Dilational rheology and relaxation properties of the adsorption layers of electrostatic complexes between Eudragit RS and chitosan sulfate at the methylene chloride-water interface.

International audienceThe electrostatic interpolyelectrolyte complex formation between the hydrophobic cationic polyelectrolyte Eudragit RS and the anionic hydrophilic polyelectrolyte chitosan sulfate at the methylene chloride–water interface has been studied by dilational rheometry

An infrared investigation in relation with chitin and chitosan characterization

© 2001 Elsevier Science Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted Manuscript version of a Published Work that appeared in final form in Polymer. To access the final edited and published work see https://doi.org/10.1016/S0032-3861(00)00713-8The use of infrared spectroscopy for characterization of the composition of chitin and chitosan covering the entire range of degree of acetylation (DA) and a wide variety of raw materials is examined further. The ratio of absorbance bands selected was calibrated using 1H liquid and 13C CP-MAS solid-state NMR as absolute techniques. IR spectra of the structural units of these polymers validated the choice of baselines and characteristic bands. The bands at 1650 and 1320 cm-1 were chosen to measure the DA. As internal reference, the intensities at 3450 and 1420 cm-1 were evaluated. The absorption band ratios involving the reference at 3450 cm-1 had poorer fit. The absorption ratio A1320/A1420 shows superior agreement between the absolute and estimated DA-values (DA% = 31.92A1320/A1420 - 12.20; r = 0.990

Dilational viscoelasticity and relaxation properties of interfacial electrostatic complexes between oppositely charged hydrophobic and hydrophilic polyelectrolytes

Strongly adsorbing hydrophobic cationic polyelectrolyte, Eudragit RS, containing approximately 2.5 mol% of pendent hydrophilic trimethylammonium (TMA) groups irreversibly adsorbs from its methylene chloride (MCl) solution at the MCl/water interface and forms solid-like adsorption layers (ALs). Submitted to periodic dilational deformations with the standard radial frequency omega(0)=0.63 rad/s, these ALs exhibit relatively high dilational storage modulus E\u27 approximately 20 mN/m and practically zero loss modulus E\u27\u27 at the bulk concentration C(Eud)=4 x 10(-3)g/L. The frequency scanning of these ALs in the diapason omega=0.01-0.63rad/s and the approximation of the experimental dependences E\u27(omega) and E\u27\u27(omega) by two relaxation times rheological model makes it possible to estimate the crossing frequency of these ALs determined from the condition E\u27(omega(c))=E\u27\u27(omega(c)) as omega(c) approximately 5 x 10(-4)rad/s. Upon dissolving the hydrophilic anionic polyelectrolyte, chitosan sulfate (ChS), in the water phase (C(ChS)=3 x 10(-2)g/L) the electrostatic interpolyelectrolyte complexes form at the MCl/water interface. The elasticity moduli E\u27 and E\u27\u27 of these mixed AL did not undergo remarkable variations, but the crossing frequency is sharply increased by approximately 10 times becoming equal to omega(c) congruent with 3 x 10(-3)rad/s. The increase of omega(c) certifies for the liquefaction of mixed Eudragit RS/ChS adsorption layers. A remarkable decrease of the storage modulus down to E\u27=8 mN/m and simultaneous increase of the crossing frequency up to omega(c) congruent with 10(-2)rad/s occurs upon increasing the concentrations of both components, Eudragit RS and ChS, up to 0.1g/L. The liquefaction effect in the mixed ALs of oppositely charged polyelectrolytes was explained on the basis of the proposed relaxation mechanism. The effect of the liquefaction of adsorption layers of strongly adsorbing hydrophobic polyelectrolytes by formation of interpolyelectrolyte complexes with hydrophilic polyelectrolytes must be taken into account in the production of nano-capsules and nano-fibers

Methyl cellulose/cellulose nanocrystal nanocomposite fibers with high ductility

Methylcellulose/cellulose nanocrystal (MC/CNC) nanocomposite fibers showing high ductility and high modulus of toughness were prepared by a simple aqueous wet-spinning from corresponding nanocomposite hydrogels into ethanol coagulation bath followed by drying. The hydrogel MC aq. concentration was maintained at 1 wt-% while the CNC aq. loading was systematically varied in the range 0 – 3 wt-%. This approach resulted in MC/CNC fiber compositions from 25/75 wt-%/wt-% to 95/5 wt-%/wt-%. The optimal mechanical properties were achieved with the MC/CNC composition of 80/20 wt-%/wt-% allowing high strain (36.1 %) and modulus of toughness (48.3 MJ/m3), still keeping a high strength (190 MPa). Further, we demonstrate that the continuous spinning of MC/CNC fibers is potentially possible. The results indicate possibilities to spin MC-based highly ductile composite fibers from environmentally benign aqueous solvents.Peer reviewe

Interactions of bile salts with a dietary fibre, methylcellulose, and impact on lipolysis

Methylcellulose (MC) has a demonstrated capacity to reduce fat absorption, hypothetically through bile salt (BS) activity inhibition. We investigated MC cholesterol-lowering mechanism, and compared the influence of two BS, sodium taurocholate (NaTC) and sodium taurodeoxycholate (NaTDC), which differ slightly by their architecture and exhibit contrasting functions during lipolysis. BS/MC bulk interactions were investigated by rheology, and BS behaviour at the MC/water interface studied with surface pressure and ellipsometry measurements. In vitro lipolysis studies were performed to evaluate the effect of BS on MC-stabilised emulsion droplets microstructure, with confocal microscopy, and free fatty acids release, with the pH-stat method. Our results demonstrate that BS structure dictates their interactions with MC, which, in turn, impact lipolysis. Compared to NaTC, NaTDC alters MC viscoelasticity more significantly, which may correlate with its weaker ability to promote lipolysis, and desorbs from the interface at lower concentrations, which may explain its higher propensity to destabilise emulsions

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Participation financière des salariés et organisation interne de l'entreprise

[eng] Many systems of compensation and incentives exist in France. Their aim is to distribute to the managers and other employees part of the profits or productivity they provide to the firm. Some of them are stocks or stock-options that give property rights on the company.. This article presents, in a first part, the consequences ofsuch systems on interest conflicts that may exist between owners and wage-earners (especially managers) of a firm.. The second part shows the incidences of those mecanisms on the control and authority systems of the firm, as well as on the allocation of power and property rights. [fre] Les systèmes de participation financière sont multiples et permettent à l'entreprise de rétrocéder à tout ou partie de ses salariés une fraction de la richesse qu'ils produisent, directement ou non. Ils permettent donc de stimuler les efforts des différentes catégories de personnels et peuvent aller jusqu'à les rendre propriétaires, dans des proportions plus ou moins importantes, de la firme qui les emploie.. La première partie de cet article a pour objet de présenter l'incidence de ces systèmes sur les conflits d'intérêt pouvant exister entre les propriétaires de l'entreprise et les différentes catégories de salariés, particulièrement les dirigeants.. La deuxième partie traite de l'impact de ces mécaniques sur le système de contrôle et d'autorité de la firme, ainsi que sur la répartition du pouvoir et des droits de propriété.