Linking mineralisation process and sedimentary product in terrestrial carbonates using a solution thermodynamic approach

Determining the processes which generate terrestrial carbonate deposits (tufas, travertines and to a lesser extent associated chemical sediments such as calcretes and speleothems) is a long-standing problem. Precipitation of mineral products from solution reflects a complex combination of biological, equilibrium and kinetic processes, and the different morphologies of carbonate sediment produced by different processes have yet to be clearly demarked. Building on the groundbreaking work of previous authors, we propose that the underlying control on the processes leading to the deposition of these products can be most parsimoniously understood from the thermodynamic properties of their source solutions. Here, we report initial observations of the differences in product generated from spring and lake systems spanning a range of temperature–supersaturation space. We find that at high supersaturation, biological influences are masked by high rates of physico-chemical precipitation, and sedimentary products from these settings infrequently exhibit classic "biomediated" fabrics such as clotted micrite. Likewise, at high temperature (>40 °C) exclusion of vascular plants and complex/diverse biofilms can significantly inhibit the magnitude of biomediated precipitation, again impeding the likelihood of encountering the "bio-type" fabrics. <br></br> Conversely, despite the clear division in product between extensive tufa facies associations and less spatially extensive deposits such as oncoid beds, no clear division can be identified between these systems in temperature–supersaturation space. We reiterate the conclusion of previous authors, which demonstrate that this division cannot be made on the basis of physico-chemical characteristics of the solution alone. We further provide a new case study of this division from two adjacent systems in the UK, where tufa-like deposition continuous on a metre scale is happening at a site with lower supersaturation than other sites exhibiting only discontinuous (oncoidal) deposition. However, a strong microbiological division is demonstrated between these sites on the basis of suspended bacterial cell distribution, which reach a prominent maximum where tufa-like deposits are forming. <br></br> We conclude that at high supersaturation, the thermodynamic properties of solutions provide a highly satisfactory means of linking process and product, raising the opportunity of identifying water characteristics from sedimentological/petrological characteristics of ancient deposits. At low supersaturation, we recommend that future research focuses on geomicrobiological processes rather than the more traditional, inorganic solution chemistry approach dominant in the past

Five-Year Growth of Rock Lichens in a Low-Arctic Mountain Environment, Northern Labrador

In 1978, three lichen growth stations were established for Rhizocarpon section Rhizocarpon species and one for Alectoria miniscula in the Cirque Mountain area of the Torngat mountains. Five years later, in 1983, the lichens were remeasured. The five-year growth represented by the change in the theoretical diameter is very variable, between 0.10 and 0.54 mm per year. These rates are larger than expected and exceed rates previously determined for an eastern Arctic area, the Northern Cumberland Peninsula of Baffin Island, by more than 3 to more than 20 times. Similar rates are known for 'great period' growth outside Arctic regions. If the growth rates represent long-term growth, the ages of recessional moraines in the Torngat Mountains should be recalculated. Moraines formerly described as Late Wisconsin to mid-Holocene may be of Neoglacial age. Variability of growth rates from one individual to another precludes using these data for constructing growth curves which may be used, even locally, in lichenometric dating.En 1978, on a établi quatre sites de croissance du lichen dans la région du mont du Cirque dans les monts Torngat: trois sites des espèces Rhizocarpon de la section Rhizocarpon et un site de Alectoria miniscula. Cinq ans plus tard, en 1983, on a mesuré de nouveau les lichens pour constater que le diamètre moyen, qui témoigne de la croissance, a crû de manière très variable, soit de 0,10 à 0,54 mm par année. Ces taux de croissance sont plus élevés que prévu puisqu'ils dépassent de 3 à 20 fois les taux déjà mesurés dans le nord de la péninsule de Cumberland, île de Baffin. De tels taux de croissance du lichen s'apparentent davantage à ceux que l'on a observé dans les régions non arctiques au cours de sa période dite de grande croissance. Si ces taux s'appliquent à de longues périodes, il faudrait réévaluer la date de dépôt des moraines de récession dans les monts Torngat. Les moraines, que l'on croit dater de la période s'étendant du Wisconsinien supérieur à l'Holocène moyen, pourraient en fait dater du néoglaciaire. Toutefois, les variations observées entre les taux de croissance ne permettent pas d'utiliser ces données, même à l'échelle locale, pour tracer des courbes de croissance qui serviraient à établir des datations lichénométriques.1978 wurden im Cirque-Mountain-Gebiet der Torngat mountains vier Stationen zur Beobachtung des Flechten-Wachstums eingerichtet : drei Stationen fur Rhizocarpon-Arten der Sektion Rhizocarpon und eine Station fur Alectoria miniscula. Fùnf Jahre spâter, 1983, wurden die Flechten wieder gemessen. Der Fùnfjahreswuchs, der sich im Wechsel des durchschnittlichen Durchmessers ablesen IaBt, ist sehr unterschiedlich, zwischen 0.10 und 0.54 mm pro Jahr. Dièse Wachstumsraten sind grôfîer als erwartet und gehen ùber die zuvor fur ein ôstliches arktisches Gebiet, die Nord-Cumberland HaIbinsel der lnsel Baffin, bestimmten Raten mehr als dreifach bis zu mehr als zwanzigfach hinaus. Àhnliche Wachstumsraten sind fur die "groBe Periode" des Flechten-Wachstums auBerhalb der arktischen Gebiete bekannt. Wenn die Wachstumsraten Langzeit-Wachstum reprâsentieren, mûfite das Alter der Rùckzugs-Morànen in den Torngat-Bergen neu berechnet werden. Morànen, die zuvor dem spàten Wisconsin bis mittleren Holozân zugeschrieben wurden, kônnten aus der Neoglazialzeit stammen. Die Variationen der Wachstumsraten von einer Person zur anderen schlieBen eine Nutzung dieser Daten zum Aufbau von Wachstumskurven aus, welche, selbst lokal, zur Datierung auf der Basis der Flechten benutzt werden kônnten

“You know that's a rip-off”: policies and practices surrounding micro-enterprises and poverty alleviation in South African township tourism

Supporting the development of small tourism businesses has been seen by policy-makers as a valuable means of alleviating poverty in South African townships. This perspective has been endorsed by several ‘responsible’ tourism businesses and academics. Following a review of the literature, this paper reports the findings of an empirical study that examined the practices of micro-business owners and the factors that shape their behaviour in two South African townships. In spite of significant visitor numbers, it finds that their narrow social networks and the imbalances of power between them and intermediaries such as travel agencies and tour operators prevent them from developing their businesses and sharing in the material gains that become available because of tourism. This analysis has important implications for local policy-makers and those advocating responsible tourism. For the former, it suggests a cessation of current initiatives in favour of greater regulation and alternative forms of investment. For the latter, it implies the need to reassess the utility of advocating responsible tourism to consumers in a context where they do not understand the dynamics which fashion what is on offer or the full implications of their choices

Mechanism of Vanadium Leaching during Surface Weathering of Basic Oxygen Furnace Steel Slag Blocks: A Microfocus X-ray Absorption Spectroscopy and Electron Microscopy Study

© 2017 American Chemical Society. Basic oxygen furnace (BOF) steelmaking slag is enriched in potentially toxic V which may become mobilized in high pH leachate during weathering. BOF slag was weathered under aerated and air-excluded conditions for 6 months prior to SEM/EDS and μXANES analysis to determine V host phases and speciation in both primary and secondary phases. Leached blocks show development of an altered region in which free lime and dicalcium silicate phases were absent and Ca-Si-H was precipitated (CaCO 3 was also present under aerated conditions). μXANES analyses show that V was released to solution as V(V) during dicalcium silicate dissolution and some V was incorporated into neo-formed Ca-Si-H. Higher V concentrations were observed in leachate under aerated conditions than in the air-excluded leaching experiment. Aqueous V concentrations were controlled by Ca 3 (VO 4 ) 2 solubility, which demonstrate an inverse relationship between Ca and V concentrations. Under air-excluded conditions Ca concentrations were controlled by dicalcium silicate dissolution and Ca-Si-H precipitation, leading to relatively high Ca and correspondingly low V concentrations. Formation of CaCO 3 under aerated conditions provided a sink for aqueous Ca, allowing higher V concentrations limited by kinetic dissolution rates of dicalcium silicate. Thus, V release may be slowed by the precipitation of secondary phases in the altered region, improving the prospects for slag reuse

Malaria during pregnancy and foetal haematological status in Blantyre, Malawi

Background: Although maternal anaemia often stems from malaria infection during pregnancy, its effects on foetal haemoglobin levels are not straightforward. Lower-than-expected cord haemoglobin values in malarious versus non-malarious regions were noted by one review, which hypothesized they resulted from foetal immune activation to maternal malaria. This study addressed this idea by examining cord haemoglobin levels in relation to maternal malaria, anaemia, and markers of foetal immune activation. Methods: Cord haemoglobin levels were examined in 32 malaria-infected and 58 uninfected women in Blantyre, Malawi, in relation to maternal haemoglobin levels, malaria status, and markers of foetal haematological status, hypoxia, and inflammation, including TNF-alpha, TGF-beta, and ferritin. All women were HIV-negative. Results: Although malaria was associated with a reduction in maternal haemoglobin (10.8 g/dL vs. 12.1 g/ dL, p < 0.001), no reduction in cord haemoglobin and no significant relationship between maternal and cord haemoglobin levels were found. Cord blood markers of haematological and hypoxic statuses did not differ between malaria-infected and uninfected women. Maternal malaria was associated with decreased TGF- and increased cord ferritin, the latter of which was positively correlated with parasitaemia (r = 0.474, p = 0.009). Increased cord ferritin was associated with significantly decreased birth weight and gestational length, although maternal and cord haemoglobin levels and malaria status had no effect on birth outcome. Conclusion: In this population, cord haemoglobin levels were protected from the effect of maternal malaria. However, decreased TGF- and elevated ferritin levels in cord blood suggest foetal immune activation to maternal malaria, which may help explain poor birth outcomes

A universal model for mobility and migration patterns

Introduced in its contemporary form by George Kingsley Zipf in 1946, but with roots that go back to the work of Gaspard Monge in the 18th century, the gravity law is the prevailing framework to predict population movement, cargo shipping volume, inter-city phone calls, as well as bilateral trade flows between nations. Despite its widespread use, it relies on adjustable parameters that vary from region to region and suffers from known analytic inconsistencies. Here we introduce a stochastic process capturing local mobility decisions that helps us analytically derive commuting and mobility fluxes that require as input only information on the population distribution. The resulting radiation model predicts mobility patterns in good agreement with mobility and transport patterns observed in a wide range of phenomena, from long-term migration patterns to communication volume between different regions. Given its parameter-free nature, the model can be applied in areas where we lack previous mobility measurements, significantly improving the predictive accuracy of most of phenomena affected by mobility and transport processes.Comment: Main text and supplementary informatio

A Far-Ultraviolet View of Starburst Galaxies

Recent observational and theoretical results on starburst galaxies related to the wavelength regime below 1200 A are discussed. The review covers stars, dust, as well as hot and cold gas. This wavelength region follows trends similar to those seen at longer wavelengths, with several notable exceptions. Even the youngest stellar populations show a turn-over in their spectral energy distributions, and line-blanketing is much more pronounced. Furthermore, the O VI line allows one to probe gas at higher temperatures than possible with lines at longer wavelengths. Molecular hydrogen lines (if detected) provide a glimpse of the cold phase. I cover the crucial wavelength regime below 912 A and the implications of recent attempts to detect the escaping ionizing radiation.Comment: 8 pages, 3 figures, Invited Talk, Starbursts--From 30 Doradus to Lyman-Break Galaxies, ed. R. de Grijs & R. M. Gonzalez Delgado (Dordrecht: Kluwer

Hopes and Fears: Community cohesion and the ‘White working class’ in one of the ‘failed spaces’ of multiculturalism

Since 2001, community cohesion has been an English policy concern, with accompanying media discourse portraying a supposed failure by Muslims to integrate. Latterly, academia has foregrounded White majority attitudes towards ethnic diversity, particularly those of the ‘White working class’. Whilst questioning this categorisation, we present data on attitudes towards diversity from low income, mainly White areas within Dewsbury, West Yorkshire, a town portrayed in media discourse as one of the ‘failed spaces’ of multiculturalism. Drawing on mixed methods research, we present and discuss data that provide a complex message, seemingly confirming pessimistic analyses around ethnic diversity and predominantly White neighbourhoods but also highlighting an appetite within the same communities for greater and more productive inter-ethnic contact. Furthermore, anxieties about diversity and integration have largely failed to coalesce into broad support for organised anti-minority politics manifest in groups such as the English Defence League

Ethical issues in implementation research: a discussion of the problems in achieving informed consent

Background: Improved quality of care is a policy objective of health care systems around the world. Implementation research is the scientific study of methods to promote the systematic uptake of clinical research findings into routine clinical practice, and hence to reduce inappropriate care. It includes the study of influences on healthcare professionals' behaviour and methods to enable them to use research findings more effectively. Cluster randomized trials represent the optimal design for evaluating the effectiveness of implementation strategies. Various codes of medical ethics, such as the Nuremberg Code and the Declaration of Helsinki inform medical research, but their relevance to cluster randomised trials in implementation research is unclear. This paper discusses the applicability of various ethical codes to obtaining consent in cluster trials in implementation research. Discussion: The appropriate application of biomedical codes to implementation research is not obvious. Discussion of the nature and practice of informed consent in implementation research cluster trials must consider the levels at which consent can be sought, and for what purpose it can be sought. The level at which an intervention is delivered can render the idea of patient level consent meaningless. Careful consideration of the ownership of information, and rights of access to and exploitation of data is required. For health care professionals and organizations, there is a balance between clinical freedom and responsibility to participate in research. Summary: While ethical justification for clinical trials relies heavily on individual consent, for implementation research aspects of distributive justice, economics, and political philosophy underlie the debate. Societies may need to trade off decisions on the choice between individualized consent and valid implementation research. We suggest that social sciences codes could usefully inform the consideration of implementation research by members of Research Ethics Committees