Growth of CuCl thin films by magnetron sputtering for ultraviolet optoelectronic applications

Copper (I) chloride (CuCl) is a potential candidate for ultraviolet (UV) optoelectronics due to its close lattice match with Si (mismatch less than 0.4%) and a high UV excitonic emission at room temperature. CuCl thin films were deposited using radio frequency magnetron sputtering technique. The influence of target to substrate distance (dts) and sputtering pressure on the composition, microstructure, and UV emission properties of the films were analyzed. The films deposited with shorter target to substrate spacing (dts=3 cm) were found to be nonstoichiometric, and the film stoichiometry improves when the substrate is moved away from the target (dts=4.5 and 6 cm). A further increase in the spacing results in poor crystalline quality. The grain interface area increases when the sputtering pressure is increased from 1.1×10–³ to 1×10–² mbar at dts=6 cm. Room temperature cathodoluminescence spectrum shows an intense and sharp UV exciton (Z₃) emission at ~385 nm with a full width at half maximum of 16 nm for the films deposited at the optimum dts of 6 cm and a pressure of 1.1×10–³ mbar. A broad deep level emission in the green region (~515 nm) is also observed. The relative intensity of the UV to green emission peaks decreased when the sputtering pressure was increased, consistent with an increase in grain boundary area. The variation in the stoichiometry and the crystallinity are attributed to the change in the intensity and energy of the flux of materials from the target due to the interaction with the background gas molecules

Calculation and comparison of heat transfer coefficient & heat flux by varying the parameters for SCWR through CFD simulations

In the present study, CFD simulation was conducted for 2•2 rod bare bundle using water at supercritical pressures. Main objective of the simulation was to compare working of different turbulence models. K-epsilon, K-omega and Spalart-Allmaras turbulence models were chosen for our study. K-epsilon and K-omega turbulence models are two equation models and are widely used for industrial research. Whereas Spalart-Allmaras is one equation model which is least computationally expensive of all the models. All three turbulence models come under the Reynolds Average Navier Strokes model (RANS). CFD results were found to be sensitive with the appropriate turbulence model and this variation is documented through various plots

Electron power absorption dynamics in capacitive radio frequency discharges driven by tailored voltage waveforms in CF4

The power absorption dynamics of electrons and the electrical asymmetry effect in capacitive radio-frequency plasmas operated in CF4 and driven by tailored voltage waveforms are investigated experimentally in combination with kinetic simulations. The driving voltage waveforms are generated as a superposition of multiple consecutive harmonics of the fundamental frequency of 13.56 MHz. Peaks/valleys and sawtooth waveforms are used to study the effects of amplitude and slope asymmetries of the driving voltage waveform on the electron dynamics and the generation of a DC self-bias in an electronegative plasma at different pressures. Compared to electropositive discharges, we observe strongly different effects and unique power absorption dynamics. At high pressures and high electronegativities, the discharge is found to operate in the drift-ambipolar (DA) heating mode. A dominant excitation/ionization maximum is observed during sheath collapse at the edge of the sheath which collapses fastest. High negative-ion densities are observed inside this sheath region, while electrons are confined for part of the RF period in a potential well formed by the ambipolar electric field at this sheath edge and the collapsed (floating potential) sheath at the electrode. For specific driving voltage waveforms, the plasma becomes divided spatially into two different halves of strongly different electronegativity. This asymmetry can be reversed electrically by inverting the driving waveform. For sawtooth waveforms, the discharge asymmetry and the sign of the DC self-bias are found to reverse as the pressure is increased, due to a transition of the electron heating mode from the α-mode to the DA-mode. These effects are interpreted with the aid of the simulation results

Oral abstracts of the 21st International AIDS Conference 18-22 July 2016, Durban, South Africa

The rate at which HIV-1 infected individuals progress to AIDS is highly variable and impacted by T cell immunity. CD8 T cell inhibitory molecules are up-regulated in HIV-1 infection and associate with immune dysfunction. We evaluated participants (n=122) recruited to the SPARTAC randomised clinical trial to determine whether CD8 T cell exhaustion markers PD-1, Lag-3 and Tim-3 were associated with immune activation and disease progression.Expression of PD-1, Tim-3, Lag-3 and CD38 on CD8 T cells from the closest pre-therapy time-point to seroconversion was measured by flow cytometry, and correlated with surrogate markers of HIV-1 disease (HIV-1 plasma viral load (pVL) and CD4 T cell count) and the trial endpoint (time to CD4 count <350 cells/μl or initiation of antiretroviral therapy). To explore the functional significance of these markers, co-expression of Eomes, T-bet and CD39 was assessed.Expression of PD-1 on CD8 and CD38 CD8 T cells correlated with pVL and CD4 count at baseline, and predicted time to the trial endpoint. Lag-3 expression was associated with pVL but not CD4 count. For all exhaustion markers, expression of CD38 on CD8 T cells increased the strength of associations. In Cox models, progression to the trial endpoint was most marked for PD-1/CD38 co-expressing cells, with evidence for a stronger effect within 12 weeks from confirmed diagnosis of PHI. The effect of PD-1 and Lag-3 expression on CD8 T cells retained statistical significance in Cox proportional hazards models including antiretroviral therapy and CD4 count, but not pVL as co-variants.Expression of ‘exhaustion’ or ‘immune checkpoint’ markers in early HIV-1 infection is associated with clinical progression and is impacted by immune activation and the duration of infection. New markers to identify exhausted T cells and novel interventions to reverse exhaustion may inform the development of novel immunotherapeutic approaches

Biosorption of Mn (II), Co (II) and Cr (VI) in a horizontal rotating tubular bioreactor: experiments and evaluation of the integral bioprocess model

In this research, a multi heavy metals removal process with mixed microbial culture was examined in a horizontal rotating tubular bioreactor (HRTB) with different combinations of process parameters. Three metals were selected as examples of cations (manganese and cobalt) and oxy-anion (hexavalent chromium). Hydrodynamic conditions and biomass sorption capacity in the HRTB had the main impact on the heavy metals removal efficiencies, which were for Mn2+ 87.0-93.6%, Co2+ 89.0-95.7% and Cr6+ 99.7-100%, respectively. For the bioprocess description in the HRTB, the integral bioprocess model that combines hydrodynamics, mass transfer and kinetics was used. This model was evaluated for the new experimental conditions and average variances between experimental and simulated data were in the range of 0.12 - 3.21·10-3. The results obtained clearly show that the integral bioprocess model is able to describe the heavy metal removal process in the HRTB