316 research outputs found

    First-year sea-ice contact predicts bromine monoxide (BrO) levels at Barrow, Alaska better than potential frost flower contact

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    International audienceReactive halogens are responsible for boundary-layer ozone depletion and mercury deposition in Polar Regions during springtime. To investigate the source of reactive halogens in the air arriving at Barrow, Alaska, we measured BrO, an indicator of reactive halogen chemistry, and correlated its abundance with airmass histories derived from meteorological back trajectories and remotely sensed sea ice properties. The BrO abundance is found to be positively correlated to first-year sea-ice contact (R2=0.55), and essentially uncorrelated with potential frost flower (PFF) contact (R2=0.04). Assuming that PFF accurately predicts frost flowers, these data indicate that snow and ice contaminated with sea salts on first-year sea ice is a more probable bromine source than are frost flowers, for airmasses impacting Barrow, Alaska. Climate-driven changes in Arctic sea ice are likely to alter frost flower and first year sea ice prevalence. An accurate understanding of how these sea ice changes would affect the halogen chemistry of the overlying atmosphere depends upon understanding the relative roles of frost flowers and saline snow and ice surfaces as reactive bromine sources

    Gas diffusion through columnar laboratory sea ice: implications for mixed-layer ventilation of CO<sub>2</sub> in the seasonal ice zone

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    Gas diffusion through the porous microstructure of sea ice represents a pathway for ocean–atmosphere exchange and for transport of biogenic gases produced within sea ice. We report on the experimental determination of the bulk gas diffusion coefficients, D, for oxygen (O2) and sulphur hexafluoride (SF6) through columnar sea ice under constant ice thickness conditions for ice surface temperatures between -4 and -12 °C. Profiles of SF6 through the ice indicate decreasing gas concentration from the ice/water interface to the ice/air interface, with evidence for solubility partitioning between gas-filled and liquid-filled pore spaces. On average, DSF6 inline image was 1.3 × 10-4 cm2 s-1 (±40%) and DO2 was 3.9 × 10-5 cm2 s-1 (±41%). The preferential partitioning of SF6 to the gas phase, which is the dominant diffusion pathway produced the greater rate of SF6 diffusion. Comparing these estimates of D with an existing estimate of the air–sea gas transfer through leads indicates that ventilation of the mixed layer by diffusion through sea ice may be negligible, compared to air–sea gas exchange through fractures in the ice pack, even when the fraction of open water is less than 1%

    Melt pond fraction and spectral sea ice albedo retrieval from MERIS data – Part 1: Validation against in situ, aerial, and ship cruise data

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    The presence of melt ponds on the Arctic sea ice strongly affects the energy balance of the Arctic Ocean in summer. It affects albedo as well as transmittance through the sea ice, which has consequences for the heat balance and mass balance of sea ice. An algorithm to retrieve melt pond fraction and sea ice albedo from Medium Resolution Imaging Spectrometer (MERIS) data is validated against aerial, shipborne and in situ campaign data. The results show the best correlation for landfast and multiyear ice of high ice concentrations. For broadband albedo, R2 is equal to 0.85, with the RMS (root mean square) being equal to 0.068; for the melt pond fraction, R2 is equal to 0.36, with the RMS being equal to 0.065. The correlation for lower ice concentrations, subpixel ice floes, blue ice and wet ice is lower due to ice drift and challenging for the retrieval surface conditions. Combining all aerial observations gives a mean albedo RMS of 0.089 and a mean melt pond fraction RMS of 0.22. The in situ melt pond fraction correlation is R2 = 0.52 with an RMS = 0.14. Ship cruise data might be affected by documentation of varying accuracy within the Antarctic Sea Ice Processes and Climate (ASPeCt) protocol, which may contribute to the discrepancy between the satellite value and the observed value: mean R2 = 0.044, mean RMS = 0.16. An additional dynamic spatial cloud filter for MERIS over snow and ice has been developed to assist with the validation on swath data

    Arctic system on trajectory to new state

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    The Arctic system is moving toward a new state that falls outside the envelope of glacial-interglacial fluctuations that prevailed during recent Earth history. This future Arctic is likely to have dramatically less permanent ice than exists at present. At the present rate of change, a summer ice-free Arctic Ocean within a century is a real possibility, a state not witnessed for at least a million years. The change appears to be driven largely by feedback-enhanced global climate warming, and there seem to be few, if any processes or feedbacks within the Arctic system that are capable of altering the trajectory toward this “super interglacial” state

    Warm‐air advection, air mass transformation and fog causes rapid ice melt

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    Direct observations during intense warm-air advection over the East Siberian Sea reveal a period of rapid sea-ice melt. A semi-stationary, high-pressure system north of the Bering Strait forced northward advection of warm, moist air from the continent. Air-mass transfor-mation over melting sea ice formed a strong, surface-based temperature inversion in which dense fog formed. This induced a positive net longwave radiation at the surface, while reduc-ing net solar radiation only marginally; the inversion also resulted in downward turbulent heat flux. The sum of these processes enhanced the surface energy flux by an average of ~15 W m-2 for a week. Satellite images before and after the episode show sea-ice concentrations decreasing from > 90% to ~50% over a large area affected by the air-mass transformation. We argue that this rapid melt was triggered by the increased heat flux from the atmosphere due to the warm-air advection

    Sunlight, clouds, sea ice, albedo, and the radiative budget: the umbrella versus the blanket

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    The surface radiation budget of the Arctic Ocean plays a central role in summer ice melt and is governed by clouds and surface albedo. I calculated the net radiation flux for a range of albedos under sunny and cloudy skies and determined the break-even value, where the net radiation is the same for cloudy and sunny skies. Break-even albedos range from 0.30 in September to 0.58 in July. For snow-covered or bare ice, sunny skies always result in less radiative heat input. In contrast, leads always have, and ponds usually have, more radiative input under sunny skies than cloudy skies. Snow-covered ice has a net radiation flux that is negative or near zero under sunny skies, resulting in radiative cooling. Areally averaged albedos for sea ice in July result in a smaller net radiation flux under cloudy skies. For May, June, August, and September, the net radiation is smaller under sunny skies
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