Pulsar Scintillation and the Local Bubble

We present here the results from an extensive scintillation study of twenty pulsars in the dispersion measure (DM) range 3 - 35 pc cm^-3 caried out using the Ooty Radio Telescope (ORT) at 327 MHz, to investigate the distribution of ionized material in the local interstellar medium. Observations were made during the period January 1993 to August 1995, in which the dynamic scintillation spectra of these pulsars were regularly monitored over 10 - 90 epochs spanning 100 days. Reliable and accurate estimates of strengths of scattering have been deduced from the scintillation parameters averaged out for their long-term fluctuations arising from refractive scintillation (RISS) effects. Our analysis reveals several anomalies in the scattering strength, which suggest tht the distribution of scattering material in the Solar neighborhood is not uniform. We have modelled these anomalous scattering effects in terms of inhomogeneities in the distribution of electron dnsity fluctuations in the local interstellar medium (LISM). Our model suggests the presence of a low density bubble surrounded by a shell of much higher density fluctuations. We are able to put constraints on geometrical and scattering properties of such a structure, and find it to be morphologically similar to the Local Bubble known from other studies.Comment: 35 pages, 12 figure

Long-Term Scintillation Studies of Pulsars: III. Testing Theoretical Models of Refractive Scintillation

Refractive interstellar scintillation (RISS) is thought to be the cause behind a variety of phenomena seen at radio wavelengths in pulsars and compact radio sources. Though there is substantial observational data to support several consequences of it, the quantitative predictions from theories have not been thoroughly tested. In this paper, data from our long-term scintillation study of 18 pulsars are used to test the predictions. The fluctuations of decorrelation bandwidth ($\nu_d$), scintillation time scale ($\tau_d$) and flux density (F) are examined for their cross-correlations and compared with the predictions. The theory predicts a strong correlation between $\nu_d$ and $\tau_d$, and strong anti-correlations between $\nu_d$ and F, and $\tau_d$ and F. For 5 pulsars, we see a reasonable agreement. There is considerable difficulty in reconciling the results for the rest of the pulsars. Our analysis shows the underlying noise sources can sometimes reduce the correlation, but cannot cause an absence of correlation. It is also unlikely that the poor flux correlations arise from a hitherto unrecognized intrinsic flux variations. For PSR B0834+06, which shows anomalous behaviour of persistent drift slopes, positive correlation is found between $\tau_d$ and the drift-corrected $\nu_d$. Many pulsars show an anti-correlation between $\nu_d$ and the drift slope, and this is in accordance with the simple models of RISS. The detections of correlated variations of observables and a reasonable agreement between the predicted and measured correlations for some pulsars confirm RISS as the primary cause of the observed fluctuations. However, the complexity seen with the detailed results suggests the necessity of more comprehensive theoretical treatments for describing refractive fluctuations and their correlations.Comment: 27 pages, 6 Figures, 6 Tables. Accepted for publication in The Astrophysical Journa

Solvophobic and solvophilic contributions in the water-to-aqueous guanidinium chloride transfer free energy of model peptides

We study the solvation free energy of two different conformations (helix and extended) of two different peptides (deca-alanine and deca-glycine) in two different solvents (water and aqueous guanidinium chloride, GdmCl). The free energies are obtained using the quasichemical organization of the potential distribution theorem, an approach that naturally provides the repulsive (solvophobic or cavity) and attractive (solvophilic) contributions to solvation. The solvophilic contribution is further parsed into a chemistry contribution arising from solute interaction with the solvent in the first solvation shell and a long-range contribution arising from non-specific interactions between the solute and the solvent beyond the first solvation shell. The cavity contribution is obtained for two different envelopes, $\Sigma_{SE}$ which theory identifies as the solvent excluded volume and a larger envelope ($\Sigma_G$) beyond which solute-solvent interactions are Gaussian. For both envelopes, the cavity contribution in water is proportional to the surface area of the envelope. The same does not hold for GdmCl(aq), revealing limitations of using molecular area to assess solvation energetics, especially in mixed solvents. The $\Sigma_G$-cavity contribution predicts that GdmCl(aq) should favor the more compact state, contrary to the role of GdmCl in unfolding proteins. The chemistry contribution attenuates this effect, but still the net local (chemistry plus $\Sigma_G$-packing) contribution is inadequate in capturing the role of GdmCl. With the inclusion of the long-range contribution, which is dominated by van~der~Waals interaction, aqueous GdmCl favors the extended conformation over the compact conformation. Our finding emphasizes the importance of weak, but attractive, long-range dispersion interactions in protein solution thermodynamics

The effect of manganese oxide on the sinterability of hydroxyapatite

The sinterability of manganese oxide (MnO2) doped hydroxyapatite (HA) ranging from 0.05 to 1 wt% was investigated. Green samples were prepared and sintered in air at temperatures ranging from 1000 to 1400 °C. Sintered bodies were characterized to determine the phase stability, grain size, bulk density, hardness, fracture toughness and Young's modulus. XRD analysis revealed that the HA phase stability was not disrupted throughout the sintering regime employed. In general, samples containing less than 0.5 wt% MnO2 and when sintered at lower temperatures exhibited higher mechanical properties than the undoped HA. The study revealed that all the MnO2-doped HA achieved >99% relative density when sintered at 1100–1250 °C as compared to the undoped HA which could only attained highest value of 98.9% at 1150 °C. The addition of 0.05 wt% MnO2 was found to be most beneficial as the samples exhibited the highest hardness of 7.58 GPa and fracture toughness of 1.65 MPam1/2 as compared to 5.72 GPa and 1.22 MPam1/2 for the undoped HA when sintered at 1000 °C. Additionally, it was found that the MnO2-doped samples attained E values above 110 GPa when sintered at temperature as low as 1000 °C if compared to 1050 °C for the undoped HA