Asteroid team

The purpose of this task is to support asteroid research and the operation of an Asteroid Team within the Earth and Space Sciences Division at the Jet Propulsion Laboratory (JPL). The Asteroid Team carries out original research on asteroids in order to discover, better characterize and define asteroid properties. This information is needed for the planning and design of NASA asteroid flyby and rendezvous missions. The asteroid Team also provides scientific and technical advice to NASA and JPL on asteroid related programs. Work on asteroid classification continued and the discovery of two Earth-approaching M asteroids was published. In the asteroid photometry program researchers obtained N or Q photometry for more than 50 asteroids, including the two M-earth-crossers. Compositional analysis of infrared spectra (0.8 to 2.6 micrometer) of asteroids is continuing. Over the next year the work on asteroid classification and composition will continue with the analysis of the 60 reduced infrared spectra which we now have at hand. The radiometry program will continue with the reduction of the N and Q bandpass data for the 57 asteroids in order to obtain albedos and diameters. This year the emphasis will shift to IRAS follow-up observations; which includes objects not observed by IRAS and objects with poor or peculiar IRAS data. As in previous year, we plan to give top priority to any opportunities for observing near-Earth asteroids and the support (through radiometric lightcurve observations from the IRTF) of any stellar occultations by asteroids for which occultation observation expeditions are fielded. Support of preparing of IRAS data for publication and of D. Matson for his participation in the NASA Planetary Astronomy Management and Operations Working Group will continue

Applications of HCMM data to soil moisture snow and estuarine current studies

There are no author-identified significant results in this report

Applications of HCMM data to soil moisture snow and estuarine current studies

There are no author-identified significant results in this report

Selected Hydrologic Applications of LANDSAT-2 Data: an Evaluation

The author has identified the following significant results. Estimates of soil moisture were obtained from visible, near-IR gamma ray and microwave data. Attempts using GOES thermal-IR were unsuccessful due to resolutions (8 km). Microwaves were the most effective at soil moisture estimates, with and without vegetative cover. Gamma rays provided only one value for the test site, produced by many data points obtained from overlapping 150 meter diameter circles. Even though the resulting averaged value was near the averaged field moisture value, this method suffers from atmospheric contaminants, the need to fly at low altitudes, and the necessity of prior calibration of a given site. Visible and near-IR relationships are present for bare fields but appear to be limited to soil moisture levels between 5 and 20%. The densely vegetated alfalfa fields correlated with near-IR reflectance only; soil moisture values from wheat fields showed no relation to either or near-IR MSS data

Infrared observations of asteroids from earth and space

Infrared reflectances at wavelength between 1 and 4 micrometers are used for determining asteroid surface mineralogy, surface composition, diameters, and albedos. Thermal models were developed for analyzing infrared observations at longer wavelengths. The discovery of a spectral feature due to water of hydration on Ceres seems to contradict the mineralogy inferred from spectrophotometry

Evaluation of LANDSAT-2 data for selected hydrologic applications

There are no author-identified significant results in this report

Application of HCMM data to soil moisture snow and estuarine current studies

There are no author-identified significant results in this report

High Resolution Spectrometry of Leaf and Canopy Chemistry for Biochemical Cycling

High-resolution laboratory spectrophotometer and Airborne Imaging Spectrometer (AIS) data were used to analyze forest leaf and canopy chemistry. Fundamental stretching frequencies of organic bonds in the visible, near infrared and short-wave infrared are indicative of concentrations and total content of nitrogen, phosphorous, starch and sugar. Laboratory spectrophotometer measurements showed very strong negative correlations with nitrogen (measured using wet chemistry) in the visible wavelengths. Strong correlations with green wet canopy weight in the atmospheric water absorption windows were observed in the AIS data. A fairly strong negative correlation between the AIS data at 1500 nm and total nitrogen and nitrogen concentration was evident. This relationship corresponds very closely to protein absorption features near 1500 nm

IRAS asteroid families

The Infrared Astronomical Satellite (IRAS) sampled the entire asteroid population at wavelengths from 12 to 100 microns during its 1983 all sky survey. The IRAS Minor Planet Survey (IMPS) includes updated results for more recently numbered as well as other additional asteroids with reliable orbital elements. Albedos and diameters were derived from the observed thermal emission and assumed absolute visual magnitudes and then entered into the IMPS database at the Infrared Processing and Analysis Center (IPAC) for members of the Themis, Eos, Koronis and Maria asteroid families and compared with their visual colors. The IMPS results for the small (down to about 20 km) asteroids within these major families confirm trends previously noted for their larger members. Each of these dynamical families which are defined by their similar proper elements appears to have homogeneous physical properties

Fe-mediated HER vs N_2RR: Exploring Factors that Contribute to Selectivity in P_3^EFe(N_2) (E = B, Si, C) Catalyst Model Systems

Mitigation of the hydrogen evolution reaction (HER) is a key challenge in selective small molecule reduction catalysis. This is especially true of catalytic nitrogen (N_2) and carbon dioxide (CO_2) reduction reactions (N_2RR and CO_2RR, respectively) using H^+/e• currency. Here we explore, via DFT calculations, three iron model systems, P_3^EFe (E = B, Si, C), known to mediate both N_2RR and HER, but with different selectivity depending on the identity of the auxiliary ligand. It is suggested that the respective efficiencies of these systems for N_2RR trend with the predicted N–H bonds strengths of two putative hydrazido intermediates of the proposed catalytic cycle, P_3^EFe(NNH_2)^+ and P_3^EFe(NNH_2). Further, a mechanism is presented for undesired HER consistent with DFT studies, and previously reported experimental data, for these systems; bimolecular proton-coupled-electron-transfer (PCET) from intermediates with weak N–H bonds is posited as an important source of H_2, instead of more traditional scenarios that proceed via metal hydride intermediates and proton transfer/electron transfer (PT/ET) pathways. Wiberg bond indices provide additional insight into key factors related to the degree of stabilization of P_3^EFe(NNH_2) species, factors that trend with overall product selectivity