Targeting of anionic membrane species by lanthanide(III) complexes: towards improved MRI contrast agents for apoptosis

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Changes in r-process abundances at late times

We explore changes in abundance patterns that occur late in the r process. As the neutrons available for capture begin to disappear, a quasiequilibrium funnel shifts material into the large peaks at A=130 and A=195, and into the rare-earth "bump" at A=160. A bit later, after the free-neutron abundance has dropped and beta-decay has begun to compete seriously with neutron capture, the peaks can widen. The degree of widening depends largely on neutron-capture rates near closed neutron shells and relatively close to stability. We identify particular nuclei the capture rates of which should be examined experimentally, perhaps at a radioactive beam facility.Comment: 8 pages, 14 figures included in tex

The Influence Of Neutron Capture Rates On The Rare Earth Region Of The r-Process Abundance Pattern

We study the sensitivity of the r-process abundance pattern to neutron capture rates along the rare earth region (A~150 to A~180). We introduce the concepts of large nuclear flow and flow saturation which determine the neutron capture rates that are influential in setting the rare earth abundances. We illustrate the value of the two concepts by considering high entropy conditions favorable for rare earth peak production and identifying important neutron capture rates among the rare earth isotopes. We also show how these rates influence nuclear flow and specific sections of the abundance pattern.Comment: 14 pages, 7 figures, submitted to PR

Neutron-Rich Freeze-Out in Viscously Spreading Accretion Disks Formed from Compact Object Mergers

Accretion disks with masses ~0.001-0.1 Msun form during the merger of neutron star (NS)-NS and black hole-NS binaries. Initially, such hyper-accreting disks cool efficiently by neutrino emission and their composition is driven neutron-rich by pair captures under degenerate conditions. However, as the disk viscously spreads and its temperature drops, cooling becomes inefficient and the disk becomes advective. Analytic arguments and numerical simulations suggest that once this occurs, powerful winds likely drive away most of the disk's remaining mass. We calculate the thermal evolution and nuclear composition of viscously spreading accretion disks formed from compact object mergers using one-dimensional height-integrated simulations. We show that freeze-out from weak equilibrium necessarily accompanies the disk's late-time transition to an advective state. As a result, hyper-accreting disks generically freeze out neutron-rich (with electron fraction Ye ~ 0.2-0.4), and their late-time outflows robustly synthesize rare neutron-rich isotopes. Using the measured abundances of these isotopes in our solar system, we constrain the compact object merger rate in the Milky Way to be < 1e-5 (M_d,0/0.1 Msun)^(-1) per year, where M_d,0 is the average initial mass of the accretion disk. Thus, either the NS-NS merger rate is at the low end of current estimates or the average disk mass produced during a typical merger is << 0.1 Msun. We also show that if most short duration gamma-ray bursts (GRBs) are produced by compact object mergers, their beaming fraction must exceed f_b ~ 0.13(M_d,0/0.1 Msun), corresponding to a jet half-opening angle > 30(M_d,0/0.1 Msun)^(1/2) degrees. This is consistent with other evidence that short duration GRB outflows are less collimated than those produced in long duration GRBs.Comment: 12 pages, 9 figures, 1 table; accepted to MNRAS; minor changes to text and figure

The influence of collective neutrino oscillations on a supernova r-process

Recently, it has been demonstrated that neutrinos in a supernova oscillate collectively. This process occurs much deeper than the conventional matter-induced MSW effect and hence may have an impact on nucleosynthesis. In this paper we explore the effects of collective neutrino oscillations on the r-process, using representative late-time neutrino spectra and outflow models. We find that accurate modeling of the collective oscillations is essential for this analysis. As an illustration, the often-used "single-angle" approximation makes grossly inaccurate predictions for the yields in our setup. With the proper multiangle treatment, the effect of the oscillations is found to be less dramatic, but still significant. Since the oscillation patterns are sensitive to the details of the emitted fluxes and the sign of the neutrino mass hierarchy, so are the r-process yields. The magnitude of the effect also depends sensitively on the astrophysical conditions - in particular on the interplay between the time when nuclei begin to exist in significant numbers and the time when the collective oscillation begins. A more definitive understanding of the astrophysical conditions, and accurate modeling of the collective oscillations for those conditions, is necessary.Comment: 27 pages, 10 figure

Precision mass measurements on neutron-rich rare-earth isotopes at JYFLTRAP - reduced neutron pairing and implications for the rr-process calculations

The rare-earth peak in the $r$-process abundance pattern depends sensitively on both the astrophysical conditions and subtle changes in nuclear structure in the region. This work takes an important step elucidating the nuclear structure and reducing the uncertainties in $r$-process calculations via precise atomic mass measurements at the JYFLTRAP double Penning trap. $^{158}$Nd, $^{160}$Pm, $^{162}$Sm, and $^{164-166}$Gd have been measured for the first time and the precisions for $^{156}$Nd, $^{158}$Pm, $^{162,163}$Eu, $^{163}$Gd, and $^{164}$Tb have been improved considerably. Nuclear structure has been probed via two-neutron separation energies $S_{2n}$ and neutron pairing energy metrics $D_n$. The data do not support the existence of a subshell closure at $N=100$. Neutron pairing has been found to be weaker than predicted by theoretical mass models. The impact on the calculated $r$-process abundances has been studied. Substantial changes resulting in a smoother abundance distribution and a better agreement with the solar $r$-process abundances are observed.Comment: 8 pages, 4 figures, accepted for publication in Physical Review Letter

Neutrino capture by r-process waiting-point nuclei

We use the Quasiparticle Random Phase Approximation to include the effects of low-lying Gamow-Teller and first forbidden strength in neutrino capture by very neutron-rich nuclei with N = 50, 82, or 126. For electron neutrinos in what is currently considered the most likely r-process site the capture cross sections are two or more times previous estimates. We briefly discuss the reliability of our calculations and their implications for nucleosynthesis.Comment: 9 pages, 4 figure