Cosmological Recombination of Lithium and its Effect on the Microwave Background Anisotropies

The cosmological recombination history of lithium, produced during Big--Bang nucleosynthesis, is presented using updated chemistry and cosmological parameters consistent with recent cosmic microwave background (CMB) measurements. For the popular set of cosmological parameters, about a fifth of the lithium ions recombine into neutral atoms by a redshift $z\sim 400$. The neutral lithium atoms scatter resonantly the CMB at 6708 \AA and distort its intensity and polarization anisotropies at observed wavelengths around $\sim 300 \mu$m, as originally suggested by Loeb (2001). The modified anistropies resulting from the lithium recombination history are calculated for a variety of cosmological models and found to result primarily in a suppression of the power spectrum amplitude. Significant modification of the power spectrum occurs for models which assume a large primordial abundance of lithium. While detection of the lithium signal might prove difficult, if offers the possibility of inferring the lithium primordial abundance and is the only probe proposed to date of the large-scale structure of the Universe for $z\sim 500-100$.Comment: 20 pages, 7 figure

Possible flakes of molecular hydrogen in the early Universe

The thermochemistry of H2 and HD in non-collapsed, non-reionized primordial gas up to the end of the dark age is investigated with recent radiation-matter and chemical reaction rates taking into account the efficient coolant HD, and the possibility of a gas-solid phase transition of H2. In the standard big-bang model we find that these molecules can freeze out and lead to the growth of flakes of solid molecular hydrogen at redshifts z ~ 6-12 in the unperturbed medium and under-dense regions. While this freezing caused by the mere adiabatic cooling of the expanding matter is less likely to occur in collapsed regions due to their higher than radiation background temperature, on the other hand the super-adiabatic expansion in voids strongly favors it. Later reionization (at z ~ 5-6) eventually destroys all these H2 flakes. The possible occurrence of H2 flakes is important for the degree of coupling between matter and radiation, as well as for the existence of a gas-grain chemistry at the end of the dark age.Comment: Accepted for publication to Astronomy and Astrophysic

The Highly Deuterated Chemistry of the Early Universe

A comprehensive chemistry of the highly deuterated species D2, D+ 2, D2H+, and D+ 3 in the early universe is presented. Fractional abundances for each are calculated as a function of redshift z in the recombination era. The abundances of the isotopologues are found to display similar behavior. Fractionation enhances the abundances of most of the more highly deuterated species as the redshift decreases due to the closing of some reaction channels as the gas temperature cools. Rate coefficients for the majority of the reactions involving the deuterated species are uncertain resulting in a corresponding uncertainty in their predicted abundances.Astronom

The Effects of Dark Matter Decay and Annihilation on the High-Redshift 21 cm Background

The radiation background produced by the 21 cm spin-flip transition of neutral hydrogen at high redshifts can be a pristine probe of fundamental physics and cosmology. At z~30-300, the intergalactic medium (IGM) is visible in 21 cm absorption against the cosmic microwave background (CMB), with a strength that depends on the thermal (and ionization) history of the IGM. Here we examine the constraints this background can place on dark matter decay and annihilation, which could heat and ionize the IGM through the production of high-energy particles. Using a simple model for dark matter decay, we show that, if the decay energy is immediately injected into the IGM, the 21 cm background can detect energy injection rates >10^{-24} eV cm^{-3} sec^{-1}. If all the dark matter is subject to decay, this allows us to constrain dark matter lifetimes <10^{27} sec. Such energy injection rates are much smaller than those typically probed by the CMB power spectra. The expected brightness temperature fluctuations at z~50 are a fraction of a mK and can vary from the standard calculation by up to an order of magnitude, although the difference can be significantly smaller if some of the decay products free stream to lower redshifts. For self-annihilating dark matter, the fluctuation amplitude can differ by a factor <2 from the standard calculation at z~50. Note also that, in contrast to the CMB, the 21 cm probe is sensitive to both the ionization fraction and the IGM temperature, in principle allowing better constraints on the decay process and heating history. We also show that strong IGM heating and ionization can lead to an enhanced H_2 abundance, which may affect the earliest generations of stars and galaxies.Comment: submitted to Phys Rev D, 14 pages, 8 figure

Detection of Emission from the CN Radical in the Cloverleaf Quasar at z=2.56

We report the detection of CN(N=3-2) emission towards the Cloverleaf quasar (z=2.56) based on observations with the IRAM Plateau de Bure Interferometer. This is the first clear detection of emission from this radical at high redshift. CN emission is a tracer of dense molecular hydrogen gas (n(H2) > 10^4 cm^{-3}) within star-forming molecular clouds, in particular in regions where the clouds are affected by UV radiation. The HCN/CN intensity ratio can be used as a diagnostic for the relative importance of photodissociation regions (PDRs) in a source, and as a sensitive probe of optical depth, the radiation field, and photochemical processes. We derive a lensing-corrected CN(N=3-2) line luminosity of L'(CN(3-2) = (4.5 +/- 0.5) x 10^9 K km/s pc^2. The ratio between CN luminosity and far-infrared luminosity falls within the scatter of the same relationship found for low-z (ultra-) luminous infrared galaxies. Combining our new results with CO(J=3-2) and HCN(J=1-0) measurements from the literature and assuming thermal excitation for all transitions, we find a CO/CN luminosity ratio of 9.3 +/- 1.9 and a HCN/CN luminosity ratio of 0.95 +/- 0.15. However, we find that the CN(N=3-2) line is likely only subthermally excited, implying that those ratios may only provide upper limits for the intrinsic 1-0 line luminosity ratios. We conclude that, in combination with other molecular gas tracers like CO, HCN, and HCO+, CN is an important probe of the physical conditions and chemical composition of dense molecular environments at high redshift.Comment: 6 pages, 5 figures, 1 table, to appear in ApJ (accepted May 23, 2007

Molecular fluorine chemistry in the early Universe

Some models of Big Bang nucleosynthesis suggest that very high baryon density regions were formed in the early Universe, and generated the production of heavy elements other than lithium such as fluorine F. We present a comprehensive chemistry of fluorine in the post-recombination epoch. Calculation of F, F- and HF abundances, as a function of redshift z, are carried out. The main result is that the chemical conditions in the early Universe can lead to the formation of HF. The final abundance of the diatomic molecule HF is predicted to be close to 3.75 10(-17) when the initial abundance of neutral fluorine F is 10(-15). These results indicate that molecules of fluorine HF were already present during the dark age. This could have implications on the evolution of proto-objects and on the anisotropies of cosmic microwave background radiation. Hydride of fluorine HF may affect enhancement of the emission line intensity from the proto-objects and could produce spectral-spatial fluctuations.Comment: Accepted in Astronomy and Astrophysics, 7 pages, 2 figure

Chemical Modelling of Young Stellar Objects, I. Method and Benchmarks

Upcoming facilities such as the Herschel Space Observatory or ALMA will deliver a wealth of molecular line observations of young stellar objects (YSOs). Based on line fluxes, chemical abundances can then be estimated by radiative transfer calculations. To derive physical properties from abundances, the chemical network needs to be modeled and fitted to the observations. This modeling process is however computationally exceedingly demanding, particularly if in addition to density and temperature, far UV (FUV) irradiation, X-rays, and multi-dimensional geometry have to be considered. We develop a fast tool, suitable for various applications of chemical modeling in YSOs. A grid of the chemical composition of the gas having a density, temperature, FUV irradiation and X-ray flux is pre-calculated as a function of time. A specific interpolation approach is developed to reduce the database to a feasible size. Published models of AFGL 2591 are used to verify the accuracy of the method. A second benchmark test is carried out for FUV sensitive molecules. The novel method for chemical modeling is more than 250,000 times faster than direct modeling and agrees within a mean factor of 1.35. The tool is distributed for public use. In the course of devloping the method, the chemical evolution is explored: We find that X-ray chemistry in envelopes of YSOs can be reproduced by means of an enhanced cosmic-ray ionization rate. We further find that the abundance of CH+ in low-density gas with high ionization can be enhanced by the recombination of doubly ionized carbon (C++) and suggest a new value for the initial abundance of the main sulphur carrier in the hot-core.Comment: Accepted by ApJS. 24 pages, 15 figures. A version with higher resolution images is available from http://www.astro.phys.ethz.ch/staff/simonbr/papgridI.pdf . Online data available at http://www.astro.phys.ethz.ch/chemgrid.html . Second paper of this series of papers available at arXiv:0906.058

Rovibrationally resolved photodissociation of HeH+

Accurate photodissociation cross sections have been obtained for the A-X electronic transition of HeH+ using ab initio potential curves and dipole transition moments. Partial cross sections have been evaluated for all rotational transitions from the vibrational levels v"=0-11 and over the entire accessible wavelength range 100-1129 Angstrom. Assuming a Boltzmann distribution of the rovibrational levels of the X state, photodissociation cross sections are presented for temperatures between 500 and 12,000 K. A similar set of calculations was performed for the pure rovibrational photodissociation in the X-X electronic ground state, but covering photon wavelengths into the far infrared. Applications of the cross sections to the destruction of HeH+in the early Universe and in UV-irradiated environments such as primordial halos and protoplanetary disks are briefly discussed

Ion chemistry in the early universe: revisiting the role of HeH+ with new quantum calculations

The role of HeH+ has been newly assessed with the aid of newly calculated rates which use entirely ab initio methods, thereby allowing us to compute more accurately the relevant abundances within the global chemical network of the early universe. A comparison with the similar role of the ionic molecule LiH+ is also presented. Quantum calculations have been carried out for the gas-phase reaction of HeH+ with H atoms with our new in-house code, based on the negative imaginary potential method. Integral cross sections and reactive rate coefficients obtained under the general conditions of early universe chemistry are presented and discussed. With the new reaction rate, the abundance of HeH+ in the early universe is more than one order of magnitude larger than in previous studies. Our more accurate findings further buttress the possibility to detect cosmological signatures of HeH+.Comment: Astronomy and Astrophysics, in pres

Molecular Tracers of Filamentary CO Emission Regions Surrounding the Central Galaxies of Clusters

Optical emission is detected from filaments around the central galaxies of clusters of galaxies. These filaments have lengths of tens of kiloparsecs. The emission is possibly due to heating caused by the dissipation of mechanical energy and by cosmic ray induced ionisation. CO millimeter and submillimeter line emissions as well as H$_{2}$ infrared emission originating in such filaments surrounding NGC~1275, the central galaxy of the Perseus cluster, have been detected. Our aim is to identify those molecular species, other than CO, that may emit detectable millimeter and submillimeter line features arising in these filaments, and to determine which of those species will produce emissions that might serve as diagnostics of the dissipation and cosmic ray induced ionisation. The time-dependent UCL photon-dominated region modelling code was used in the construction of steady-state models of molecular filamentary emission regions at appropriate pressures, for a range of dissipation and cosmic ray induced ionisation rates and incident radiation fields.HCO$^+$ and C$_2$H emissions will potentially provide information about the cosmic ray induced ionisation rates in the filaments. HCN and, in particular, CN are species with millimeter and submillimeter lines that remain abundant in the warmest regions containing molecules. Detections of the galaxy cluster filaments in HCO$^{+}$, C$_{2}$H, and CN emissions and further detections of them in HCN emissions would provide significant constraints on the dissipation and cosmic ray induced ionisation rates.Comment: 11 pages, 3 figures, 3 tables, accepted in A&