Soot formation and burnout in flames

The amount of soot formed when burning a benzene/hexane mixture in a turbulent combustor was examined. Soot concentration profiles in the same combustor for kerosene fuel are given. The chemistry of the formation of soot precursors, the nucleation, growth and subsequent burnout of soot particles, and the effect of mixing on the previous steps were considered

Periodic orbit bifurcations and scattering time delay fluctuations

We study fluctuations of the Wigner time delay for open (scattering) systems which exhibit mixed dynamics in the classical limit. It is shown that in the semiclassical limit the time delay fluctuations have a distribution that differs markedly from those which describe fully chaotic (or strongly disordered) systems: their moments have a power law dependence on a semiclassical parameter, with exponents that are rational fractions. These exponents are obtained from bifurcating periodic orbits trapped in the system. They are universal in situations where sufficiently long orbits contribute. We illustrate the influence of bifurcations on the time delay numerically using an open quantum map.Comment: 9 pages, 3 figures, contribution to QMC200

Superscars in the LiNC=LiCN isomerization reaction

We demonstrate the existence of superscarring in the LiNC=LiCN isomerization reaction described by a realistic potential interaction in the range of readily attainable experimental energies. This phenomenon arises as the effect of two periodic orbits appearing "out of the blue"in a saddle--node bifurcation taking place in the dynamics of the system. Potential practical consequences of this superlocalization in the corresponding wave functions are also considered.Comment: 6 pages, 5 figures. to appear in EP

Texture Evolution of AZ31 Magnesium Alloy Sheet at High Strain Rates

In the current contribution the mechanical behaviour at high strain rates of AZ31 magnesium alloy sheet is studied. Uniaxial deformation properties were studied by means of tensile split Hopkinson pressure bar (SHPB) at different temperatures. The influence of the strain rate and temperature on the deformation mechanisms was investigated by means of electron backscatter diffraction (EBSD) and neutron diffraction. It is shown that twinning plays an important role on high strain rate deformation of this alloy, even at elevated temperatures. Significant evidence of prismatic slip as a deformation mechanism is observed, also at warm temperatures, leading to the alignment of directions with the tensile axis and to a spread of the intensities of the basal pole figure towards the in-plane direction perpendicular to the tensile axis. The rate of decrease of the CRSS of non-basal systems is observed to be slower than at quasi-static rates. Secondary twinning and pyramidal slip were also outlined for some conditions. At warm temperatures, in contrast to quasi-static range, a generalized dynamic recrystallization is not observed. Moreover, the activation of rotational recrystallization mechanisms is reporte

Potencial de uso de métricas de paisagem para relacionar a dinâmica de uso da terra com a qualidade da água: estudo de caso na região serrana do Estado do Rio de Janeiro.

A configuração de uma paisagem está relacionada à dinâmica do uso e cobertura da terra na qual ela se insere. Este fato afeta diretamente a sua estrutura e confere padrões espaciais aos fragmentos florestais, bem como aos usos predominantes da terra de uma determinada região. Essa configuração espacial reflete tanto nos processos naturais como a qualidade da água, quanto nos aspectos socioeconômicos associados. Por isso, faz-se necessário o entendimento dessa distribuição espacial; o que pode ser obtido a partir do cálculo de métricas de paisagem. No presente trabalho foram analisadas 16 métricas de paisagem em uma bacia de drenagem na região montanhosa do Rio de Janeiro, denominada Pito Aceso - afluente do Rio Grande, que por sua vez é afluente do Rio Paraíba do Sul. Posteriormente aos cálculos das métricas, foi realizada uma análise por componentes principais onde foi possível observar as métricas que se mostraram mais eficientes para evidenciar a estrutura da paisagem em análise. Como estudos da qualidade da água também foram realizados na bacia, a próxima etapa do trabalho será associar esses resultados aos resultados de qualidade da água, de forma a demonstrar a potencialidade do uso dessas análises para subsidiar o planejamento sustentável das paisagens bem como dos recursos hídricos

Semiclassical structure of chaotic resonance eigenfunctions

We study the resonance (or Gamow) eigenstates of open chaotic systems in the semiclassical limit, distinguishing between left and right eigenstates of the non-unitary quantum propagator, and also between short-lived and long-lived states. The long-lived left (right) eigenstates are shown to concentrate as $\hbar\to 0$ on the forward (backward) trapped set of the classical dynamics. The limit of a sequence of eigenstates $\{\psi(\hbar)\}_{\hbar\to 0}$ is found to exhibit a remarkably rich structure in phase space that depends on the corresponding limiting decay rate. These results are illustrated for the open baker map, for which the probability density in position space is observed to have self-similarity properties.Comment: 4 pages, 4 figures; some minor corrections, some changes in presentatio

Twinning and grain subdivision during dynamic deformation of a Mg AZ31 sheet alloy at room temperature

The microstructural evolution of an AZ31 rolled sheet during dynamic deformation at strain rates of ∼103 s−1 has been investigated by electron backscatter diffraction, X-ray and neutron diffraction. The influence of orientation on the predominant deformation mechanisms and on the recovery processes taking place during deformation has been systematically examined. The results have been compared with those corresponding to the same alloy tested quasi-statically under equivalent conditions. It has been found that strain rate enhances the activation of extension twinning dramatically, while contraction and secondary twinning are not significantly influenced. The polarity of extension twinning is even reversed in some grains under selected testing conditions. Significant grain subdivision by the formation of geometrically necessary boundaries (GNBs) takes place during both quasi-static and dynamic deformation of this AZ31 alloy. It is remarkable that GNBs of high misorientations form even at the highest strain rates. The phenomenon of recovery has been found to be orientation dependen