Which wets TiB2 inoculant particles: Al or Al3Ti?

TiB2 particles are proven effective nucleants of commercial purity aluminium, resulting in smaller grains and hence greater desired mechanical properties; however, there is uncertainty as to the mechanism by which it operates. Here we clarify what happens in the initial stages by computing the total Gibbs energy change associated with four possible nucleation mechanisms, each characterised by the termination of the TiB2(0001) substrate (Ti or B) and the solid that forms on it (Al or Al3Ti). The appropriate solid//solid interfacial energies are derived from Density Functional Theory (DFT) calculations, while the bulk energies are derived from thermodynamic data, supplemented with strain energies calculated from DFT. Solid//liquid interfacial energies are estimated using simple models with parameters based on the literature and DFT calculations. The results suggest that the Ti termination of TiB2 is more stable than the B termination in the melt, and that the direct formation of Al off a Ti-terminated TiB2 substrate is the most favourable mechanism for the nucleation of Al rather than the previously proposed formation of a Al3Ti interlayer. On the B termination of TiB2, Al formation is more stable for thick solid layers, but this is much more uncertain for thin solid layers where it is possible that Al3Ti formation is more stable

Waterborne: Vietnamese Australians and Sydney's Georges River parks and green spaces

Waterborne: Vietnamese Australians and Sydney's Georges River parks and green spaces, has been created by talking with the Vietnamese Australians who live around the Georges River and who often visit its parklands. They explain here their memories of their early homelands, which are given a context with information about the histories of rivers and parks in Vietnam. Then these Vietnamese Australians talk about their hopes about parks in Australia and their actual experiences in the parks and rivers around their new homes near the Georges River

Waters of belonging : Al-miyahu Tajma'unah: Arabic Australians and the Georges River Parklands

This series arises from Parklands, Culture and Communities, a project which looks at how cultural diversity shapes people's understandings and use of the Georges River and green spaces in Sydney's south west. We focus on the experiences of four local communities (Aboriginal, Vietnamese, Arabic and Anglo Australians) and their relationships with the river, parks and each other. Culturally diverse uses and views have not often been recognised in Australia in park and green space management models, which tend to be based on Anglo-Celtic 'norms' about nature and recreation. UTS and the Office of Environment and Heritage supported this research because they have been interested in how the more diverse cultural knowledges held by Australians today might offer support for managing green spaces more effectively

An Assessment of Tarong Bottom Ash for Use on Agricultural Soils

Coal combustion by-products (CCBs), including fly ash and bottom ash, present a waste disposal problem in Australia due to a continuing demand for coal fired power. Pozzolanic Enterprises handle ash produced by the Tarong Energy coalfired power station in SouthWest Queensland, which produces approximately 1,200,000 tonnes per annum of CCBs. This comprises roughly 1,100,000 tonnes of fly ash and 100,000 tonnes of furnace bottom ash. The volume and unique properties of the Tarong bottom ash present a significant opportunity for agronomic use. Of particular interest is the ability of Tarong bottom ash to markedly improve the water holding capacity of soils. Given Australia's rural environment is currently enduring a 'one-in-one- hundred-year' drought a study of the ability of Tarong bottom ash to improve water holding capacity is timely. This paper details physical and chemical properties relevant to agronomic use and water holding capacity of ash/soil blends along with some results from initial field trials

Nucleation of Pb starfish clusters on the five-fold Al-Pd-Mn quasicrystal surface

The nucleation of Pb clusters on the five-fold Al-Pd-Mn quasicrystal surface has been investigated using scanning tunneling microscopy (STM) and ab initio calculations based on density-functional theory (DFT). In the submonolayer regime, Pb atoms are highly mobile and adsorb preferentially within equatorially truncated pseudo-Mackay clusters present at the surface. The decoration of these unique adsorption sites leads to the formation of five-fold islands dubbed “starfish” and eventually to a quasiperiodic Pb monolayer. From a comparison of measured and calculated STM images it is concluded that most starfish clusters on all terraces are composed of ten Pb adatoms. A model of the structure of the starfish cluster has been proposed. Our total-energy calculations confirm its stability. The experimentally measured height profile of the starfish cluster is also reproduced by the DFT calculations

The impact of the demographic transition on dengue in Thailand: Insights from a statistical analysis and mathematical modeling

Background: An increase in the average age of dengue hemorrhagic fever (DHF) cases has been reported in Thailand. The cause of this increase is not known. Possible explanations include a reduction in transmission due to declining mosquito populations, declining contact between human and mosquito, and changes in reporting. We propose that a demographic shift toward lower birth and death rates has reduced dengue transmission and lengthened the interval between large epidemics. Methods and Findings: Using data from each of the 72 provinces of Thailand, we looked for associations between force of infection (a measure of hazard, defined as the rate per capita at which susceptible individuals become infected) and demographic and climactic variables. We estimated the force of infection from the age distribution of cases from 1985 to 2005. We find that the force of infection has declined by 2% each year since a peak in the late 1970s and early 1980s. Contrary to recent findings suggesting that the incidence of DHF has increased in Thailand, we find a small but statistically significant decline in DHF incidence since 1985 in a majority of provinces. The strongest predictor of the change in force of infection and the mean force of infection is the median age of the population. Using mathematical simulations of dengue transmission we show that a reduced birth rate and a shift in the population's age structure can explain the shift in the age distribution of cases, reduction of the force of infection, and increase in the periodicity of multiannual oscillations of DHF incidence in the absence of other changes. Conclusions: Lower birth and death rates decrease the flow of susceptible individuals into the population and increase the longevity of immune individuals. The increase in the proportion of the population that is immune increases the likelihood that an infectious mosquito will feed on an immune individual, reducing the force of infection. Though the force of infection has decreased by half, we find that the critical vaccination fraction has not changed significantly, declining from an average of 85% to 80%. Clinical guidelines should consider the impact of continued increases in the age of dengue cases in Thailand. Countries in the region lagging behind Thailand in the demographic transition may experience the same increase as their population ages. The impact of demographic changes on the force of infection has been hypothesized for other diseases, but, to our knowledge, this is the first observation of this phenomenon

Holidaying in a disaster zone isn't as crazy as it might seem

This article focuses on the valuable role of volunteer tourism in the recovery of tourism to Nepal following the 2015 earthquake. It shows that sustainable tourism practices can positively contribute to post disastare rebuilding