239,644 research outputs found

    Gauge Theory of Gravity Requires Massive Torsion Field

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    One of the greatest unsolved issues of the physics of this century is to find a quantum field theory of gravity. According to a vast amount of literature unification of quantum field theory and gravitation requires a gauge theory of gravity which includes torsion and an associated spin field. Various models including either massive or massless torsion fields have been suggested. We present arguments for a massive torsion field, where the probable rest mass of the corresponding spin three gauge boson is the Planck mass.Comment: 3 pages, Revte

    Primitive model electrolytes. A comparison of the HNC approximation for the activity coefficient with Monte Carlo data

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    Accuracy of the mean activity coefficient expression (Hansen-Vieillefosse-Belloni equation), valid within the hypernetted chain (HNC) approximation, was tested in a wide concentration range against new Monte Carlo (MC) data for +1:-1 and +2:-2 primitive model electrolytes. The expression has an advantage that the excess chemical potential can be obtained directly, without invoking the time consuming Gibbs-Duhem calculation. We found the HNC results for the mean activity coefficient to be in good agreement with the machine calculations performed for the same model. In addition, the thermodynamic consistency of the HNC approximation was tested. The mean activity coefficients, calculated via the Gibbs-Duhem equation, seem to follow the MC data slightly better than the Hansen-Vieillefosse-Belloni expression. For completeness of the calculation, the HNC excess internal energies and osmotic coefficients are also presented. These results are compared with the calculations based on other theories commonly used to describe electrolyte solutions, such as the mean spherical approximation, Pitzer's extension of the Debye-H\"uckel theory, and the Debye-H\"uckel limiting law.Comment: 15 pages, 6 figure

    Heat Capacity Effects Associated with the Hydrophobic Hydration and Interaction of Simple Solutes: A Detailed Structural and Energetical Analysis Based on MD Simulations

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    We examine the SPCE and TIP5P water models to study heat capacity effects associated with the hydrophobic hydration and interaction of Xenon particles. We calculate the excess chemical potential for Xenon employing the Widom particle insertion technique. The solvation enthalpy and excess heat capacity is obtained from the temperature dependence of the chemical potentials and, alternatively, directly by Ewald summation, as well as a reaction field based method. All three different approaches provide consistent results. The reaction field method allows a separation of the individual components to the heat capacity of solvation into solute/solvent and solvent/solvent parts, revealing the solvent/solvent part as the dominating contribution. A detailed spacial analysis of the heat capacity of the water molecules around a pair of Xenon particles at different separations reveals that the enhanced heat capacity of the water molecules in the bisector plane between two Xenon atoms is responsible for the maximum of the heat capacity observed at the desolvation barrier, recently reported by Shimizu and Chan ({\em J. Am. Chem. Soc.},{\bf 123}, 2083--2084 (2001)). The about 60% enlarged heat capacity of water in the concave part of the joint Xenon-Xenon hydration shell is the result of a counterplay of strengthened hydrogen bonds and an enhanced breaking of hydrogen bonds with increasing temperature. Differences between the two models concerning the heat capacity in the Xenon-Xenon contact state are attributed to the different water model bulk heat capacities, and to the different spacial extension of the structure effect introduced by the hydrophobic particles. Similarities between the different states of water in the joint Xenon-Xenon hydration shell and the properties of stretched water are discussed.Comment: 14 pages, 16 figures, twocolumn revte

    Branching process approach for Boolean bipartite networks of metabolic reactions

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    The branching process (BP) approach has been successful in explaining the avalanche dynamics in complex networks. However, its applications are mainly focused on unipartite networks, in which all nodes are of the same type. Here, motivated by a need to understand avalanche dynamics in metabolic networks, we extend the BP approach to a particular bipartite network composed of Boolean AND and OR logic gates. We reduce the bipartite network into a unipartite network by integrating out OR gates, and obtain the effective branching ratio for the remaining AND gates. Then the standard BP approach is applied to the reduced network, and the avalanche size distribution is obtained. We test the BP results with simulations on the model networks and two microbial metabolic networks, demonstrating the usefulness of the BP approach

    Uniform materials and the multiplicative decomposition of the deformation gradient in finite elasto-plasticity

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    In this work we analyze the relation between the multiplicative decomposition F=FeFp\mathbf F=\mathbf F^{e}\mathbf F^{p} of the deformation gradient as a product of the elastic and plastic factors and the theory of uniform materials. We prove that postulating such a decomposition is equivalent to having a uniform material model with two configurations - total ϕ\phi and the inelastic ϕ1\phi_{1}. We introduce strain tensors characterizing different types of evolutions of the material and discuss the form of the internal energy and that of the dissipative potential. The evolution equations are obtained for the configurations (ϕ,ϕ1)(\phi,\phi_{1}) and the material metric g\mathbf g. Finally the dissipative inequality for the materials of this type is presented.It is shown that the conditions of positivity of the internal dissipation terms related to the processes of plastic and metric evolution provide the anisotropic yield criteria
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