with a double pass single duct solar air collector. The CFD software of COMSOL Multiphysics V5.3a is used to model three designs: Cocurrent (model A), countercurrent (model B), and U-shape (model C). The numerical results reveal that the U-shape design offers a greater thermal performance of 5.4% and 6.5%, respectively, compared with the cocurrent and countercurrent flow models. Furthermore, an outdoor experiment is performed based on the numerical modeling of flow configurations. The experimental setup is examined for three configurations of model C, namely, solar air heater (SAH) without RAC model C-I (plain model), SAH with in-line RAC layout (model C-II), and SAH with staggered RAC layout (model C-III). We found the double pass single duct solar air collector (model C) design is in a good agreement with the experimental data, and model C-III has a better thermal efficiency of 60.2%, compared to those of model C-II, 53.1%, and model C-I, 49.4%

To retain or remove the syndesmotic screw: a review of literature

Introduction: Syndesmotic positioning screws are frequently placed in unstable ankle fractures. Many facets of adequate placement techniques have been the subject of various studies. Whether or not the syndesmosis screw should be removed prior to weight-bearing is still debated. In this study, the recent literature is reviewed concerning the need for removal of the syndesmotic screw. Materials and methods: A comprehensive literature search was conducted in the electronic databases of the Cochrane Library, Pubmed Medline and EMbase from January 2000 to October 2010. Results: A total of seven studies were identified in the literature. Most studies found no difference in outcome between retained or removed screws. Patients with screws that were broken, or showed loosening, had similar or improved outcome compared to patients with removed screws. Removal of the syndesmotic screws, when deemed necessary, is usually not performed before 8-12 weeks. Conclusion: There is paucity in randomized controlled trials on the absolute need for removal of the syndesmotic screw. However, current literature suggests that it might be reserved for intact screws that cause hardware irritation or reduced range of motion after 4-6 months

Temperature-Dependent Dynamic Disproportionation in LiNiO₂

Nickelate materials offer diverse functionalities for energy and computing applications. Lithium nickel oxide (LiNiO2) is an archetypal layered nickelate, but the electronic structure of this correlated material is not yet fully understood. Here, we investigate the temperature-dependent speciation and spin dynamics of Ni ions in LiNiO2. Our ab initio simulations predict that Ni ions disproportionate into three states, which dynamically interconvert and whose populations vary with temperature. These predictions are verified using x-ray absorption spectroscopy, x-ray magnetic circular dichroism, and resonant inelastic x-ray scattering at the Ni L3,2-edge. Charge transfer multiplet calculations consistent with disproportionation reproduce all experimental features. Together, our experimental and computational results support a model of dynamic disproportionation that explains diverse physical observations of LiNiO2, including magnetometry, thermally activated electronic conduction, diffractometry, core-level spectroscopies, and the stability of ubiquitous antisite defects. This unified understanding of the fundamental material properties of LiNiO2 is important for applications of nickelate materials as battery cathodes, catalysts, and superconductors.<br/

CFD analysis of a one-pass photovoltaic/thermal air system with and without offset strip fins

The focus on managing PV panel temperature has undergone a remarkable development in the last two decades. Specifically, in countries with moderate weather temperature and high insolation, the problem of keeping the PV cell temperature in an optimal range has been managed by use of PV/T collectors. In this work, a single pass PV/T collector using laminar air flow has been assessed. Two PV/T collector designs are utilised, one with and one without offset strip fins. COMSOL Multiphysics v5.3a has been used for the analysis of the thermal and electrical performances. Two assumptions were implemented in order to reduce the computational time from 95 hours to 7 hours, namely ignoring radiative effects between the fins and the wall channels, and representing thin layers as 2D boundaries, whilst ensuring a high level of conformity (4%),. Monocrystalline silicon PV cells were used with a power temperature coefficient of 0.41%. A validation against work in the literature was made, showing a good consistency. The objective of this work is to verify the performance of the air PV/T collector with offset strip fins compared to an unfinned air PV/T collector. The results reveal that the use of offset strip fins has a noticeable impact on both the electrical and thermal efficiencies of the system. In addition, the maximum combined efficiency (ηC o ) for the finned PV/T system is 84.7% while the unfinned PV/T system is 51.2%

Information Extraction from Unstructured Text for the Biodefense Knowledge Center

The Bio-Encyclopedia at the Biodefense Knowledge Center (BKC) is being constructed to allow an early detection of emerging biological threats to homeland security. It requires highly structured information extracted from variety of data sources. However, the quantity of new and vital information available from every day sources cannot be assimilated by hand, and therefore reliable high-throughput information extraction techniques are much anticipated. In support of the BKC, Lawrence Livermore National Laboratory and Oak Ridge National Laboratory, together with the University of Utah, are developing an information extraction system built around the bioterrorism domain. This paper reports two important pieces of our effort integrated in the system: key phrase extraction and semantic tagging. Whereas two key phrase extraction technologies developed during the course of project help identify relevant texts, our state-of-the-art semantic tagging system can pinpoint phrases related to emerging biological threats. Also we are enhancing and tailoring the Bio-Encyclopedia by augmenting semantic dictionaries and extracting details of important events, such as suspected disease outbreaks. Some of these technologies have already been applied to large corpora of free text sources vital to the BKC mission, including ProMED-mail, PubMed abstracts, and the DHS's Information Analysis and Infrastructure Protection (IAIP) news clippings. In order to address the challenges involved in incorporating such large amounts of unstructured text, the overall system is focused on precise extraction of the most relevant information for inclusion in the BKC

Temperature-Dependent Dynamic Disproportionation in LiNiO2_2

Nickelate materials offer diverse functionalities for energy and computing applications. Lithium nickel oxide (LiNiO$_2$) is an archetypal layered nickelate, but the electronic structure of this correlated material is not yet fully understood. Here we investigate the temperature-dependent speciation and spin dynamics of Ni ions in LiNiO$_2$. Our ab initio simulations predict that Ni ions disproportionate into three states, which dynamically interconvert and whose populations vary with temperature. These predictions are verified using x-ray absorption spectroscopy, x-ray magnetic circular dichroism, and resonant inelastic x-ray scattering at the Ni L$_{3,2}$-edge. Charge-transfer multiplet calculations consistent with disproportionation reproduce all experimental features. Together, our experimental and computational results support a model of dynamic disproportionation that explains diverse physical observations of LiNiO$_2$, including magnetometry, thermally activated electronic conduction, diffractometry, core-level spectroscopies, and the stability of ubiquitous antisite defects. This unified understanding of the fundamental material properties of LiNiO$_2$ is important for applications of nickelate materials as battery cathodes, catalysts, and superconductors.30 pages, 16 figure