Negative magnetocaloric effect from highly sensitive metamagnetism in CoMnSi_{1-x}Ge_{x}

We report a novel negative magnetocaloric effect in CoMnSi_{1-x}Ge_{x} arising from a metamagnetic magnetoelastic transition. The effect is of relevance to magnetic refrigeration over a wide range of temperature, including room temperature. In addition we report a very high shift in the metamagnetic transition temperature with applied magnetic field. This is driven by competition between antiferromagnetic and ferromagnetic order which can be readily tuned by applied pressure and compositional changes.Comment: 5 pages, 5 figures, REVTeX, submitted to Physical Revie

Cascade of magnetic field induced Lifshitz transitions in the ferromagnetic Kondo lattice material YbNi4P2

A ferromagnetic quantum critical point is thought not to exist in two and three-dimensional metallic systems yet is realized in the Kondo lattice compound YbNi4(P,As)2, possibly due to its one-dimensionality. It is crucial to investigate the dimensionality of the Fermi surface of YbNi4P2 experimentally but common probes such as ARPES and quantum oscillation measurements are lacking. Here, we studied the magnetic field dependence of transport and thermodynamic properties of YbNi4P2. The Kondo effect is continuously suppressed and additionally we identify nine Lifshitz transitions between 0.4 and 18 T. We analyze the transport coefficients in detail and identify the type of Lifshitz transitions as neck or void type to gain information on the Fermi surface of YbNi4P2. The large number of Lifshitz transitions observed within this small energy window is unprecedented and results from the particular flat renormalized band structure with strong 4f-electron character shaped by the Kondo lattice effect.Comment: 6 pages, 4 figure

Nernst and Seebeck Coefficients of the Cuprate SuperconductorYBa2_2Cu3_3O6.67_{6.67}: A Study of Fermi Surface Reconstruction

The Seebeck and Nernst coefficients $S$ and $\nu$ of the cuprate superconductor YBa$_2$Cu$_3$O$_y$ (YBCO) were measured in a single crystal with doping $p = 0.12$ in magnetic fields up to H = 28 T. Down to T=9 K, $\nu$ becomes independent of field by $H \simeq 30$ T, showing that superconducting fluctuations have become negligible. In this field-induced normal state, $S/T$ and $\nu/T$ are both large and negative in the $T \to 0$ limit, with the magnitude and sign of $S/T$ consistent with the small electron-like Fermi surface pocket detected previously by quantum oscillations and the Hall effect. The change of sign in $S(T)$ at $T \simeq 50$ K is remarkably similar to that observed in La$_{2-x}$Ba$_x$CuO$_4$, La$_{2-x-y}$Nd$_y$Sr$_x$CuO$_4$ and La$_{2-x-y}$Eu$_y$Sr$_x$CuO$_4$, where it is clearly associated with the onset of stripe order. We propose that a similar density-wave mechanism causes the Fermi surface reconstruction in YBCO.Comment: Final version accepted for publication in Phys. Rev. Lett. New title, shorter abstract, minor revision of text and added reference

Technology for NASA's Planetary Science Vision 2050.

NASAs Planetary Science Division (PSD) initiated and sponsored a very successful community Workshop held from Feb. 27 to Mar. 1, 2017 at NASA Headquarters. The purpose of the Workshop was to develop a vision of planetary science research and exploration for the next three decades until 2050. This abstract summarizes some of the salient technology needs discussed during the three-day workshop and at a technology panel on the final day. It is not meant to be a final report on technology to achieve the science vision for 2050

Understanding the needs of Mena public transport customers: culture of service and gender responsive recommendations

Fast population growth, urban sprawl and the raise in households’ motorization observed in all major cities of the Middle-East and North-Africa (MENA) region, are constantly challenging public transport providers who seek to handle efficiently the continuously rising travel demand. Most of the MENA cities suffer from traffic congestion that not only impacts the quality of life of MENA citizens, but also their access to job opportunities, health services, and social and political participation. Alongside the development of public transport network, it is crucial to encourage urban dwellers to reduce their dependence on personal cars, use public transport, and develop soft mobility skills. Therefore, operators and service providers need to define customer-centric strategy and build a culture of service excellence in line with their customers’expectations. In cooperation with academic partners, the UITP MENA Centre for Transport Excellence launched the User-Oriented Public Transport research project with the aim to understand the perceptions of female and male users and non-users about public transport services in five MENA cities: Algiers, Amman, Beirut, Casablanca and Muscat. The methodological framework was built around the five dimensions of the user’s needs pyramid: safety, security, ease-to-use, comfort and experience. Based on the quantitative analysis of data collected from 984 respondents and the qualitative analysis of 49 women’s testimonies collected during the focus groups, recommendations were made to encourage culture of service and gender mainstreaming in public transport development in the region

Broken rotational symmetry in the pseudogap phase of a high-Tc superconductor

The nature of the pseudogap phase is a central problem in the quest to understand high-Tc cuprate superconductors. A fundamental question is what symmetries are broken when that phase sets in below a temperature T*. There is evidence from both polarized neutron diffraction and polar Kerr effect measurements that time- reversal symmetry is broken, but at temperatures that differ significantly. Broken rotational symmetry was detected by both resistivity and inelastic neutron scattering at low doping and by scanning tunnelling spectroscopy at low temperature, but with no clear connection to T*. Here we report the observation of a large in-plane anisotropy of the Nernst effect in YBa2Cu3Oy that sets in precisely at T*, throughout the doping phase diagram. We show that the CuO chains of the orthorhombic lattice are not responsible for this anisotropy, which is therefore an intrinsic property of the CuO2 planes. We conclude that the pseudogap phase is an electronic state which strongly breaks four-fold rotational symmetry. This narrows the range of possible states considerably, pointing to stripe or nematic orders.Comment: Published version. Journal reference and DOI adde

Lifshitz critical point in the cuprate superconductor YBa2Cu3Oy from high-field Hall effect measurements

The Hall coefficient R_H of the cuprate superconductor YBa2Cu3Oy was measured in magnetic fields up to 60 T for a hole concentration p from 0.078 to 0.152, in the underdoped regime. In fields large enough to suppress superconductivity, R_H(T) is seen to go from positive at high temperature to negative at low temperature, for p > 0.08. This change of sign is attributed to the emergence of an electron pocket in the Fermi surface at low temperature. At p < 0.08, the normal-state R_H(T) remains positive at all temperatures, increasing monotonically as T \to 0. We attribute the change of behaviour across p = 0.08 to a Lifshitz transition, namely a change in Fermi-surface topology occurring at a critical concentration p_L = 0.08, where the electron pocket vanishes. The loss of the high-mobility electron pocket across p_L coincides with a ten-fold drop in the conductivity at low temperature, revealed in measurements of the electrical resistivity $\rho$ at high fields, showing that the so-called metal-insulator crossover of cuprates is in fact driven by a Lifshitz transition. It also coincides with a jump in the in-plane anisotropy of $\rho$, showing that without its electron pocket the Fermi surface must have strong two-fold in-plane anisotropy. These findings are consistent with a Fermi-surface reconstruction caused by a unidirectional spin-density wave or stripe order.Comment: 16 pages, 13 figures, see associated Viewpoint: M. Vojta, Physics 4, 12 (2011

Boron-containing delocalised lipophilic cations for the selective targeting of cancer cells

Correction for “Boron-containing delocalised lipophilic cations for the selective targeting of cancer cells” by Gianpiero Calabrese et al., Med. Chem. Commun., 2017, 8, 67–72.</p

Enhancement of the Nernst effect by stripe order in a high-Tc superconductor

The Nernst effect in metals is highly sensitive to two kinds of phase transition: superconductivity and density-wave order. The large positive Nernst signal observed in hole-doped high-Tc superconductors above their transition temperature Tc has so far been attributed to fluctuating superconductivity. Here we show that in some of these materials the large Nernst signal is in fact caused by stripe order, a form of spin / charge modulation which causes a reconstruction of the Fermi surface. In LSCO doped with Nd or Eu, the onset of stripe order causes the Nernst signal to go from small and negative to large and positive, as revealed either by lowering the hole concentration across the quantum critical point in Nd-LSCO, or lowering the temperature across the ordering temperature in Eu-LSCO. In the latter case, two separate peaks are resolved, respectively associated with the onset of stripe order at high temperature and superconductivity near Tc. This sensitivity to Fermi-surface reconstruction makes the Nernst effect a promising probe of broken symmetry in high-Tc superconductors