Calcium isotopic composition of high-latitude proxy carrier Neogloboquadrina pachyderma (sin.)

The accurate reconstruction of sea surface temperature (SST) history in climate-sensitive regions (e.g. tropical and polar oceans) became a challenging task in palaeoceanographic research. Biogenic shell carbonate SST proxies successfully developed for tropical regions often fail in cool water environments. Their major regional shortcomings and the cryptic diversity now found within the major high latitude proxy carrier Neogloboquadrina pachyderma (sin.) highlight an urgent need to explore complementary SST proxies for these cool-water regions. Here we incorporate the genetic component into a calibration study of a new SST proxy for the high latitudes. We found that the calcium isotopic composition (δ44/40Ca) of calcite from genotyped net catches and core-top samples of the planktonic foraminifera Neogloboquadrina pachyderma (sin.) is related to temperature and unaffected by genetic variations. The temperature sensitivity has been found to be 0.17 (±0.02)‰ per 1°C, highlighting its potential for downcore applications in open marine cool-water environments. Our results further indicate that in extreme polar environments, below a critical threshold temperature of 2.0 (±0.5)°C associated with salinities below 33.0 (±0.5)‰, a prominent shift in biomineralization affects the δ44/40Ca of genotyped and core-top N. pachyderma (sin.), becoming insensitive to temperature. These findings highlight the need of more systematic calibration studies on single planktonic foraminiferal species in order to unravel species-specific factors influencing the temperature sensitivity of Ca isotope fractionation and to validate the proxies' applicability

Discovery of a stellar companion to the nearby solar-analogue HD 104304

Sun-like stars are promising candidates to host exoplanets and are often included in exoplanet surveys by radial velocity (RV) and direct imaging. In this paper we report on the detection of a stellar companion to the nearby solar-analogue star HD 104304, which previously was considered to host a planetary mass or brown dwarf companion. We searched for close stellar and substellar companions around extrasolar planet host stars with high angular resolution imaging to characterize planet formation environments. The detection of the stellar companion was achieved by high angular resolution measurements, using the "Lucky Imaging" technique at the ESO NTT 3.5m with the AstraLux Sur instrument. We combined the results with VLT/NACO archive data, where the companion could also be detected. The results were compared to precise RV measurements of HD 104304, obtained at the Lick and Keck observatories from 2001-2010. We confirmed common proper motion of the binary system. A spectral type of M4V of the companion and a mass of 0.21 M_Sun was derived. Due to comparison of the data with RV measurements of the unconfirmed planet candidate listed in the Extrasolar Planets Encyclopaedia, we suggest that the discovered companion is the origin of the RV trend and that the inclination of the orbit of approximately 35 degrees explains the relatively small RV signal.Comment: 4 pages, 4 PNG figures, use aa.cls, accepted for publication in Astronomy & Astrophysic

PYRAMIR: Calibration and operation of a pyramid near-infrared wavefront sensor

The concept of pyramid wavefront sensors (PWFS) has been around about a decade by now. However, there is still a great lack of characterizing measurements that allow the best operation of such a system under real life conditions at an astronomical telescope. In this article we, therefore, investigate the behavior and robustness of the pyramid infrared wavefront sensor PYRAMIR mounted at the 3.5 m telescope at the Calar Alto Observatory under the influence of different error sources both intrinsic to the sensor, and arising in the preceding optical system. The intrinsic errors include diffraction effects on the pyramid edges and detector read out noise. The external imperfections consist of a Gaussian profile in the intensity distribution in the pupil plane during calibration, the effect of an optically resolved reference source, and noncommon-path aberrations. We investigated the effect of three differently sized reference sources on the calibration of the PWFS. For the noncommon-path aberrations the quality of the response of the system is quantified in terms of modal cross talk and aliasing. We investigate the special behavior of the system regarding tip-tilt control. From our measurements we derive the method to optimize the calibration procedure and the setup of a PWFS adaptive optics (AO) system. We also calculate the total wavefront error arising from aliasing, modal cross talk, measurement error, and fitting error in order to optimize the number of calibrated modes for on-sky operations. These measurements result in a prediction of on-sky performance for various conditions

Calcium isotopic composition of high-latitude proxy carrier Neogloboquadrina pachyderma (sin.)

International audienceThe accurate reconstruction of sea surface temperature (SST) history in climate-sensitive regions (e.g. tropical and polar oceans) became a challenging task in palaeoceanographic research. However, biogenic shell carbonate SST proxies successfully developed for tropical regions often fail in cool water environments. Their major regional shortcomings and the cryptic diversity now found within the major high latitude proxy carrier Neogloboquadrina pachyderma (sin.) highlight an urgent need to develop complementary SST proxies for these cool water regions. Here we incorporate the genetic component into a calibration study of a new SST proxy for the high latitudes. We found that the calcium isotopic composition (?44/40Ca) of calcite from genotyped net catches and core-top samples of the planktonic foraminifera Neogloboquadrina pachyderma (sin) is strongly related to temperature and unaffected by genetic variations. The temperature sensitivity has been found to be 0.17 (±0.04)? per 1°C highlighting its potential for downcore applications in open marine cool-water environments. Our results further indicate that however in extreme polar environments, below a critical threshold temperature of 2.0 (±0.5)°C and salinity of 33.0 (±0.5)? a prominent shift in biomineralization affect the Ca isotope composition of N. pachyderma (sin.) becoming insensitive to temperature. These findings highlight the need of systematic calibration studies to unravel the influencing factors on Ca isotope fractionation and to validate the proxies' applicability

Mechanism of Hydrogen-Bonded Complex Formation between Ibuprofen and Nanocrystalline Hydroxyapatite.

Nanocrystalline hydroxyapatite (nanoHA) is the main hard component of bone and has the potential to be used to promote osseointegration of implants and to treat bone defects. Here, using active pharmaceutical ingredients (APIs) such as ibuprofen, we report on the prospects of combining nanoHA with biologically active compounds to improve the clinical performance of these treatments. In this study, we designed and investigated the possibility of API attachment to the surface of nanoHA crystals via the formation of a hydrogen-bonded complex. The mechanistic studies of an ibuprofen/nanoHA complex formation have been performed using a holistic approach encompassing spectroscopic (Fourier transform infrared (FTIR) and Raman) and X-ray diffraction techniques, as well as quantum chemistry calculations, while comparing the behavior of the ibuprofen/nanoHA complex with that of a physical mixture of the two components. Whereas ibuprofen exists in dimeric form both in solid and liquid state, our study showed that the formation of the ibuprofen/nanoHA complex most likely occurs via the dissociation of the ibuprofen dimer into monomeric species promoted by ethanol, with subsequent attachment of a monomer to the HA surface. An adsorption mode for this process is proposed; this includes hydrogen bonding of the hydroxyl group of ibuprofen to the hydroxyl group of the apatite, together with the interaction of the ibuprofen carbonyl group to an HA Ca center. Overall, this mechanistic study provides new insights into the molecular interactions between APIs and the surfaces of bioactive inorganic solids and sheds light on the relationship between the noncovalent bonding and drug release properties

Experimental diagenesis: insights into aragonite to calcite transformation of Arctica islandica shells by hydrothermal treatment

Abstract. Biomineralised hard parts form the most important physical fossil record of past environmental conditions. However, living organisms are not in thermodynamic equilibrium with their environment and create local chemical compartments within their bodies where physiologic processes such as biomineralisation take place. In generating their mineralised hard parts, most marine invertebrates produce metastable aragonite rather than the stable polymorph of CaCO3, calcite. After death of the organism the physiological conditions, which were present during biomineralisation, are not sustained any further and the system moves toward inorganic equilibrium with the surrounding inorganic geological system. Thus, during diagenesis the original biogenic structure of aragonitic tissue disappears and is replaced by inorganic structural features

The very red afterglow of GRB 000418 - further evidence for dust extinction in a GRB host galaxy

We report near-infrared and optical follow-up observations of the afterglow of the Gamma-Ray Burst 000418 starting 2.5 days after the occurrence of the burst and extending over nearly seven weeks. GRB 000418 represents the second case for which the afterglow was initially identified by observations in the near-infrared. During the first 10 days its R-band afterglow was well characterized by a single power-law decay with a slope of 0.86. However, at later times the temporal evolution of the afterglow flattens with respect to a simple power-law decay. Attributing this to an underlying host galaxy we find its magnitude to be R=23.9 and an intrinsic afterglow decay slope of 1.22. The afterglow was very red with R-K=4 mag. The observations can be explained by an adiabatic, spherical fireball solution and a heavy reddening due to dust extinction in the host galaxy. This supports the picture that (long) bursts are associated with events in star-forming regions.Comment: Accepted for publication in The Astrophysical Journal. 12 pages; citations & references updated; minor textual change

GRAVITY: getting to the event horizon of Sgr A*

We present the second-generation VLTI instrument GRAVITY, which currently is in the preliminary design phase. GRAVITY is specifically designed to observe highly relativistic motions of matter close to the event horizon of Sgr A*, the massive black hole at center of the Milky Way. We have identified the key design features needed to achieve this goal and present the resulting instrument concept. It includes an integrated optics, 4-telescope, dual feed beam combiner operated in a cryogenic vessel; near infrared wavefront sensing adaptive optics; fringe tracking on secondary sources within the field of view of the VLTI and a novel metrology concept. Simulations show that the planned design matches the scientific needs; in particular that 10 microarcsecond astrometry is feasible for a source with a magnitude of K=15 like Sgr A*, given the availability of suitable phase reference sources.Comment: 13 pages, 11 figures, to appear in the conference proceedings of SPIE Astronomical Instrumentation, 23-28 June 2008, Marseille, Franc

Surface Brightness Fluctuations: A Case for Extremely Large Telescopes

The Surface Brightness Fluctuations (SBF) Method for distance determinations of elliptical galaxies is been modeled in order to investigate the effect of the Point Spread Function (PSF). We developed a method to simulate observations of SBF of galaxies having various properties and located at different distances. We will use this method in order to test the accuracy on the estimates of the extra-galactic distances for PSFs representing typical seeing conditions, Adaptive Optics (AO) systems and for future observations with Extremely Large Telescopes (ELTs) close to the diffraction limit.Comment: 3 pages, 2 figures, to appear in the proceedings of the ESO Workshop "Science with Adaptive Optics", eds. W. Brandner & M. Kasper, Springer-Verlag 200