Raman spectroscopy study of the interface structure in (CaCuO2)n/(SrTiO3)m superlattices

Raman spectra of CaCuO2/SrTiO3 superlattices show clear spectroscopic marker of two structures formed in CaCuO2 at the interface with SrTiO3. For non-superconducting superlattices, grown in low oxidizing atmosphere, the 425 cm-1 frequency of oxygen vibration in CuO2 planes is the same as for CCO films with infinite layer structure (planar Cu-O coordination). For superconducting superlattices grown in highly oxidizing atmosphere, a 60 cm-1 frequency shift to lower energy occurs. This is ascribed to a change from planar to pyramidal Cu-O coordination because of oxygen incorporation at the interface. Raman spectroscopy proves to be a powerful tool for interface structure investigation

Correlation between the transition temperature and the superfluid density in BCS superconductor NbB_2+x

The results of the muon-spin rotation experiments on BCS superconductors NbB_2+x (x = 0.2, 0.34) are reported. Both samples, studied in the present work, exhibit rather broad transitions to the superconducting state, suggesting a distribution of the volume fractions with different transition temperatures (T_c)'s. By taking these distributions into account, the dependence of the inverse squared zero-temperature magnetic penetration depth (\lambda_0^{-2}) on T_c was reconstructed for temperatures in the range 1.5K<T_c<8.0K. \lambda_0^{-2} was found to obey the power law dependence \lambda_0^{-2}\propto T_c^{3.1(1)} which appears to be common for some families of BCS superconductors as, {\it e.g.}, Al doped MgB_2 and high-temperature cuprate superconductors as underdoped YBa_2Cu_3O_{7-\delta}.Comment: 9 pages, 7 figures. Accepted for publication in Phys. Rev.

Effect of Al doping on the optical phonon spectrum in Mg(1-x)Al(x)B(2)

Raman and infrared absorption spectra of Mg(1-x)Al(x)B(2) have been collected for 0<x<0.5 in the spectral range of optical phonons. The x-dependence of the peak frequency, the width and the intensity of the observed Raman lines has been carefully analized. A peculiar x-dependence of the optical modes is pointed out for two different Al doping ranges. In particular the onset of the high-doping structural phase previously observed in diffraction measurements is marked by the appearence of new spectral components at high frequencies. A connection between the whole of our results and the observed suppression of superconductivity in the high doping region is established

Infrared properties of Mg1−x_{1-x}Alx(_x(B1−y_{1-y}Cy_{y})2_2 single crystals in the normal and superconducting state

The reflectivity $R (\omega)$ of $ab$-oriented Mg$_{1-x}$Al$_x$(B$_{1-y }$C$_y$)$_2$ single crystals has been measured by means of infrared microspectroscopy for $1300<\omega<17000$ cm$^{-1}$. An increase with doping of the scattering rates in the $\pi$ and $\sigma$ bands is observed, being more pronounced in the C doped crystals. The $\sigma$-band plasma frequency also changes with doping due to the electron doping, while the $\pi$-band one is almost unchanged. Moreover, a $\sigma\to\sigma$ interband excitation, predicted by theory, is observed at $\omega_{IB} \simeq 0.47$ eV in the undoped sample, and shifts to lower energies with doping. By performing theoretical calculation of the doping dependence $\omega_{IB}$, the experimental observations can be explained with the increase with electron doping of the Fermi energy of the holes in the $\sigma$-band. On the other hand, the $\sigma$ band density of states seems not to change substantially. This points towards a $T_c$ reduction driven mainly by disorder, at least for the doping level studied here. The superconducting state has been also probed by infrared synchrotron radiation for $30<\omega<150$ cm$^{-1}$ in one pure and one C-doped sample. In the undoped sample ($T_c$ = 38.5 K) a signature of the $\pi$-gap only is observed. At $y$ = 0.08 ($T_c$ = 31.9 K), the presence of the contribution of the $\sigma$-gap indicates dirty-limit superconductivity in both bands.Comment: 12 pages, 9 figure

Study of pressure effect on the magnetic penetration depth in MgB2_2

A study of the pressure effect on the magnetic penetration depth $\lambda$ in polycrystalline MgB$_{2}$ was performed by measuring the temperature dependence of the magnetization under an applied pressure of 0.15 and 1.13 GPa. We found that $\lambda^{-2}$ at low temperature is only slightly affected by pressure [$\frac{\Delta \lambda^{-2}}{\lambda^{-2}} = 1.5(9)$], in contrast to cuprate superconductors, where, in the same range of pressure, a very large effect on $\lambda^{-2}$ was found. Theoretical estimates indicate that most of the pressure effect on $\lambda^{-2}$ in MgB$_2$ arises from the electron-phonon interaction.Comment: 5 pages, 2 figure

Coexistence of pressure-induced structural phases in bulk black phosphorus: a combined x-ray diffraction and Raman study up to 18 GPa

We report a study of the structural phase transitions induced by pressure in bulk black phosphorus by using both synchrotron x-ray diffraction for pressures up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black phosphorus attracted large attention because of the unique properties of fewlayers samples (phosphorene), but some basic questions are still open in the case of the bulk system. As concerning the presence of a Raman spectrum above 10 GPa, which should not be observed in an elemental simple cubic system, we propose a new explanation by attributing a key role to the non-hydrostatic conditions occurring in Raman experiments. Finally, a combined analysis of Raman and XRD data allowed us to obtain quantitative information on presence and extent of coexistences between different structural phases from ~5 up to ~15 GPa. This information can have an important role in theoretical studies on pressure-induced structural and electronic phase transitions in black phosphorus