Non destructive examination of composite structures using dielectric examination

Dielectric measurements are widely used in the laboratory to probe the dynamics of molecules, particularly the dynamics of polymer molecules. The dielectric technique exploits the fact that many molecules, although electrically neutral posses an asymmetric distribution of charges which can be approximated to an electric dipole. The (usually thermal) motion of the molecule can be detected by the interaction of this dipole with a time varying electric field. The great advantage of the technique is that no transducers or sensors are required; the direct application of an electric field produces a directly measurable electric response over a frequency range of MHz to GHz. This paper discusses the practical application of dielectric measurements to composite structures and the information that can be obtained on the state of the polymer in polymer composite matrix materials

Unified first law of black-hole dynamics and relativistic thermodynamics

A unified first law of black-hole dynamics and relativistic thermodynamics is derived in spherically symmetric general relativity. This equation expresses the gradient of the active gravitational energy E according to the Einstein equation, divided into energy-supply and work terms. Projecting the equation along the flow of thermodynamic matter and along the trapping horizon of a blackhole yield, respectively, first laws of relativistic thermodynamics and black-hole dynamics. In the black-hole case, this first law has the same form as the first law of black-hole statics, with static perturbations replaced by the derivative along the horizon. There is the expected term involving the area and surface gravity, where the dynamic surface gravity is defined as in the static case but using the Kodama vector and trapping horizon. This surface gravity vanishes for degenerate trapping horizons and satisfies certain expected inequalities involving the area and energy. In the thermodynamic case, the quasi-local first law has the same form, apart from a relativistic factor, as the classical first law of thermodynamics, involving heat supply and hydrodynamic work, but with E replacing the internal energy. Expanding E in the Newtonian limit shows that it incorporates the Newtonian mass, kinetic energy, gravitational potential energy and thermal energy. There is also a weak type of unified zeroth law: a Gibbs-like definition of thermal equilibrium requires constancy of an effective temperature, generalising the Tolman condition and the particular case of Hawking radiation, while gravithermal equilibrium further requires constancy of surface gravity. Finally, it is suggested that the energy operator of spherically symmetric quantum gravity is determined by the Kodama vector, which encodes a dynamic time related to E.Comment: 18 pages, TeX, expanded somewhat, to appear in Class. Quantum Gra

Interacting with the biomolecular solvent accessible surface via a haptic feedback device

Background: From the 1950s computer based renderings of molecules have been produced to aid researchers in their understanding of biomolecular structure and function. A major consideration for any molecular graphics software is the ability to visualise the three dimensional structure of the molecule. Traditionally, this was accomplished via stereoscopic pairs of images and later realised with three dimensional display technologies. Using a haptic feedback device in combination with molecular graphics has the potential to enhance three dimensional visualisation. Although haptic feedback devices have been used to feel the interaction forces during molecular docking they have not been used explicitly as an aid to visualisation. Results: A haptic rendering application for biomolecular visualisation has been developed that allows the user to gain three-dimensional awareness of the shape of a biomolecule. By using a water molecule as the probe, modelled as an oxygen atom having hard-sphere interactions with the biomolecule, the process of exploration has the further benefit of being able to determine regions on the molecular surface that are accessible to the solvent. This gives insight into how awkward it is for a water molecule to gain access to or escape from channels and cavities, indicating possible entropic bottlenecks. In the case of liver alcohol dehydrogenase bound to the inhibitor SAD, it was found that there is a channel just wide enough for a single water molecule to pass through. Placing the probe coincident with crystallographic water molecules suggests that they are sometimes located within small pockets that provide a sterically stable environment irrespective of hydrogen bonding considerations. Conclusion: By using the software, named HaptiMol ISAS (available from http://​www.​haptimol.​co.​uk), one can explore the accessible surface of biomolecules using a three-dimensional input device to gain insights into the shape and water accessibility of the biomolecular surface that cannot be so easily attained using conventional molecular graphics software

Luttinger liquid behaviour and superconducting correlations in t-J ladders

The low energy behaviour of the isotropic t--J ladder system is investigated using exact diagonalization techniques, specifically finding the Drude weight, the charge velocity and the compressibility. By applying the ideas of Luttinger liquid theory, we determine the correlation exponent $K_\rho$ which defines the behaviour of the long range correlations in the system. The boundary to phase separation is determined and a phase diagram is presented. At low electron density, a Tomonaga-Luttinger-like phase is stabilized whilst at higher electron densities a gapped phase with power law pairing correlations is stabilized: A large region of this gapped phase is found to exhibit dominant superconducting correlations.Comment: 6 pages revtex, 8 figure

Generalized inverse mean curvature flows in spacetime

Motivated by the conjectured Penrose inequality and by the work of Hawking, Geroch, Huisken and Ilmanen in the null and the Riemannian case, we examine necessary conditions on flows of two-surfaces in spacetime under which the Hawking quasilocal mass is monotone. We focus on a subclass of such flows which we call uniformly expanding, which can be considered for null as well as for spacelike directions. In the null case, local existence of the flow is guaranteed. In the spacelike case, the uniformly expanding condition leaves a 1-parameter freedom, but for the whole family, the embedding functions satisfy a forward-backward parabolic system for which local existence does not hold in general. Nevertheless, we have obtained a generalization of the weak (distributional) formulation of this class of flows, generalizing the corresponding step of Huisken and Ilmanen's proof of the Riemannian Penrose inequality.Comment: 21 pages, 1 figur

A Cosmological Constant Limits the Size of Black Holes

In a space-time with cosmological constant $\Lambda>0$ and matter satisfying the dominant energy condition, the area of a black or white hole cannot exceed $4\pi/\Lambda$. This applies to event horizons where defined, i.e. in an asymptotically deSitter space-time, and to outer trapping horizons (cf. apparent horizons) in any space-time. The bound is attained if and only if the horizon is identical to that of the degenerate `Schwarzschild-deSitter' solution. This yields a topological restriction on the event horizon, namely that components whose total area exceeds $4\pi/\Lambda$ cannot merge. We discuss the conjectured isoperimetric inequality and implications for the cosmic censorship conjecture.Comment: 10 page

Optical Conductivity of a t--J Ladder

The optical conductivity $\sigma(\omega )$ of a doped two-leg t--J ladder is calculated for an electric field polarized parallel to the legs of the ladder. The conductivity has a Drude weight proportional to the hole doping and an apparent threshold for absorption (a pseudo gap) which may be associated with the energy to break a pair. This pseudogap in $\sigma (\omega )$ is present even though the pairs have a modified $d_{x^2-y^2}$-like wave function because the geometry of the ladder leads to quasi-particle states which probe the gap along an antinode.Comment: Latex file, figures upon request, submitted in Phys. Rev.

Dilatonic wormholes: construction, operation, maintenance and collapse to black holes

The CGHS two-dimensional dilaton gravity model is generalized to include a ghost Klein-Gordon field, i.e. with negative gravitational coupling. This exotic radiation supports the existence of static traversible wormhole solutions, analogous to Morris-Thorne wormholes. Since the field equations are explicitly integrable, concrete examples can be given of various dynamic wormhole processes, as follows. (i) Static wormholes are constructed by irradiating an initially static black hole with the ghost field. (ii) The operation of a wormhole to transport matter or radiation between the two universes is described, including the back-reaction on the wormhole, which is found to exhibit a type of neutral stability. (iii) It is shown how to maintain an operating wormhole in a static state, or return it to its original state, by turning up the ghost field. (iv) If the ghost field is turned off, either instantaneously or gradually, the wormhole collapses into a black hole.Comment: 9 pages, 7 figure

The Magnetization of Cu_2(C_5H_{12}N_2)_2Cl_4 : A Heisenberg Spin Ladder System

We study the magnetization of a Heisenberg spin ladder using exact diagonalization techniques, finding three distinct magnetic phases. We consider the results in relation to the experimental behaviour of the new copper compound Cu_2(C_5H_{12}N_2)_2Cl_4 and deduce that the compound is well described by such a model with a ratio of `chain' to `rung' bond strengths (J/J^\prime) of the order of 0.2, consistent with results from the magnetic susceptibility. The effects of temperature, spin impurities and additional diagonal bonds are presented and we give evidence that these diagonal bonds are indeed of a ferromagnetic nature.Comment: Latex file (4 pages), related figures (encapsulated postscript) appende