Atmospheric Pressure Humid Argon DBD Plasma for the Application of Sterilization - Measurement and Simulation of Hydrogen, Oxygen, and Hydrogen Peroxide Formation

Hydrogen, oxygen, and hydrogen peroxide have been measured downstream of an atmospheric pressure humid argon dielectric barrier discharge. The yield of the three species was studied as a function of the discharge power and gas flow rate. Hydrogen peroxide was measured after dissolution into water downstream of the discharge, while hydrogen and oxygen were measured in the gas phase. The production rates of both hydrogen and oxygen were found to be at least one order of magnitude greater than that of hydrogen peroxide. In all cases, the molar rate of molecular hydrogen production was more than twice that of molecular oxygen. At various total gas flow rate, and over a range of energy density of 0 to 1500 J/L, the concentration of hydrogen found at the reactor outlet varied from 0 to 1000 ppm, while oxygen reached a maximum concentration of about 400 ppm. The corresponding concentration of hydrogen peroxide that was calculated to have been in the reactor outlet gas did not exceed 11 ppm. Mechanisms for this system based on experiments and a numerical model are presented. The results of experiments on the use of post-discharge effluent gas of humid argon plasma for sterilization purposes (inactivation of E. Coli) bacteria are also presented and discussed in relation to the results of the chemical measurements and simulations

BIOLOGICAL APPLICATIONS OF ATMOSPHERIC PRESSURE DIELECTRIC BARRIER DISCHARGES

International audienceA reduction of more than 4 orders of magnitude of survivors was obtained by exposing a Bacillus Stearothermophilus spores - contaminated surface to an atmospheric pressure DBD post-discharge for 20 minutes. Decontamination mechanisms are investigated assuming that (i) inactivation is obtained when the bacteria DNA is fragmented, (ii) the protein coats are the main protection of the cell core DNA in the case of bacteria spores. The degradation of DNA (plasmid) and protein (RNAse A) samples submitted to the postdischarge is evaluated according to the operating conditions: gas composition, treatment time and sample state, i.e. hydrated or dried samples

RADIATION KINETICS AND CHEMICAL REACTIVITY OF BARRIER DISCHARGES IN HUMID ARGON

International audienceThe technique of spatially resolved cross-correlation spectroscopy was used to record two-dimensional luminosity distributions for the selected spectral bands of molecular nitrogen (λ=337.1 nm), OH-radical (λ=308 nm), and two spectral lines of excited Ar (λ=750.4 nm and λ=763.5 nm) emitted by the microdischarges of the barrier discharge in flowing humid argon at atmospheric pressure. Concentrations of two stable reaction products of H2O decomposition (H2 and O2) in argon plasma were determined experimentally as functions of humidity. Comparison of these results with the corresponding measurements of radiation kinetics permitted a detailed analysis of the influence of the discharge mechanism on its chemical reactivity in humid argon to be accomplished

A new climate index controlling winter wave activity along the Atlantic coast of Europe: The West Europe Pressure Anomaly

International audienceA pioneering and replicable method based on a 66-year numerical weather and wave hindcast is developed to optimize a climate index based on the sea level pressure (SLP) that best explains winter wave height variability along the coast of western Europe, from Portugal to UK (36–52 ∘ N). The resulting so-called Western Europe Pressure Anomaly (WEPA) is based on the sea level pressure gradient between the stations Valentia (Ireland) and Santa Cruz de Tenerife (Canary Islands). The WEPA positive phase reflects an intensified and southward shifted SLP difference between the Icelandic low and the Azores high, driving severe storms that funnel high-energy waves toward western Europe southward of 52 ∘ N. WEPA outscores by 25–150% the other leading atmospheric modes in explaining winter-averaged significant wave height, and even by a largest amount the winter-averaged extreme wave heights. WEPA is also the only index capturing the 2013/2014 extreme winter that caused widespread coastal erosion and flooding in western Europe

Renewed global partnerships and redesigned roadmaps for rabies prevention and control

Canine rabies, responsible for most human rabies deaths, is a serious global public health concern. This zoonosis is entirely preventable, but by focusing solely upon rabies prevention in humans, this "incurable wound" persists at high costs. Although preventing human deaths through canine rabies elimination is feasible, dog rabies control is often neglected, because dogs are not considered typical economic commodities by the animal health sector. Here, we demonstrate that the responsibility of managing rabies falls upon multiple sectors, that a truly integrated approach is the key to rabies elimination, and that considerable progress has been made to this effect. Achievements include the construction of global rabies networks and organizational partnerships; development of road maps, operational toolkits, and a blueprint for rabies prevention and control; and opportunities for scaling up and replication of successful programs. Progress must continue towards overcoming the remaining challenges preventing the ultimate goal of rabies elimination

Extreme wave activity during 2013/2014 winter and morphological impacts along the Atlantic coast of Europe

Studies of coastal vulnerability due to climate change tend to focus on the consequences of sea level rise, rather than the complex coastal responses resulting from changes to the extreme wave climate. Here we investigate the 2013/2014 winter wave conditions that severely impacted the Atlantic coast of Europe and demonstrate that this winter was the most energetic along most of the Atlantic coast of Europe since at least 1948. Along exposed open-coast sites, extensive beach and dune erosion occurred due to offshore sediment transport. More sheltered sites experienced less erosion and one of the sites even experienced accretion due to beach rotation induced by alongshore sediment transport. Storm wave conditions such as were encountered during the 2013/2014 winter have the potential to dramatically change the equilibrium state (beach gradient, coastal alignment, and nearshore bar position) of beaches along the Atlantic coast of Europe

Increased winter-mean wave height, variability and periodicity in the North-East Atlantic over 1949-2017

A 69-year (1948-2017) numerical weather and wave hindcast is used to investigate the interannual variability and trend of winter wave height along the west coast of Europe. Results show that the winter-mean wave height, variability, and periodicity all increased significantly in the northeast Atlantic over the last seven decades which primarily correlate with changes in the climate indices North Atlantic Oscillation (NAO) and West Europe Pressure Anomaly (WEPA) affecting atmospheric circulation in the North Atlantic. NAO and WEPA primarily explain the increase in winter-mean wave height and periodicity, respectively, while both WEPA and NAO explain the increase in interannual variability. This increase in trend, variability, and periodicity resulted in more frequent high-energy winters with high NAO and/or WEPA over the last decades. The ability of climate models to predict the winter NAO and WEPA indices a few months ahead will be crucial to anticipate coastal hazards in this region. Plain Language Summary We explore the evolution of winter-mean wave height, variability, and periodicity in the northeast Atlantic over 1949-2017 and the links with the primary climate indices explaining winter wave activity, which is critical from the coastal hazard perspective. The climate indices NAO and WEPA primarily drive the increase in winter-mean wave height and periodicity, respectively, while both WEPA and NAO explain the increase in interannual variability, resulting in more frequent high-energy winters over the last seven decades. Extreme winter-mean wave heights become more frequent as WEPA and NAO positivity and variability increase. Predicting WEPA and NAO a few months ahead is crucial to anticipate coastal hazards, which is of interest for coastal and climate communities

Classification of beach response to extreme storms

publisher: Elsevier articletitle: Classification of beach response to extreme storms journaltitle: Geomorphology articlelink: http://dx.doi.org/10.1016/j.geomorph.2017.07.022 content_type: article copyright: Crown Copyright © 2017 Published by Elsevier B.V