Investigation of slip transfer across HCP grain boundaries with application to cold dwell facet fatigue

This paper addresses the role of grain boundary slip transfer and thermally-activated discrete dislocation plasticity in the redistribution of grain boundary stresses during cold dwell fatigue in titanium alloys. Atomistic simulations have been utilised to calculate the grain boundary energies for titanium with respect to the misorientation angles. The grain boundary energies are utilised within a thermally-activated discrete dislocation plasticity model incorporating slip transfer controlled by energetic and grain boundary geometrical criteria. The model predicts the grain size effect on the flow strength in Ti alloys. Cold dwell fatigue behaviour in Ti-6242 alloy is investigated and it is shown that significant stress redistribution from soft to hard grains occurs during the stress dwell, which is observed both for grain boundaries for which slip transfer is permitted and inhibited. However, the grain boundary slip penetration is shown to lead to significantly higher hard-grain basal stresses near the grain boundary after dwell, thus exacerbating the load shedding stress compared to an impenetrable grain boundary. The key property controlling the dwell fatigue response is argued to remain the time constant associated with the thermal activation process for dislocation escape, but the slip penetrability is also important and exacerbates the load shedding. The inclusion of a macrozone does not significantly change the conclusions but does potentially lead to the possibility of a larger initial facet

On the QED Effective Action in Time Dependent Electric Backgrounds

We apply the resolvent technique to the computation of the QED effective action in time dependent electric field backgrounds. The effective action has both real and imaginary parts, and the imaginary part is related to the pair production probability in such a background. The resolvent technique has been applied previously to spatially inhomogeneous magnetic backgrounds, for which the effective action is real. We explain how dispersion relations connect these two cases, the magnetic case which is essentially perturbative in nature, and the electric case where the imaginary part is nonperturbative. Finally, we use a uniform semiclassical approximation to find an expression for very general time dependence for the background field. This expression is remarkably similar in form to Schwinger's classic result for the constant electric background.Comment: 27 pages, no figures; reference adde

Euler-Heisenberg lagrangians and asymptotic analysis in 1+1 QED, part 1: Two-loop

We continue an effort to obtain information on the QED perturbation series at high loop orders, and particularly on the issue of large cancellations inside gauge invariant classes of graphs, using the example of the l - loop N - photon amplitudes in the limit of large photons numbers and low photon energies. As was previously shown, high-order information on these amplitudes can be obtained from a nonperturbative formula, due to Affleck et al., for the imaginary part of the QED effective lagrangian in a constant field. The procedure uses Borel analysis and leads, under some plausible assumptions, to a number of nontrivial predictions already at the three-loop level. Their direct verification would require a calculation of this `Euler-Heisenberg lagrangian' at three-loops, which seems presently out of reach. Motivated by previous work by Dunne and Krasnansky on Euler-Heisenberg lagrangians in various dimensions, in the present work we initiate a new line of attack on this problem by deriving and proving the analogous predictions in the simpler setting of 1+1 dimensional QED. In the first part of this series, we obtain a generalization of the formula of Affleck et al. to this case, and show that, for both Scalar and Spinor QED, it correctly predicts the leading asymptotic behaviour of the weak field expansion coefficients of the two loop Euler-Heisenberg lagrangians.Comment: 28 pages, 1 figures, final published version (minor modifications, refs. added

Fermion Determinants

The current status of bounds on and limits of fermion determinants in two, three and four dimensions in QED and QCD is reviewed. A new lower bound on the two-dimensional QED determinant is derived. An outline of the demonstration of the continuity of this determinant at zero mass when the background magnetic field flux is zero is also given.Comment: 10 page

Practically linear analogs of the Born-Infeld and other nonlinear theories

I discuss theories that describe fully nonlinear physics, while being practically linear (PL), in that they require solving only linear differential equations. These theories may be interesting in themselves as manageable nonlinear theories. But, they can also be chosen to emulate genuinely nonlinear theories of special interest, for which they can serve as approximations. The idea can be applied to a large class of nonlinear theories, exemplified here with a PL analogs of scalar theories, and of Born-Infeld (BI) electrodynamics. The general class of such PL theories of electromagnetism are governed by a Lagrangian L=-(1/2)F_mnQ^mn+ S(Q_mn), where the electromagnetic field couples to currents in the standard way, while Qmn is an auxiliary field, derived from a vector potential that does not couple directly to currents. By picking a special form of S(Q_mn), we can make such a theory similar in some regards to a given fully nonlinear theory, governed by the Lagrangian -U(F_mn). A particularly felicitous choice is to take S as the Legendre transform of U. For the BI theory, this Legendre transform has the same form as the BI Lagrangian itself. Various matter-of-principle questions remain to be answered regarding such theories. As a specific example, I discuss BI electrostatics in more detail. As an aside, for BI, I derive an exact expression for the short-distance force between two arbitrary point charges of the same sign, in any dimension.Comment: 20 pages, Version published in Phys. Rev.

The dynamics of market structure and market size in two health services industries

The relationship between the size of a market and the competitiveness of the market has been of long-standing interest to IO economists. Empirical studies have used the relationship between the size of the geographic market and both the number of firms in the market and the average sales of the firms to draw inferences about the degree of competition in the market. This paper extends this framework to incorporate the analysis of entry and exit flows. A key implication of recent entry and exit models is that current market structure will likely depend upon the history of past participation. The paper explores these issues empirically by examining producer dynamics for two health service industries, dentistry and chiropractic services.Markets ; Industrial organization ; Service industries

Entry, exit and the determinants of market structure

Market structure is determined by the entry and exit decisions of individual producers. These decisions are driven by expectations of future profits which, in turn, depend on the nature of competition within the market. In this paper we estimate a dynamic, structural model of entry and exit in an oligopolistic industry and use it to quantify the determinants of market structure and long-run firm values for two U.S. service industries, dentists and chiropractors. We find that entry costs faced by potential entrants, fixed costs faced by incumbent producers, and the toughness of short-run price competition are all important determinants of long run firm values and market structure. As the number of firms in the market increases, the value of continuing in the market and the value of entering the market both decline, the probability of exit rises, and the probability of entry declines. The magnitude of these effects differ substantially across markets due to differences in exogenous cost and demand factors and across the dentist and chiropractor industries. Simulations using the estimated model for the dentist industry show that pressure from both potential entrants and incumbent firms discipline long-run profits. We calculate that a seven percent reduction in the mean sunk entry cost would reduce a monopolist's long-run profits by the same amount as if the firm operated in a duopoly.Markets ; Competition ; Service industries

Magnetic-field Induced Screening Effect and Collective Excitations

We explicitly construct the fermion propagator in a magnetic field background B to take the lowest Landau-level approximation. We analyze the energy and momentum dependence in the polarization tensor and discuss the collective excitations. We find there appear two branches of collective modes in one of two transverse gauge particles; one represents a massive and attenuated gauge particle and the other behaves similar to the zero sound at finite density.Comment: 5 pages, 3 figures; references on the zero sound added and typos correcte

The Synthesis and Characterization of New, Robust Titanium (IV) Scorpionate Complexes

Titanium complexes possessing sterically encumbered ligands have allowed for the preparation of reactive moieties (imido, alkylidene and alkylidyne species) relevant to reactions such as olefin polymerization and alkyne hydroamination. For this reason, we have targeted robust scorpionate ancillary ligands to support reactive titanium centers. Thus, a series of titanium complexes were synthesized using an achiral oxazoline-based scorpionate ligand, tris(4,4-dimethyl-2-oxazolinyl)phenyl borate [To^M^]^-^ as well as the related chiral ligand, tris(4-isopropyl-2-oxazolinyl)phenyl borate [To^P^]^-^. The complex [Ti(κ^3^- To^M^)Cl~3~] was prepared in moderate yield (43%) by the rapid (<1 min at room temperature) reaction of Li[To^M^] and TiCl~4~ in methylene chloride; this new compound was characterized by ^1^H NMR spectroscopy as the expected C~3v~-symmetric species. One route to Ti (IV) alkyls involves salt metathesis; accordingly, syntheses of [To^M^]Ti alkyl complexes by interaction of [Ti(κ^3^-To^M^)Cl~3~] and one or three equivalents of alkylating agents, such as benzyl potassium (KCH~2~C~6~H~5~), trimethylsilylmethyl
lithium (LiCH~2~Si(CH~3~) ~3~), or neopentyl lithium (LiCH~2~C(CH~3~)~3~) are currently under investigation. The complexes [Ti(=NBut) (κ~3~-To^M^)(Cl)(Bu^t^py)] (Bu^t^py=4 tert-butylpyridine) and [Ti(=NBu^t^) (κ~3~-To^P^)(Cl)(Bu^t^py)] were synthesized by reaction of the known Ti imido [Ti(=NBu^t^)(Cl)~2~(Bu^t^py)~2~] with Li[To^M^] or Li[To^P^], respectively, by stirring overnight in methylene chloride at ambient temperature. The complexes were identified using ^1^H NMR spectroscopy, ^1^H-^13^C HMQC and ^1^H-^15^N HMBC correlation experiments