High Photovoltaic Quantum Efficiency in Ultrathin van der Waals Heterostructures

We report experimental measurements for ultrathin (< 15 nm) van der Waals heterostructures exhibiting external quantum efficiencies exceeding 50%, and show that these structures can achieve experimental absorbance > 90%. By coupling electromagnetic simulations and experimental measurements, we show that pn WSe2/MoS2 heterojunctions with vertical carrier collection can have internal photocarrier collection efficiencies exceeding 70%.Comment: ACS Nano, 2017. Manuscript (25 pages, 7 figures) plus supporting information (7 pages, 4 figures

Electrical Control of Linear Dichroism in Black Phosphorus from the Visible to Mid-Infrared

The incorporation of electrically tunable materials into photonic structures such as waveguides and metasurfaces enables dynamic control of light propagation by an applied potential. While many materials have been shown to exhibit electrically tunable permittivity and dispersion, including transparent conducting oxides (TCOs) and III-V semiconductors and quantum wells, these materials are all optically isotropic in the propagation plane. In this work, we report the first known example of electrically tunable linear dichroism, observed here in few-layer black phosphorus (BP), which is a promising candidate for multi-functional, broadband, tunable photonic elements. We measure active modulation of the linear dichroism from the mid-infrared to visible frequency range, which is driven by anisotropic quantum-confined Stark and Burstein-Moss effects, and field-induced forbidden-to-allowed optical transitions. Moreover, we observe high BP absorption modulation strengths, approaching unity for certain thicknesses and photon energies

Methane and carbon dioxide adsorption on edge-functionalized graphene: A comparative DFT study

With a view towards optimizing gas storage and separation in crystalline and disordered nanoporous carbon-based materials, we use ab initio density functional theory calculations to explore the effect of chemical functionalization on gas binding to exposed edges within model carbon nanostructures. We test the geometry, energetics, and charge distribution of in-plane and out-of-plane binding of CO2 and CH4 to model zigzag graphene nanoribbons edge-functionalized with COOH, OH, NH2, H2PO3, NO2, and CH3. Although different choices for the exchange-correlation functional lead to a spread of values for the binding energy, trends across the functional groups are largely preserved for each choice, as are the final orientations of the adsorbed gas molecules. We find binding of CO2 to exceed that of CH4 by roughly a factor of two. However, the two gases follow very similar trends with changes in the attached functional group, despite different molecular symmetries. Our results indicate that the presence of NH2, H2PO3, NO2, and COOH functional groups can significantly enhance gas binding with respect to a hydrogen-passivated edge, making the edges potentially viable binding sites in materials with high concentrations of edge carbons. To first order, in-plane binding strength correlates with the larger permanent and induced dipole moments on these groups. Implications for tailoring carbon structures for increased gas uptake and improved CO2/CH4 selectivity are discussed.Comment: 12 pages, 7 figure

Exploring the Expanding Universe and Dark Energy using the Statefinder Diagnostic

The coming few years are likely to witness a dramatic increase in high quality Sn data as current surveys add more high redshift supernovae to their inventory and as newer and deeper supernova experiments become operational. Given the current variety in dark energy models and the expected improvement in observational data, an accurate and versatile diagnostic of dark energy is the need of the hour. This paper examines the Statefinder diagnostic in the light of the proposed SNAP satellite which is expected to observe about 2000 supernovae per year. We show that the Statefinder is versatile enough to differentiate between dark energy models as varied as the cosmological constant on the one hand, and quintessence, the Chaplygin gas and braneworld models, on the other. Using SNAP data, the Statefinder can distinguish a cosmological constant ($w=-1$) from quintessence models with $w \geq -0.9$ and Chaplygin gas models with $\kappa \leq 15$ at the $3\sigma$ level if the value of \om is known exactly. The Statefinder gives reasonable results even when the value of \om is known to only $\sim 20$ accuracy. In this case, marginalizing over \om and assuming a fiducial LCDM model allows us to rule out quintessence with $w \geq -0.85$ and the Chaplygin gas with $\kappa \leq 7$ (both at $3\sigma$). These constraints can be made even tighter if we use the Statefinders in conjunction with the deceleration parameter. The Statefinder is very sensitive to the total pressure exerted by all forms of matter and radiation in the universe. It can therefore differentiate between dark energy models at moderately high redshifts of z \lleq 10.Comment: 21 pages, 17 figures. Minor typos corrected to agree with version published in MNRAS. Results unchange