Mixed state Pauli channel parameter estimation

The accuracy of any physical scheme used to estimate the parameter describing the strength of a single qubit Pauli channel can be quantified using standard techniques from quantum estimation theory. It is known that the optimal estimation scheme, with m channel invocations, uses initial states for the systems which are pure and unentangled and provides an uncertainty of O[1/m^(1/2)]. This protocol is analogous to a classical repetition and averaging scheme. We consider estimation schemes where the initial states available are not pure and compare a protocol involving quantum correlated states to independent state protocols analogous to classical repetition schemes. We show, that unlike the pure state case, the quantum correlated state protocol can yield greater estimation accuracy than any independent state protocol. We show that these gains persist even when the system states are separable and, in some cases, when quantum discord is absent after channel invocation. We describe the relevance of these protocols to nuclear magnetic resonance measurements

On the physical origins of the negative index of refraction

The physical origins of negative refractive index are derived from a dilute microscopic model, producing a result that is generalized to the dense condensed phase limit. In particular, scattering from a thin sheet of electric and magnetic dipoles driven above resonance is used to form a fundamental description for negative refraction. Of practical significance, loss and dispersion are implicit in the microscopic model. While naturally occurring negative index materials are unavailable, ferromagnetic and ferroelectric materials provide device design opportunities.Comment: 4 pages, 1 figur

Nuclear magnetic resonance spectroscopy: An experimentally accessible paradigm for quantum computing

We present experimental results which demonstrate that nuclear magnetic resonance spectroscopy is capable of efficiently emulating many of the capabilities of quantum computers, including unitary evolution and coherent superpositions, but without attendant wave-function collapse. Specifically, we have: (1) Implemented the quantum XOR gate in two different ways, one using Pound-Overhauser double resonance, and the other using a spin-coherence double resonance pulse sequence; (2) Demonstrated that the square root of the Pound-Overhauser XOR corresponds to a conditional rotation, thus obtaining a universal set of gates; (3) Devised a spin-coherence implementation of the Toffoli gate, and confirmed that it transforms the equilibrium state of a four-spin system as expected; (4) Used standard gradient-pulse techniques in NMR to equalize all but one of the populations in a two-spin system, so obtaining the pseudo-pure state that corresponds to |00>; (5) Validated that one can identify which basic pseudo-pure state is present by transforming it into one-spin superpositions, whose associated spectra jointly characterize the state; (6) Applied the spin-coherence XOR gate to a one-spin superposition to create an entangled state, and confirmed its existence by detecting the associated double-quantum coherence via gradient-echo methods.Comment: LaTeX + epsfig + amsmath packages, 27 pages, 12 figures, to appear in Physica D; revision updates list of authors and reference

Understanding High Temperature Superconductors: Progress and Prospects

I review progress in measurements of the dynamic spin susceptibility in the normal state which yield a new phase diagram and discuss microscopic calculations which yield qualitative, and in many cases, quantitative agreement with the measured changes in the quasiparticle, transport, magnetotransport, and optical properties of the cuprate superconductors as one varies doping and temperature provided one describes the systems as nearly anti-ferromagnetic Fermi liquids in which the effective magnetic interaction between planar quasiparticles mirrors the dynamic spin susceptibility measured in NMR and INS experiments. Together with the demonstration that the NAFL pairing potential leads inexorably to a d_x2-y2,pairing state, this work provides a "proof of concept" for the NAFL description of high Tc materials. I review Eliashberg calculations of the mean-field behavior found in overdoped systems and discuss the extent to which the crossovers to pseudoscaling and pseudogap behavior found in the effective magnetic interaction and quasiparticle behavior in the optimally doped and underdoped systems may be derived microscopically. I conclude with a tentative scenario for the dependence of Tc on doping level and imperfections in different systems.Comment: 6 pages, 1 figure. To appear in a special issue of Physica C of the M2S-HTSC-V Conference held Feb. 28-Mar. 4, 1997, in Beijing, Chin

Smile: A Simple Diagnostic for Selection on Observables

This paper develops a simple diagnostic for the selection on observables assumption in the case of a binary treatment variable. I show that, under common assumptions, when selection on observables does not hold, designs based on selection on observables will estimate treatment effects approaching infinity or negative infinity among observations with propensity scores close to 0 or 1. Researchers can check for violations of selection on observables either informally by looking for a "smile" shape in a binned scatterplot, or with a simple formal test. When selection on observables fails, the researcher can detect the sign of the resulting bias

Smile: A Simple Diagnostic for Selection on Observables

This paper develops a simple diagnostic for the selection on observables assumption in the case of a binary treatment variable. I show that, under common assumptions, when selection on observables does not hold, designs based on selection on observables will estimate treatment effects approaching infinity or negative infinity among observations with propensity scores close to 0 or 1. Researchers can check for violations of selection on observables either informally by looking for a "smile" shape in a binned scatterplot, or with a simple formal test. When selection on observables fails, the researcher can detect the sign of the resulting bias

NMR multiple quantum coherences in quasi-one-dimensional spin systems: Comparison with ideal spin-chain dynamics

The 19F spins in a crystal of fluorapatite have often been used to experimentally approximate a one-dimensional spin system. Under suitable multi-pulse control, the nuclear spin dynamics may be modeled to first approximation by a double-quantum one-dimensional Hamiltonian, which is analytically solvable for nearest-neighbor couplings. Here, we use solid-state nuclear magnetic resonance techniques to investigate the multiple quantum coherence dynamics of fluorapatite, with an emphasis on understanding the region of validity for such a simplified picture. Using experimental, numerical, and analytical methods, we explore the effects of long-range intra-chain couplings, cross-chain couplings, as well as couplings to a spin environment, all of which tend to damp the oscillations of the multiple quantum coherence signal at sufficiently long times. Our analysis characterizes the extent to which fluorapatite can faithfully simulate a one-dimensional quantum wire.Comment: 14 pages, 11 eps color figure

Motional diminishing of optical activity: a novel method for studying molecular dynamics in liquids and plastic crystals

Molecular dynamics calculations and optical spectroscopy measurements of weakly active infrared modes are reported. The results are qualitatively understood in terms of the "motional diminishing" of IR lines, a process analogous to the motional narrowing of a nuclear magnetic resonance (NMR) signal. In molecular solids or liquids where the appropriate intramolecular resonances are observable, motional diminishing can be used to study the fluctuations of the intermolecular interactions having time scales of 1psec to 100psec.Comment: RevTeX in LaTeX file, 12 preprint pages, 4 ps figures included. Also available from http://insti.physics.sunysb.edu/~mmartin/pubs.html Accepted for publication in Chem. Phys. Let