1,354 research outputs found
Doping of inorganic materials in microreactors – preparation of Zn doped Fe₃O₄ nanoparticles
Microreactor systems are now used more and more for the continuous production of metal nanoparticles and metal oxide nanoparticles owing to the controllability of the particle size, an important property in many applications. Here, for the first time, we used microreactors to prepare metal oxide nanoparticles with controlled and varying metal stoichiometry. We prepared and characterised Zn-substituted Fe₃O₄ nanoparticles with linear increase of Zn content (ZnxFe₃−xO₄ with 0 ≤ x ≤ 0.48), which causes linear increases in properties such as the saturation magnetization, relative to pure Fe₃O₄. The methodology is simple and low cost and has great potential to be adapted to the targeted doping of a vast array of other inorganic materials, allowing greater control on the chemical stoichiometry for nanoparticles prepared in microreactors
The digital data processing concepts of the LOFT mission
The Large Observatory for X-ray Timing (LOFT) is one of the five mission
candidates that were considered by ESA for an M3 mission (with a launch
opportunity in 2022 - 2024). LOFT features two instruments: the Large Area
Detector (LAD) and the Wide Field Monitor (WFM). The LAD is a 10 m 2 -class
instrument with approximately 15 times the collecting area of the largest
timing mission so far (RXTE) for the first time combined with CCD-class
spectral resolution. The WFM will continuously monitor the sky and recognise
changes in source states, detect transient and bursting phenomena and will
allow the mission to respond to this. Observing the brightest X-ray sources
with the effective area of the LAD leads to enormous data rates that need to be
processed on several levels, filtered and compressed in real-time already on
board. The WFM data processing on the other hand puts rather low constraints on
the data rate but requires algorithms to find the photon interaction location
on the detector and then to deconvolve the detector image in order to obtain
the sky coordinates of observed transient sources. In the following, we want to
give an overview of the data handling concepts that were developed during the
study phase.Comment: Proc. SPIE 9144, Space Telescopes and Instrumentation 2014:
Ultraviolet to Gamma Ray, 91446
Spectroscopic characterisation of CARMENES target candidates from FEROS, CAFE and HRS high-resolution spectra
CARMENES (Calar Alto high-Resolution search for M dwarfs with Exoearths with
Near-infrared and optical Echelle Spectrographs) started a new planet survey on
M-dwarfs in January this year. The new high-resolution spectrographs are
operating in the visible and near-infrared at Calar Alto Observatory. They will
perform high-accuracy radial-velocity measurements (goal 1 m s-1) of about 300
M-dwarfs with the aim to detect low-mass planets within habitable zones. We
characterised the candidate sample for CARMENES and provide fundamental
parameters for these stars in order to constrain planetary properties and
understand star-planet systems. Using state-of-the-art model atmospheres
(PHOENIX-ACES) and chi2-minimization with a downhill-simplex method we
determine effective temperature, surface gravity and metallicity [Fe/H] for
high-resolution spectra of around 480 stars of spectral types M0.0-6.5V taken
with FEROS, CAFE and HRS. We find good agreement between the models and our
observed high-resolution spectra. We show the performance of the algorithm, as
well as results, parameter and spectral type distributions for the CARMENES
candidate sample, which is used to define the CARMENES target sample. We also
present first preliminary results obtained from CARMENES spectra
Quantitative atomic spectroscopy for primary thermometry
Quantitative spectroscopy has been used to measure accurately the
Doppler-broadening of atomic transitions in Rb vapor. By using a
conventional platinum resistance thermometer and the Doppler thermometry
technique, we were able to determine with a relative uncertainty of
, and with a deviation of from the
expected value. Our experiment, using an effusive vapour, departs significantly
from other Doppler-broadened thermometry (DBT) techniques, which rely on weakly
absorbing molecules in a diffusive regime. In these circumstances, very
different systematic effects such as magnetic sensitivity and optical pumping
are dominant. Using the model developed recently by Stace and Luiten, we
estimate the perturbation due to optical pumping of the measured value
was less than . The effects of optical pumping on atomic and
molecular DBT experiments is mapped over a wide range of beam size and
saturation intensity, indicating possible avenues for improvement. We also
compare the line-broadening mechanisms, windows of operation and detection
limits of some recent DBT experiments
Modelling the molecular Zeeman effect in M-dwarfs: methods and first results
We present first quantitative results of the surface magnetic field
measurements in selected M-dwarfs based on detailed spectra synthesis conducted
simultaneously in atomic and molecular lines of the FeH Wing-Ford
transitions. A modified version of the Molecular
Zeeman Library (MZL) was used to compute Land\'e g-factors for FeH lines in
different Hund's cases. Magnetic spectra synthesis was performed with the
Synmast code. We show that the implementation of different Hund's case for FeH
states depending on their quantum numbers allows us to achieve a good fit to
the majority of lines in a sunspot spectrum in an automatic regime. Strong
magnetic fields are confirmed via the modelling of atomic and FeH lines for
three M-dwarfs YZ~CMi, EV~Lac, and AD~Leo, but their mean intensities are found
to be systematically lower than previously reported. A much weaker field
(~kG against ~kG) is required to fit FeH lines in the spectra of
GJ~1224. Our method allows us to measure average magnetic fields in very
low-mass stars from polarized radiative transfer. The obtained results indicate
that the fields reported in earlier works were probably overestimated by about
\%. Higher quality observations are needed for more definite results.Comment: Accepted by A&A, 13 pages, 7 figures, 1 tabl
Anabranching and maximum flow efficiency in Magela Creek, northern Australia
Anabranching is the prevailing river pattern found along alluvial tracts of the world's largest rivers. Hydraulic geometry and bed material discharge are compared between single channel and anabranching reaches up to 4 times bank-full discharge in Magela Creek, northern Australia. The anabranching channels exhibit greater sediment transporting capacity per unit available stream power, i.e., maximum flow efficiency (MFE). Simple flume experiments corroborate our field results showing the flow efficiency gains associated with anabranching, and highlight the prospect of a dominant anabranch, which is found in many anabranching rivers. These results demonstrate that anabranching can constitute a stable river pattern in dynamic equilibrium under circumstances in which a continuous single channel would be unable to maintain sediment conveyance. We propose the existence of a flow efficiency continuum that embraces dynamic equilibrium and disequilibrium (vertically accreting) anabranching rivers
Patient level pooled analysis of 68,500 patients from seven major vitamin D fracture trials in the US and Europe
Objectives To identify participants’ characteristics that influence the anti-fracture efficacy of vitamin D or vitamin
D plus calcium with respect to any fracture, hip fracture, and clinical vertebral fracture and to assess the influence of dosing regimens and co-administration of calcium. Design Individual patient data analysis using pooled data from randomised trials. Data sources Seven major randomised trials of vitamin D with calcium or vitamin D alone, yielding a total of 68 517 participants (mean age 69.9 years, range 47-107 years, 14.7% men). Study selection Studies included were randomised studies with at least one intervention arm in which vitamin D was given, fracture as an outcome, and at least 1000 participants. Data synthesis Logistic regression analysis was used to identify significant interaction terms, followed by Cox’s proportional hazards models incorporating age, sex, fracture history, and hormone therapy and bisphosphonate use. Results Trials using vitamin D with calcium showed a
reduced overall risk of fracture (hazard ratio 0.92, 95% confidence interval 0.86 to 0.99, P=0.025) and hip fracture (all studies: 0.84, 0.70 to 1.01, P=0.07; studies using 10 μg of vitamin D given with calcium: 0.74, 0.60 to 0.91, P=0.005). For vitamin D alone in daily doses of 10 μg or 20 μg, no significant effects were found. No interaction was found between fracture history and treatment
response, nor any interaction with age, sex, or hormone replacement therapy. Conclusion This individual patient data analysis indicates that vitamin D given alone in doses of 10-20 μg is not effective in preventing fractures. By contrast, calcium and vitamin D given together reduce hip fractures and total fractures, and probably vertebral fractures, irrespective of age, sex, or previous fractures.The WHI program is funded by the National Heart, Lung, and Blood Institute, National Institutes of Health, US Department of Health and Human Services through contracts N01WH22110, 24152, 32100-2, 32105-6, 32108-9, 32111-13, 32115, 32118-32119, 32122, 42107-26, 42129-32, and 44221. AA acknowledges personal funding from the UK Medical Research Council and Chief Scientist Office of the Scottish Government Health Directorates
Rotation, magnetism, and metallicity of M dwarf systems
Close M-dwarf binaries and higher multiples allow the investigation of
rotational evolution and mean magnetic flux unbiased from scatter in
inclination angle and age since the orientation of the spin axis of the
components is most likely parallel and the individual systems are coeval.
Systems composed of an early (M0.0 -- M4.0) and a late (M4.0 -- M8.0) type
component offer the possibility to study differences in rotation and magnetism
between partially and fully convective stars. We have selected 10 of the
closest dM systems to determine the rotation velocities and the mean magnetic
field strengths based on spectroscopic analysis of FeH lines of Wing-Ford
transitions at 1 m observed with VLT/CRIRES. We also studied the quality
of our spectroscopic model regarding atmospheric parameters including
metallicity. A modified version of the Molecular Zeeman Library (MZL) was used
to compute Land\'e g-factors for FeH lines. Magnetic spectral synthesis was
performed with the Synmast code. We confirmed previously reported findings that
less massive M-dwarfs are braked less effectively than objects of earlier
types. Strong surface magnetic fields were detected in primaries of four
systems (GJ 852, GJ 234, LP 717-36, GJ 3322), and in the secondary of the
triple system GJ 852. We also confirm strong 2 kG magnetic field in the primary
of the triple system GJ 2005. No fields could be accurately determined in
rapidly rotating stars with \vsini>10 \kms. For slow and moderately rotating
stars we find the surface magnetic field strength to increase with the
rotational velocity \vsini which is consistent with other results from
studying field stars.Comment: Accepted by MNRAS, 10 pages, 4 figures, 4 table
Iron porphyrin molecules on Cu(001): Influence of adlayers and ligands on the magnetic properties
The structural and magnetic properties of Fe octaethylporphyrin (OEP)
molecules on Cu(001) have been investigated by means of density functional
theory (DFT) methods and X-ray absorption spectroscopy. The molecules have been
adsorbed on the bare metal surface and on an oxygen-covered surface, which
shows a reconstruction. In order to allow
for a direct comparison between magnetic moments obtained from sum-rule
analysis and DFT we calculate the dipolar term , which is also
important in view of the magnetic anisotropy of the molecule. The measured
X-ray magnetic circular dichroism shows a strong dependence on the photon
incidence angle, which we could relate to a huge value of , e.g. on
Cu(001) amounts to -2.07\,\mbo{} for normal incidence leading to a
reduction of the effective spin moment . Calculations have also
been performed to study the influence of possible ligands such as Cl and O
atoms on the magnetic properties of the molecule and the interaction between
molecule and surface, because the experimental spectra display a clear
dependence on the ligand, which is used to stabilize the molecule in the gas
phase. Both types of ligands weaken the hybridization between surface and
porphyrin molecule and change the magnetic spin state of the molecule, but the
changes in the X-ray absorption are clearly related to residual Cl ligands.Comment: 17 figures, full articl
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