Improving polymer based photovoltaic devices by reducing the voltage loss at the donor-acceptor interface

The costs of large area, organic photovoltaic devices are stronly related to their module efficiency. Even for niche markets, such as consumer electronics, efficiency is imperative since the available area is limited. Therefore, if polymer photovoltaics is to become a mature technology, it is key to increase the power conversion efficiency of the devices. In our contribution an analysis is given of the energy loss factors in P3HT:[C6O]PCBM cells. The main loss occurs as a voltage loss at the donor-accpetor interface. Since this loss factor is linked to the HOMO-LUMO levels of the system, it is impossilble to reduce this loss using the same material combination. We present polymer: [C6O]PCBM cells with similar optical properties but with a reduced voltage loss at the interface, leading to enhanced open circuit Voltage of 1.0 V (compared to 0.62 V for P3HT:[C6O]PCBM devices). The polymer is an alternating copolymer with fluorence and benzothiadiazole units (PFTBT). Well-characterised devices yield already an AM 1.5 efficiency of 4%, thus competing with state-of-the-art P3HT:PCBM devices

X-ray imager using solution processed organic transistor arrays and bulk heterojunction photodiodes on thin, flexible plastic substrate

\u3cp\u3eWe describe the fabrication and characterization of large-area active-matrix X-ray/photodetector array of high quality using organic photodiodes and organic transistors. All layers with the exception of the electrodes are solution processed. Because it is processed on a very thin plastic substrate of 25 mu;m thickness, the photodetector is only 100 mu;m thick. When combined with an 300-μm-thick X-ray scintillator, this gives a thin, low-weight and shatterproof X-ray detector of ca. 400 mu;m thickness. We demonstrate X-ray imaging under conditions that are used in medical applications. \u3c/p\u3

X-ray imaging sensor arrays on foil using solution processed organic photodiodes and organic transistors

\u3cp\u3eWe demonstrate organic imaging sensor arrays fabricated on flexible plastic foil with the solution processing route for both photodiodes and thin film transistors. We used the photovoltaic P3HT:PCBM blend for fabricating the photodiodes using spin coating and pentacene as semiconductor material for the TFTs. Photodiodes fabricated with P3HT:PCBM absorb in the green part of the visible spectrum which matches with the typical scintillator output wavelength. The arrays consist of 32x32 pixels with variation in pixel resolution of 200μmx200μm, 300μmx300μm and of 1mmx1mm. The accurate reproducibility of shadow images of the objects demonstrates the potential of these arrays for imaging purposes. We also demonstrate that the crosstalk is relatively insignificant despite the fact that the active photodiode forms a continuous layer in the array. Since both photodiodes and TFTs are made of organic material, they are processed at low temperatures below 150°C on foil which means that these imaging sensors can be flexible, light weight and low cost when compared to conventional amorphous silicon based imaging sensors on rigid substrates. In combination with a scintillator on top of the arrays, we show the potential of these arrays for the X-ray imaging applications. \u3c/p\u3

The effect of three-dimensional morphology on the efficiency of hybrid polymer solar cells

The efficiency of polymer solar cells critically depends on the intimacy of mixing of the donor and acceptor semiconductors used in these devices to create charges and on the presence of unhindered percolation pathways in the individual components to transport holes and electrons. The visualization of these bulk heterojunction morphologies in three dimensions has been challenging and has hampered progress in this area. Here, we spatially resolve the morphology of 2%-efficient hybrid solar cells consisting of poly(3-hexylthiophene) as the donor and ZnO as the acceptor in the nanometre range by electron tomography. The morphology is statistically analysed for spherical contact distance and percolation pathways. Together with solving the three-dimensional exciton-diffusion equation, a consistent and quantitative correlation between solar-cell performance, photophysical data and the three-dimensional morphology has been obtained for devices with different layer thicknesses that enables differentiating between generation and transport as limiting factors to performance.