A route to explain water anomalies from results on an aqueous solution of salt

In this paper we investigate the possibility to detect the hypothesized liquid-liquid critical point of water in supercooled aqueous solutions of salts. Molecular dynamics computer simulations are conducted on bulk TIP4P water and on an aqueous solution of sodium chloride in TIP4P water, with concentration c = 0.67 mol/kg. The liquid-liquid critical point is found both in the bulk and in the solution. Its position in the thermodynamic plane shifts to higher temperature and lower pressure for the solution. Comparison with available experimental data allowed us to produce the phase diagrams of both bulk water and the aqueous solution as measurable in experiments. Given the position of the liquid-liquid critical point in the solution as obtained from our simulations, the experimental determination of the hypothesized liquid-liquid critical point of water in aqueous solutions of salts appears possible.Comment: 5 pages, 6 figures. Accepted for publication on the Journal of Chemical Physics (2010)

Driving extreme variability: The evolving corona and evidence for jet launching in Markarian 335

Variations in the X-ray emission from the narrow line Seyfert 1 galaxy, Markarian 335 (Mrk 335), are studied on both long and short timescales through observations made between 2006 and 2013 with XMM-Newton, Suzaku and NuSTAR. Changes in the geometry and energetics of the corona that give rise to this variability are inferred through measurements of the relativistically blurred reflection seen from the accretion disc. On long timescales, we find that during the high flux epochs the corona has expanded, covering the inner regions of the accretion disc out to a radius of 26(-7,+10)rg. The corona contracts to within 12rg and 5rg in the intermediate and low flux epochs, respectively. While the earlier high flux observation made in 2006 is consistent with a corona extending over the inner part of the accretion disc, a later high flux observation that year revealed that the X-ray source had become collimated into a vertically-extended jet-like corona and suggested relativistic motion of material upward. On short timescales, we find that an X-ray flare during a low flux epoch in 2013 corresponded to a reconfiguration from a slightly extended corona to one much more compact, within just 2~3rg of the black hole. There is evidence that during the flare itself, the spectrum softened and the corona became collimated and slightly extended vertically as if a jet-launching event was aborted. Understanding the evolution of the X-ray emitting corona may reveal the underlying mechanism by which the luminous X-ray sources in AGN are powered.Comment: 21 pages, 9 figures. Accepted for publication in MNRA

Mrk 1014: An AGN Dominated ULIRG at X-rays

In this paper we report on an XMM-Newton observation of the ultraluminous infrared QSO Mrk 1014. The X-ray observation reveals a power-law dominated (photon index of about 2.2) spectrum with a slight excess in the soft energy range. AGN and starburst emission models fit the soft excess emission equally well, however, the most plausible explanation is an AGN component as the starburst model parameter, temperature and luminosity, appear physically unrealistic. The mean luminosity of Mrk 1014 is about 2 times 10^44 erg s^-1. We have also observed excess emission at energies greater than 5 keV. This feature could be attributed to a broadened and redshifted iron complex, but deeper observations are required to constrain its origin. The light curve shows small scale variability over the 11 ks observation. There is no evidence of intrinsic absorption in Mrk 1014. The X-ray observations support the notion of an AGN dominated central engine. We establish the need for a longer observation to constrain more precisely the nature of the X-ray components.Comment: 5 pages incl. 3 figures, MNRAS in pres

Structural Properties of High and Low Density Water in a Supercooled Aqueous Solution of Salt

We consider and compare the structural properties of bulk TIP4P water and of a sodium chloride aqueous solution in TIP4P water with concentration c = 0.67 mol/kg, in the metastable supercooled region. In a previous paper [D. Corradini, M. Rovere and P. Gallo, J. Chem. Phys. 132, 134508 (2010)] we found in both systems the presence of a liquid-liquid critical point (LLCP). The LLCP is believed to be the end point of the coexistence line between a high density liquid (HDL) and a low density liquid (LDL) phase of water. In the present paper we study the different features of water-water structure in HDL and LDL both in bulk water and in the solution. We find that the ions are able to modify the bulk LDL structure, rendering water-water structure more similar to the bulk HDL case. By the study of the hydration structure in HDL and LDL, a possible mechanism for the modification of the bulk LDL structure in the solution is identified in the substitution of the oxygen by the chloride ion in oxygen coordination shells.Comment: 10 pages, 10 figures, 2 tables. Accepted for publication on J. Phys. Chem

Wearable Platform for Automatic Recognition of Parkinson Disease by Muscular Implication Monitoring

The need for diagnostic tools for the characterization of progressive movement disorders - as the Parkinson Disease (PD) - aiming to early detect and monitor the pathology is getting more and more impelling. The parallel request of wearable and wireless solutions, for the real-time monitoring in a non-controlled environment, has led to the implementation of a Quantitative Gait Analysis platform for the extraction of muscular implications features in ordinary motor action, such as gait. The here proposed platform is used for the quantification of PD symptoms. Addressing the wearable trend, the proposed architecture is able to define the real-time modulation of the muscular indexes by using 8 EMG wireless nodes positioned on lower limbs. The implemented system “translates” the acquisition in a 1-bit signal, exploiting a dynamic thresholding algorithm. The resulting 1-bit signals are used both to define muscular indexes both to drastically reduce the amount of data to be analyzed, preserving at the same time the muscular information. The overall architecture has been fully implemented on Altera Cyclone V FPGA. The system has been tested on 4 subjects: 2 affected by PD and 2 healthy subjects (control group). The experimental results highlight the validity of the proposed solution in Disease recognition and the outcomes match the clinical literature results

Reliability Analysis of Complex NASA Systems with Model-Based Engineering

The emergence of model-based engineering, with Model- Based Systems Engineering (MBSE) leading the way, is transforming design and analysis methodologies. The recognized benefits to systems development include moving from document-centric information systems and document-centric project communication to a model-centric environment in which control of design changes in the life cycles is facilitated. In addition, a single source of truth about the system, that is up-to-date in all respects of the design, becomes the authoritative source of data and information about the system. This promotes consistency and efficiency in regard to integration of the system elements as the design emerges and thereby may further optimize the design. Therefore Reliability Engineers (REs) supporting NASA missions must be integrated into model-based engineering to ensure the outputs of their analyses are relevant and value-needed to the design, development, and operational processes for failure risks assessment and communication

Modelling the Extreme X-ray Spectrum of IRAS 13224-3809

The extreme NLS1 galaxy IRAS 13224-3809 shows significant variability, frequency depended time lags, and strong Fe K line and Fe L features in the long 2011 XMM-Newton observation. In this work we study the spectral properties of IRAS 13224-3809 in detail, and carry out a series of analyses to probe the nature of the source, focusing in particular on the spectral variability exhibited. The RGS spectrum shows no obvious signatures of absorption by partially ionised material (warm absorbers). We fit the 0.3-10.0 keV spectra with a model that includes relativistic reflection from the inner accretion disc, a standard powerlaw AGN continuum, and a low-temperature (~0.1 keV) blackbody, which may originate in the accretion disc, either as direct or reprocessed thermal emission. We find that the reflection model explains the time-averaged spectrum well, and we also undertake flux-resolved and time-resolved spectral analyses, which provide evidence of gravitational light-bending effects. Additionally, the temperature and flux of the blackbody component are found to follow the $L\propto T^{4}$ relation expected for simple thermal blackbody emission from a constant emitting area, indicating a physical origin for this component.Comment: 12 pages, 7 figures, accepted for publication in MNRA

Fragile to strong crossover coupled to liquid-liquid transition in hydrophobic solutions

Using discrete molecular dynamics simulations we study the relation between the thermodynamic and diffusive behaviors of a primitive model of aqueous solutions of hydrophobic solutes consisting of hard spheres in the Jagla particles solvent, close to the liquid-liquid critical point of the solvent. We find that the fragile-to-strong dynamic transition in the diffusive behavior is always coupled to the low-density/high-density liquid transition. Above the liquid-liquid critical pressure, the diffusivity crossover occurs at the Widom line, the line along which the thermodynamic response functions show maxima. Below the liquid-liquid critical pressure, the diffusivity crossover occurs when the limit of mechanical stability lines are crossed, as indicated by the hysteresis observed when going from high to low temperature and vice versa. These findings show that the strong connection between dynamics and thermodynamics found in bulk water persists in hydrophobic solutions for concentrations from low to moderate, indicating that experiments measuring the relaxation time in aqueous solutions represent a viable route for solving the open questions in the field of supercooled water.Comment: 6 pages, 4 figures. Accepted for publication on Physical Review

A Method for the Measurement of Digitizers’ Absolute Phase Error

A lot of engineering applications, from telecommunications to power systems, require accurate measurement of phase angles. Some of them, like synchrophasor measurement and calibration of instrument transformers with digital output, in order to reach high phase measurement accuracy, require the knowledge of phase error of digitizers. Therefore, in this paper a method for the measurement of digitizers’ absolute phase errors is proposed. It adopts a sinewave and two square waves, that are the digitizer sample clock and a phase reference signal. Combining the measurements of the relative phase differences between the adopted signals it is possible to accurately evaluate the absolute phase error of a digitize

Seyfert galaxies with Swift: giant flares, rapid drops, and other surprises

Swift has initiated a new era of understanding the extremes of active galactic nuclei (AGN) variability, their drivers and underlying physics. This is based on its rapid response, high sensitivity, good spatial resolution, and its ability to collect simultaneously X--ray-to-optical SEDs. Here, we present results from our recent monitoring campaigns with Swift of highly variable AGN, including outbursts, deep low states, and unusual long-term trends in several Seyfert galaxies including Mrk 335, WPVS007, and RXJ2314.9+2243. We also report detection of a new X-ray and optical outburst of IC 3599 and our Swift follow-ups. IC 3599 was previously known as one of the AGN with the highest-amplitude outbursts. We briefly discuss implications of this second outburst of IC 3599 for emission scenarios including accretion-disk variability, repeat tidal disruption events, and the presence of a binary supermassive black hole.Comment: to appear in "Swift: 10 years of discovery", Proceedings of Scienc