Factura, 1878 marzo 6, Madrid, de Escribanía del Número y Notaría de D. Vicente Reyter a D. Juan de Tro y Ortolano

Factura impresa escrita a mano en tinta negraAlcance y contenido: Versa sobre la redacción del testamento del destinatario de la factura. Precio en realesEn el membrete: "Escribanía del Número y Notaría de D. Vicente Reyter"Factura firmada con Recibí p. o. y rubricada por Julián MarcosMembrete del establecimiento con ornamentos en la parte izquierda de la cabeceraPapel ocre con rayasFactura por las dos caras al verso sin cumplimenta

Very High Surface Capacity with Si Negative Electrodes Embedded in Copper Foam as 3D Current Collector

For the last 10 years, a tremendous amount of work has been published to solve the problem of capacity fade of silicon-based electrodes which prevents their utilization in commercial lithium-ion batteries. The use of Si nanoparticles/nanowires to better accommodate large strain without cracking has developed and is very popular in the academic community. By playing on the nano-architecturing effect or tailoring the composite electrode formulation, several groups have reached up to 1000 cycles in half-cells versus lithium metal [1,2]. However, a careful look at the papers shows that in all studies the active mass loading is very low, typically less than 1 mg per cm², and thus the practical surface capacity of the corresponding electrodes is low, typically less than 1 mAh per cm². This is much lower than that of the state of the art graphite-based negative electrode, which reaches up to 5 mAh per cm² in cellular phones for example. As a consequence, although silicon is much more attractive than graphite due to its very high gravimetric capacity (3572 mAh g-1 versus 372 mAh g-1 for graphite) and volumetric capacity (2249 versus 779 mAh cm-3 for graphite), Si-based composite electrodes show lower practical surface capacity, as a matter of fact. The point is that the cycle life of Si-based electrodes dramatically decreases as the active mass loading increases, e.g. 1000 cycles at 0.5 mg per cm² vs. 50 cycles at 4 mg per cm² (Figure 1). We demonstrated that using copper foam instead of copper foil as current collector shows a great advantage in the cycle life and power performance. More than 400 cycles at an impressive Si loading of 10 mg cm-² could be reached, i.e. with a surface capacity of 10 mAh cm-2 [3]. The thinness of the composite coating on the foam walls favors a better preservation of the electronic wiring upon cycling and fast lithium ion diffusion. A higher coulombic efficiency in half cells with lithium metal as the counter electrode is achieved by using carbon nanofibers (CNF) rather than carbon black (CB). The possibility to reach in practice higher surface could allow a significant increase of both the volumetric and gravimetric energy densities by 23% and 19%, respectively, for the Cu foam-Silicon//LiFePO4 stack compared to the Graphite/LiFePO4 stack of traditional design. Acknowledgements Financial funding from the Agence Nationale de la Recherche (ANR) of France (BASILIC project) and the Natural Science and Engineering Research Council (NSERC) of Canada is acknowledged. The authors thank D. Pilon (Metafoam Inc.) for supplying the Cu foams. References [1] L. Hu, F. La Mantia, H. Wu, X. Xie, J. McDonough, M. Pasta, Y. Cui, Adv. Energy Mater., 1, 1012 (2011). [2] I. Kovalenko, B. Zdyrko, A. Magasinski, B. Hertzberg, Z. Milicev, R. Burtovyy, I. Luzinov and G. Yushin, Science, 334, 75 (2011). [3] D. Mazouzi, , D. Reyter, M. Gauthier, P. Moreau, D. Guyomard, L. Roué, B. Lestriez, Adv. Energy Mater., DOI: 10.1002/aenm.201301718. Figure 1. (a) Surface SEM images of a Cu foam filled with 5 mg of Si/CNF/CMC/Buffer composite electrode (4.6 mg Si per cm2). (b) Cycle life as a function of the active mass loading for Foil-Si/CB/CMC/Buffer and Foam-Si/CNF/CMC/Buffer electrodes (Si//Li half-cell with LP30+2%VC+10%FEC, capacity limitation of 1200mAh per g of Si). </jats:p

3D morphological analysis of copper foams as current collectors for Li-ion batteries by means of X-ray tomography

International audienceno abstrac

3D morphological analysis of copper foams as current collectors for Li-ion batteries by means of X-ray tomography

International audienceAs-received and chemically treated copper foams were characterized by means of laboratory X-ray tomography with a resolution of 0.5 µm. 3D image processing and analysis allowed the morphological parameters (size, sphericity, tortuosity…) of the pores and copper skeleton to be determined. The chemical dissolution of the Cu foam in an acid hydrogen peroxide solution results in an increase of the open pore size (from 54 to 93 µm) and a decrease of the foam thickness (from 140 to 115 µm). With an open porosity of 81.8% and a specific surface area as high as 280,000 (49,000) m 2 m-3 of Cu (foam), the chemically-treated Cu foam appears very attractive for use as a 3D current collector for metal (e.g. Si) based anodes for Li-ion batteries

High Performance Silicon-Based Negative Electrodes for Li-Ion Batteries

Abstract not Available.</jats:p