205 research outputs found

    Spin-dependent transport in molecular tunnel junctions

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    We present measurements of magnetic tunnel junctions made using a self-assembled-monolayer molecular barrier. Ni/octanethiol/Ni samples were fabricated in a nanopore geometry. The devices exhibit significant changes in resistance as the angle between the magnetic moments in the two electrodes is varied, demonstrating that low-energy electrons can traverse the molecular barrier while maintaining spin coherence. An analysis of the voltage and temperature dependence of the data suggests that the spin-coherent transport signals can be degraded by localized states in the molecular barriers.Comment: 4 pages, 5 color figure

    Controlling the stereochemistry and regularity of butanethiol self-assembled monolayers on Au(111)

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    © 2014 American Chemical Society. The rich stereochemistry of the self-assembled monolayers (SAMs) of four butanethiols on Au(111) is described, the SAMs containing up to 12 individual C, S, or Au chiral centers per surface unit cell. This is facilitated by synthesis of enantiomerically pure 2-butanethiol (the smallest unsubstituted chiral alkanethiol), followed by in situ scanning tunneling microscopy (STM) imaging combined with density functional theory molecular dynamics STM image simulations. Even though butanethiol SAMs manifest strong headgroup interactions, steric interactions are shown to dominate SAM structure and chirality. Indeed, steric interactions are shown to dictate the nature of the headgroup itself, whether it takes on the adatom-bound motif RS•Au(0)S•R or involves direct binding of RS• to face-centered-cubic or hexagonal-close-packed sites. Binding as RS• produces large, organizationally chiral domains even when R is achiral, while adatom binding leads to rectangular plane groups that suppress long-range expression of chirality. Binding as RS• also inhibits the pitting intrinsically associated with adatom binding, desirably producing more regularly structured SAMs

    CosmoCaixa PRINT3D: Reimprimir la realidad

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    "PRINT3D" is an exhibition that invites us to travel into the future through 3D printing. To what extent will it transform our day to day life and what will that mean for the current production system? A tour through this exhibition will help us discover the versatility of this technology. In it, we will find multiple practical applications in which 3D printing is already being used, in fields as diverse as medicine, construction or art. We will navigate through time thanks to 3D printing, discovering how it allows us to recreate extinct species or archaeological relics in great detail. But not only will we be able to travel to the past, but we will also imagine our future, making use of this type of impression in space and on other planets. In these settings where resources are very limited, the versatility of this technology is unmatched. How far will 3D printing take us
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