Predicting the Success of Invasive Species in the Great Bay Estuarine Researve

The University of New Hampshire Zoology Department reports on a study designed to continue monitoring the distribution of invasive species in the Great Bay Estuary and to carry out laboratory experiments designed to test the effects of salinity on ascidian mortality and determine predators of ascidian species. Researchers collected presence/absence and abundance data of invasive species at four sites within the Great Bay Estuarine System. The report gives a brief description of the results of the monitoring program to compare results obtained from 2006 to 2007 and to assess the response of ascidians to varying salinity and predators. This report specifically includes monitoring data from 2007 and results of laboratory and field experiments examining the effects of salinity and predators on ascidian distribution

Linear, third- and fifth-order nonlinear spectroscopy of a charge transfer system coupled to an underdamped vibration

We study hole, electron and exciton transport in a charge transfer system in the presence of underdamped vibrational motion. We analyze the signature of these processes in the linear and third-, and fifth-order nonlinear electronic spectra. Calculations are performed with a numerically exact hierarchical equations of motion method for an underdamped Brownian oscillator spectral density. We find that combining electron, hole and exciton transfer can lead to non-trivial spectra with more structure than with excitonic coupling alone. Traces taken during the waiting time of a two-dimensional spectrum are dominated by vibrational motion and do not reflect the electron, hole, and exciton dynamics directly. We find that the fifth-order nonlinear response is particularly sensitive to the charge transfer process. While third-order 2D spectroscopy detects the correlation between two coherences, fifth-order 2D spectroscopy (2D population spectroscopy) is here designed to detect correlations between the excited states during two different time periods

Does settlement plate material matter? The influence of substrate type on fouling community development

Benthic community composition and ascidian abundance can differ dramatically between adjacent man-made and natural substrates. Although multiple factors, including light exposure, surface orientation, predation exposure, and habitat type, are known to contribute to these patterns, few studies have directly tested the influence of substrate identity on community development. We compared fouling communities on settlement plates composed of commonly occurring natural (granite) and artificial (concrete, high density polyethylene, and PVC) marine materials deployed from late May to mid November 2014 from a floating dock in Newcastle, NH. We sought to determine if observed patterns resulted from differential recruitment onto substrate materials or post-settlement survival and growth. To do this, half of the plates were cleaned during bi-weekly examinations, and half were left un-cleaned. Preliminary analyses indicate that community composition differs between substrate types. These results will help us understand how substrate features contribute to non-native species establishment and habitat dominance, and may inform decisions regarding material usage in marine construction. These findings also underline the importance of settlement substrate choice in scientific studies, as plate material may influence experimental conclusions

Correlated fluctuations in the exciton dynamics and spectroscopy of DNA

The absorption of ultraviolet light creates excitations in DNA, which subsequently start moving in the helix. Their fate is important for an understanding of photo damage, and is determined by the interplay of electronic couplings between bases and the structure of the DNA environment. We model the effect of dynamical fluctuations in the environment and study correlation, which is present when multiple base pairs interact with the same mode in the environment. We find that the correlations strongly affect the exciton dynamics, and show how they are observed in the decay of the anisotropy as a function of a coherence and a population time in a non-linear optical experiment

On finite-size Lyapunov exponents in multiscale systems

We study the effect of regime switches on finite size Lyapunov exponents (FSLEs) in determining the error growth rates and predictability of multiscale systems. We consider a dynamical system involving slow and fast regimes and switches between them. The surprising result is that due to the presence of regimes the error growth rate can be a non-monotonic function of initial error amplitude. In particular, troughs in the large scales of FSLE spectra is shown to be a signature of slow regimes, whereas fast regimes are shown to cause large peaks in the spectra where error growth rates far exceed those estimated from the maximal Lyapunov exponent. We present analytical results explaining these signatures and corroborate them with numerical simulations. We show further that these peaks disappear in stochastic parametrizations of the fast chaotic processes, and the associated FSLE spectra reveal that large scale predictability properties of the full deterministic model are well approximated whereas small scale features are not properly resolved.Comment: Accepted for publication in Chao

Non-Markovian entanglement dynamics in the presence of system-bath coherence

A complete treatment of the entanglement of two-level systems, which evolves through the contact with a thermal bath, must include the fact that the system and the bath are not fully separable. Therefore, quantum coherent superpositions of system and bath states, which are almost never fully included in theoretical models, are invariably present when an entangled state is prepared experimentally. We show their importance for the time evolution of the entanglement of two qubits coupled to independent baths. In addition, our treatment is able to handle slow and low-temperature thermal baths.Comment: Accepted for publication in Phys. Rev. Lett