Transport Theory beyond Binary Collisions

Using the Schwinger-Keldysh technique, we derive the transport equations for a system of quantum scalar fields. We first discuss the general structure of the equations and then their collision terms. Taking into account up to three-loop diagrams in \phi^3 model and up to four-loop diagrams in \phi^4 model, we obtain the transport equations which include the contributions of multi-particle collisions and particle production processes, in addition to mean-field effects and binary interactions.Comment: 30 pages, 21 figures, minor changes, to appear in Phys. Rev.

Molecular and mass spectroscopic analysis of isotopically labeled organic residues

Experimental studies aimed at understanding the evolution of complex organic molecules on interstellar grains were performed. The photolysis of frozen gas mixtures of various compositions containing H2O, CO, NH3, and CH4 was studied. These species were chosen because of their astrophysical importance as deducted from observational as well as theoretical studies of ice mantles on interstellar grains. These ultraviolet photolyzed ices were warmed up in order to produce refractory organic molecules like the ones formed in molecular clouds when the icy mantles are being irradiated and warmed up either by a nearby stellar source or impulsive heating. The laboratory studies give estimates of the efficiency of production of such organic material under interstellar conditions. It is shown that the gradual carbonization of organic mantles in the diffuse cloud phase leads to higher and higher visual absorptivity - yellow residues become brown in the laboratory. The obtained results can be applied to explaining the organic components of comets and their relevance to the origin of life

Phase space spinor amplitudes for spin 1/2 systems

The concept of phase space amplitudes for systems with continuous degrees of freedom is generalized to finite-dimensional spin systems. Complex amplitudes are obtained on both a sphere and a finite lattice, in each case enabling a more fundamental description of pure spin states than that previously given by Wigner functions. In each case the Wigner function can be expressed as the star product of the amplitude and its conjugate, so providing a generalized Born interpretation of amplitudes that emphasizes their more fundamental status. The ordinary product of the amplitude and its conjugate produces a (generalized) spin Husimi function. The case of spin-\half is treated in detail, and it is shown that phase space amplitudes on the sphere transform correctly as spinors under under rotations, despite their expression in terms of spherical harmonics. Spin amplitudes on a lattice are also found to transform as spinors. Applications are given to the phase space description of state superposition, and to the evolution in phase space of the state of a spin-\half magnetic dipole in a time-dependent magnetic field.Comment: 19 pages, added new results, fixed typo

Phenomenological approach to the critical dynamics of the QCD phase transition revisited

The phenomenological dynamics of the QCD critical phenomena is revisited. Recently, Son and Stephanov claimed that the dynamical universality class of the QCD phase transition belongs to model H. In their discussion, they employed a time-dependent Ginzburg-Landau equation for the net baryon number density, which is a conserved quantity. We derive the Langevin equation for the net baryon number density, i.e., the Cahn-Hilliard equation. Furthermore, they discussed the mode coupling induced through the {\it irreversible} current. Here, we show the {\it reversible} coupling can play a dominant role for describing the QCD critical dynamics and that the dynamical universality class does not necessarily belong to model H.Comment: 13 pages, the Curie principle is discussed in S.2, to appear in J.Phys.

Minimum Decision Cost for Quantum Ensembles

For a given ensemble of $N$ independent and identically prepared particles, we calculate the binary decision costs of different strategies for measurement of polarised spin 1/2 particles. The result proves that, for any given values of the prior probabilities and any number of constituent particles, the cost for a combined measurement is always less than or equal to that for any combination of separate measurements upon sub-ensembles. The Bayes cost, which is that associated with the optimal strategy (i.e., a combined measurement) is obtained in a simple closed form.Comment: 11 pages, uses RevTe

Estimation of a probability in inverse binomial sampling under normalized linear-linear and inverse-linear loss

Sequential estimation of the success probability $p$ in inverse binomial sampling is considered in this paper. For any estimator $\hat p$, its quality is measured by the risk associated with normalized loss functions of linear-linear or inverse-linear form. These functions are possibly asymmetric, with arbitrary slope parameters $a$ and $b$ for $\hat pp$ respectively. Interest in these functions is motivated by their significance and potential uses, which are briefly discussed. Estimators are given for which the risk has an asymptotic value as $p$ tends to $0$, and which guarantee that, for any $p$ in $(0,1)$, the risk is lower than its asymptotic value. This allows selecting the required number of successes, $r$, to meet a prescribed quality irrespective of the unknown $p$. In addition, the proposed estimators are shown to be approximately minimax when $a/b$ does not deviate too much from $1$, and asymptotically minimax as $r$ tends to infinity when $a=b$.Comment: 4 figure

The cytoplasm of living cells: A functional mixture of thousands of components

Inside every living cell is the cytoplasm: a fluid mixture of thousands of different macromolecules, predominantly proteins. This mixture is where most of the biochemistry occurs that enables living cells to function, and it is perhaps the most complex liquid on earth. Here we take an inventory of what is actually in this mixture. Recent genome-sequencing work has given us for the first time at least some information on all of these thousands of components. Having done so we consider two physical phenomena in the cytoplasm: diffusion and possible phase separation. Diffusion is slower in the highly crowded cytoplasm than in dilute solution. Reasonable estimates of this slowdown can be obtained and their consequences explored, for example, monomer-dimer equilibria are established approximately twenty times slower than in a dilute solution. Phase separation in all except exceptional cells appears not to be a problem, despite the high density and so strong protein-protein interactions present. We suggest that this may be partially a byproduct of the evolution of other properties, and partially a result of the huge number of components present.Comment: 11 pages, 1 figure, 1 tabl

Channel kets, entangled states, and the location of quantum information

The well-known duality relating entangled states and noisy quantum channels is expressed in terms of a channel ket, a pure state on a suitable tripartite system, which functions as a pre-probability allowing the calculation of statistical correlations between, for example, the entrance and exit of a channel, once a framework has been chosen so as to allow a consistent set of probabilities. In each framework the standard notions of ordinary (classical) information theory apply, and it makes sense to ask whether information of a particular sort about one system is or is not present in another system. Quantum effects arise when a single pre-probability is used to compute statistical correlations in different incompatible frameworks, and various constraints on the presence and absence of different kinds of information are expressed in a set of all-or-nothing theorems which generalize or give a precise meaning to the concept of ``no-cloning.'' These theorems are used to discuss: the location of information in quantum channels modeled using a mixed-state environment; the $CQ$ (classical-quantum) channels introduced by Holevo; and the location of information in the physical carriers of a quantum code. It is proposed that both channel and entanglement problems be classified in terms of pure states (functioning as pre-probabilities) on systems of $p\geq 2$ parts, with mixed bipartite entanglement and simple noisy channels belonging to the category $p=3$, a five-qubit code to the category $p=6$, etc.; then by the dimensions of the Hilbert spaces of the component parts, along with other criteria yet to be determined.Comment: Latex 32 pages, 4 figures in text using PSTricks. Version 3: Minor typographical errors correcte

Error estimates for solid-state density-functional theory predictions: an overview by means of the ground-state elemental crystals

Predictions of observable properties by density-functional theory calculations (DFT) are used increasingly often in experimental condensed-matter physics and materials engineering as data. These predictions are used to analyze recent measurements, or to plan future experiments. Increasingly more experimental scientists in these fields therefore face the natural question: what is the expected error for such an ab initio prediction? Information and experience about this question is scattered over two decades of literature. The present review aims to summarize and quantify this implicit knowledge. This leads to a practical protocol that allows any scientist - experimental or theoretical - to determine justifiable error estimates for many basic property predictions, without having to perform additional DFT calculations. A central role is played by a large and diverse test set of crystalline solids, containing all ground-state elemental crystals (except most lanthanides). For several properties of each crystal, the difference between DFT results and experimental values is assessed. We discuss trends in these deviations and review explanations suggested in the literature. A prerequisite for such an error analysis is that different implementations of the same first-principles formalism provide the same predictions. Therefore, the reproducibility of predictions across several mainstream methods and codes is discussed too. A quality factor Delta expresses the spread in predictions from two distinct DFT implementations by a single number. To compare the PAW method to the highly accurate APW+lo approach, a code assessment of VASP and GPAW with respect to WIEN2k yields Delta values of 1.9 and 3.3 meV/atom, respectively. These differences are an order of magnitude smaller than the typical difference with experiment, and therefore predictions by APW+lo and PAW are for practical purposes identical.Comment: 27 pages, 20 figures, supplementary material available (v5 contains updated supplementary material

Classical Equations for Quantum Systems

The origin of the phenomenological deterministic laws that approximately govern the quasiclassical domain of familiar experience is considered in the context of the quantum mechanics of closed systems such as the universe as a whole. We investigate the requirements for coarse grainings to yield decoherent sets of histories that are quasiclassical, i.e. such that the individual histories obey, with high probability, effective classical equations of motion interrupted continually by small fluctuations and occasionally by large ones. We discuss these requirements generally but study them specifically for coarse grainings of the type that follows a distinguished subset of a complete set of variables while ignoring the rest. More coarse graining is needed to achieve decoherence than would be suggested by naive arguments based on the uncertainty principle. Even coarser graining is required in the distinguished variables for them to have the necessary inertia to approach classical predictability in the presence of the noise consisting of the fluctuations that typical mechanisms of decoherence produce. We describe the derivation of phenomenological equations of motion explicitly for a particular class of models. Probabilities of the correlations in time that define equations of motion are explicitly considered. Fully non-linear cases are studied. Methods are exhibited for finding the form of the phenomenological equations of motion even when these are only distantly related to those of the fundamental action. The demonstration of the connection between quantum-mechanical causality and causalty in classical phenomenological equations of motion is generalized. The connections among decoherence, noise, dissipation, and the amount of coarse graining necessary to achieve classical predictability are investigated quantitatively.Comment: 100pages, 1 figur