239,644 research outputs found
Gauge Theory of Gravity Requires Massive Torsion Field
One of the greatest unsolved issues of the physics of this century is to find
a quantum field theory of gravity. According to a vast amount of literature
unification of quantum field theory and gravitation requires a gauge theory of
gravity which includes torsion and an associated spin field. Various models
including either massive or massless torsion fields have been suggested. We
present arguments for a massive torsion field, where the probable rest mass of
the corresponding spin three gauge boson is the Planck mass.Comment: 3 pages, Revte
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Manufacturing Mechatronics Using Thermal Spray Shape Deposition
A new technology for manufacturing mechatronics is described. The technique is based on recursive
masking and deposition of thermally sprayed materials. Using these methods, mechanical structures
can be created that embed and interconnect electronic components. This results in highly integrated
mechatronic devices. A simple, electromechanical artifact was designed and produced to assess the
feasibility of these techniques. The details and limitations of this project will be discussed. Areas of
future research are identified which are aimed at realizing the full potential of this emerging manufacturing
process.Mechanical Engineerin
Primitive model electrolytes. A comparison of the HNC approximation for the activity coefficient with Monte Carlo data
Accuracy of the mean activity coefficient expression
(Hansen-Vieillefosse-Belloni equation), valid within the hypernetted chain
(HNC) approximation, was tested in a wide concentration range against new Monte
Carlo (MC) data for +1:-1 and +2:-2 primitive model electrolytes. The
expression has an advantage that the excess chemical potential can be obtained
directly, without invoking the time consuming Gibbs-Duhem calculation. We found
the HNC results for the mean activity coefficient to be in good agreement with
the machine calculations performed for the same model. In addition, the
thermodynamic consistency of the HNC approximation was tested. The mean
activity coefficients, calculated via the Gibbs-Duhem equation, seem to follow
the MC data slightly better than the Hansen-Vieillefosse-Belloni expression.
For completeness of the calculation, the HNC excess internal energies and
osmotic coefficients are also presented. These results are compared with the
calculations based on other theories commonly used to describe electrolyte
solutions, such as the mean spherical approximation, Pitzer's extension of the
Debye-H\"uckel theory, and the Debye-H\"uckel limiting law.Comment: 15 pages, 6 figure
Heat Capacity Effects Associated with the Hydrophobic Hydration and Interaction of Simple Solutes: A Detailed Structural and Energetical Analysis Based on MD Simulations
We examine the SPCE and TIP5P water models to study heat capacity effects
associated with the hydrophobic hydration and interaction of Xenon particles.
We calculate the excess chemical potential for Xenon employing the Widom
particle insertion technique. The solvation enthalpy and excess heat capacity
is obtained from the temperature dependence of the chemical potentials and,
alternatively, directly by Ewald summation, as well as a reaction field based
method. All three different approaches provide consistent results. The reaction
field method allows a separation of the individual components to the heat
capacity of solvation into solute/solvent and solvent/solvent parts, revealing
the solvent/solvent part as the dominating contribution. A detailed spacial
analysis of the heat capacity of the water molecules around a pair of Xenon
particles at different separations reveals that the enhanced heat capacity of
the water molecules in the bisector plane between two Xenon atoms is
responsible for the maximum of the heat capacity observed at the desolvation
barrier, recently reported by Shimizu and Chan ({\em J. Am. Chem. Soc.},{\bf
123}, 2083--2084 (2001)). The about 60% enlarged heat capacity of water in the
concave part of the joint Xenon-Xenon hydration shell is the result of a
counterplay of strengthened hydrogen bonds and an enhanced breaking of hydrogen
bonds with increasing temperature. Differences between the two models
concerning the heat capacity in the Xenon-Xenon contact state are attributed to
the different water model bulk heat capacities, and to the different spacial
extension of the structure effect introduced by the hydrophobic particles.
Similarities between the different states of water in the joint Xenon-Xenon
hydration shell and the properties of stretched water are discussed.Comment: 14 pages, 16 figures, twocolumn revte
Branching process approach for Boolean bipartite networks of metabolic reactions
The branching process (BP) approach has been successful in explaining the
avalanche dynamics in complex networks. However, its applications are mainly
focused on unipartite networks, in which all nodes are of the same type. Here,
motivated by a need to understand avalanche dynamics in metabolic networks, we
extend the BP approach to a particular bipartite network composed of Boolean
AND and OR logic gates. We reduce the bipartite network into a unipartite
network by integrating out OR gates, and obtain the effective branching ratio
for the remaining AND gates. Then the standard BP approach is applied to the
reduced network, and the avalanche size distribution is obtained. We test the
BP results with simulations on the model networks and two microbial metabolic
networks, demonstrating the usefulness of the BP approach
Uniform materials and the multiplicative decomposition of the deformation gradient in finite elasto-plasticity
In this work we analyze the relation between the multiplicative decomposition
of the deformation gradient as a product
of the elastic and plastic factors and the theory of uniform materials. We
prove that postulating such a decomposition is equivalent to having a uniform
material model with two configurations - total and the inelastic
. We introduce strain tensors characterizing different types of
evolutions of the material and discuss the form of the internal energy and that
of the dissipative potential. The evolution equations are obtained for the
configurations and the material metric .
Finally the dissipative inequality for the materials of this type is
presented.It is shown that the conditions of positivity of the internal
dissipation terms related to the processes of plastic and metric evolution
provide the anisotropic yield criteria
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Generalised additive dependency inflated models including aggregated covariates
Let us assume that X, Y and U are observed and that the conditional mean of U given X and Y can be expressed via an additive dependency of X, λ(X)Y and X + Y for some unspecified function . This structured regression model can be transferred to a hazard model or a density model when applied on some appropriate grid, and has important forecasting applications via structured marker dependent hazards models or structured density models including age-period-cohort relationships. The structured regression model is also important when the severity of the dependent variable has a complicated dependency on waiting times X, Y and the total waiting time X+Y . In case the conditional mean of U approximates a density, the regression model can be used to analyse the age-period-cohort model, also when exposure data are not available. In case the conditional mean of U approximates a marker dependent hazard, the regression model introduces new relevant age-period-cohort time scale interdependencies in understanding longevity. A direct use of the regression relationship introduced in this paper is the estimation of the severity of outstanding liabilities in non-life insurance companies. The technical approach taken is to use B-splines to capture the underlying one-dimensional unspecified functions. It is shown via finite sample simulation studies and an application for forecasting future asbestos related deaths in the UK that the B-spline approach works well in practice. Special consideration has been given to ensure identifiability of all models considered
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