Vibronic coupling explains the ultrafast carotenoid-to-bacteriochlorophyll energy transfer in natural and artificial light harvesters

The initial energy transfer in photosynthesis occurs between the light-harvesting pigments and on ultrafast timescales. We analyze the carotenoid to bacteriochlorophyll energy transfer in LH2 Marichromatium purpuratum as well as in an artificial light-harvesting dyad system by using transient grating and two-dimensional electronic spectroscopy with 10 fs time resolution. We find that F\"orster-type models reproduce the experimentally observed 60 fs transfer times, but overestimate coupling constants, which leads to a disagreement with both linear absorption and electronic 2D-spectra. We show that a vibronic model, which treats carotenoid vibrations on both electronic ground and excited state as part of the system's Hamiltonian, reproduces all measured quantities. Importantly, the vibronic model presented here can explain the fast energy transfer rates with only moderate coupling constants, which are in agreement with structure based calculations. Counterintuitively, the vibrational levels on the carotenoid electronic ground state play a central role in the excited state population transfer to bacteriochlorophyll as the resonance between the donor-acceptor energy gap and vibrational ground state energies is the physical basis of the ultrafast energy transfer rates in these systems

Faraday rotation in the MOJAVE blazars: 3C 273 a case study

Radio polarimetric observations of Active Galactic Nuclei can reveal the magnetic field structure in the parsec-scale jets of these sources. We have observed the gamma-ray blazar 3C 273 as part of our multi-frequency survey with the Very Long Baseline Array to study Faraday rotation in a large sample of jets. Our observations re-confirm the transverse rotation measure gradient in 3C 273. For the first time the gradient is seen to cross zero which is further indication for a helical magnetic field and spine-sheath structure in the jet. We believe the difference to previous epochs is due to a different part of the jet being illuminated in our observations.Comment: 6 pages, 3 figures. To appear in the proceedings of "Beamed and Unbeamed Gamma-rays from Galaxies", held in Muonio, Finland, April 11-15, 2011. Journal of Physics: Conference Serie

MOJAVE: monitoring of jets in active galactic nuclei with VLBA experiments. V. Multi-epoch VLBA images

We present images from a long-term program (MOJAVE: Monitoring of Jets in active galactic nuclei (AGNs) with VLBA Experiments) to survey the structure and evolution of parsec-scale jet phenomena associated with bright radio-loud active galaxies in the northern sky. The observations consist of 2424 15 GHz Very Long Baseline Array (VLBA) images of a complete flux-density-limited sample of 135 AGNs above declination –20°, spanning the period 1994 August to 2007 September. These data were acquired as part of the MOJAVE and 2 cm Survey programs, and from the VLBA archive. The sample-selection criteria are based on multi-epoch parsec-scale (VLBA) flux density, and heavily favor highly variable and compact blazars. The sample includes nearly all the most prominent blazars in the northern sky, and is well suited for statistical analysis and comparison with studies at other wavelengths. Our multi-epoch and stacked-epoch images show 94% of the sample to have apparent one-sided jet morphologies, most likely due to the effects of relativistic beaming. Of the remaining sources, five have two-sided parsec-scale jets, and three are effectively unresolved by the VLBA at 15 GHz, with essentially all of the flux density contained within a few tenths of a milliarcsecond

Spectral evolution of bright NS LMXBs with INTEGRAL: an application of the thermal plus bulk Comptonization model

The aim of this work is to investigate in a physical and quantitative way the spectral evolution of bright Neutron Star Low-Mass X-ray Binaries (NS LMXBs), with special regard to the transient hard X-ray tails. We analyzed INTEGRAL data for five sources (GX 5-1, GX 349+2, GX 13+1, GX 3+1, GX 9+1) and built broad-band X-ray spectra from JEM-X1 and IBIS/ISGRI data. For each source, X-ray spectra from different states were fitted with the recently proposed model compTB. The spectra have been fit with a two-compTB model. In all cases the first compTB describes the dominant part of the spectrum that we interpret as thermal Comptonization of soft seed photons (< 1 keV), likely from the accretion disk, by a 3-5 keV corona. In all cases, this component does not evolve much in terms of Comptonization efficiency, with the system converging to thermal equilibrium for increasing accretion rate. The second compTB varies more dramatically spanning from bulk plus thermal Comptonization of blackbody seed photons to the blackbody emission alone. These seed photons (R < 12 km, kT_s > 1 keV), likely from the neutron star and the innermost part of the system, the Transition Layer, are Comptonized by matter in a converging flow. The presence and nature of this second compTB component (be it a pure blackbody or Comptonized) are related to the inner local accretion rate which can influence the transient behaviour of the hard tail: high values of accretion rates correspond to an efficient Bulk Comptonization process (bulk parameter delta > 0) while even higher values of accretion rates suppress the Comptonization, resulting in simple blackbody emission (delta=0).Comment: 12 pages, 10 figures, accepted for publication in A&

INTEGRAL observations of the field of the BL Lacertae object S5~0716+714

We have performed observations of the blazar S5 0716+714 with INTEGRAL on 2-6 April 2004. In the first months of 2004, the source had increased steadily in optical brightness and had undergone two outbursts. During the latter, occurred in March, it reached the extreme level of R = 12.1 mag, which triggered our INTEGRAL program. The target has been detected with IBIS/ISGRI up to 60 keV, with a flux of ~3 x 10e-11 erg/s/cm2 in the 30-60 keV interval, a factor of ~2 higher than observed by the BeppoSAX PDS in October 2000. In the field of S5 0716+714 we have also detected the Flat Spectrum Radio Quasar S5 0836+710 and the two Seyfert galaxies Mkn 3 and Mkn 6. Their IBIS/ISGRI spectra are rather flat, albeit consistent with those measured by BeppoSAX. In the spectrum of Mkn 3 we find some evidence of a break between ~60 and ~100 keV, reminiscent of the high energy cut-offs observed in other Seyfert galaxies. This is the first report of INTEGRAL spectra of weak Active Galactic Nuclei.Comment: 5 pages, 5 figures, in press in A&

Probing the innermost regions of AGN jets and their magnetic fields with RadioAstron II. Observations of 3C 273 at minimum activity

RadioAstron is a 10 m orbiting radio telescope mounted on the Spektr-R satellite, launched in 2011, performing Space Very Long Baseline Interferometry (SVLBI) observations supported by a global ground array of radio telescopes. With an apogee of about 350 000 km, it is offering for the first time the possibility to perform {\mu}as-resolution imaging in the cm-band. We present observations at 22 GHz of 3C 273, performed in 2014, designed to reach a maximum baseline of approximately nine Earth diameters. Reaching an angular resolution of 0.3 mas, we study a particularly low-activity state of the source, and estimate the nuclear region brightness temperature, comparing with the extreme one detected one year before during the RadioAstron early science period. We also make use of the VLBA-BU-BLAZAR survey data, at 43 GHz, to study the kinematics of the jet in a 1.5-year time window. We find that the nuclear brightness temperature is two orders of magnitude lower than the exceptionally high value detected in 2013 with RadioAstron at the same frequency (1.4x10^13 K, source-frame), and even one order of magnitude lower than the equipartition value. The kinematics analysis at 43 GHz shows that a new component was ejected 2 months after the 2013 epoch, visible also in our 22 GHz map presented here. Consequently this was located upstream of the core during the brightness temperature peak. These observations confirm that the previously detected extreme brightness temperature in 3C 273, exceeding the inverse Compton limit, is a short-lived phenomenon caused by a temporary departure from equipartition. Thus, the availability of interferometric baselines capable of providing {\mu}as angular resolution does not systematically imply measured brightness temperatures over the known physical limits for astrophysical sources.Comment: Accepted for publication in A&

Multi-Epoch Multiwavelength Spectra and Models for Blazar 3C~279

Of the blazars detected by EGRET in GeV gamma rays, 3C 279 is not only the best-observed by EGRET, but also one of the best-monitored at lower frequencies. We have assembled eleven spectra, from GHz radio through GeV gamma rays, from the time intervals of EGRET observations. Although some of the data have appeared in previous publications, most are new, including data taken during the high states in early 1999 and early 2000. All of the spectra show substantial gamma-ray contribution to the total luminosity of the object; in a high state, the gamma-ray luminosity dominates over that at all other frequencies by a factor of more than 10. There is no clear pattern of time correlation; different bands do not always rise and fall together, even in the optical, X-ray, and gamma-ray bands. The spectra are modeled using a leptonic jet, with combined synchrotron self-Compton + external Compton gamma-ray production. Spectral variability of 3C 279 is consistent with variations of the bulk Lorentz factor of the jet, accompanied by changes in the spectral shape of the electron distribution. Our modeling results are consistent with the UV spectrum of 3C 279 being dominated by accretion disk radiation during times of low gamma-ray intensity.Comment: 39 pages including 13 figures; data tables not included (see ApJ web version or contact author

The unprecedented optical outburst of the quasar 3C 454.3. The WEBT campaign of 2004-2005

The radio quasar 3C 454.3 underwent an exceptional optical outburst lasting more than 1 year and culminating in spring 2005. The maximum brightness detected was R = 12.0, which represents the most luminous quasar state thus far observed (M_B ~ -31.4). In order to follow the emission behaviour of the source in detail, a large multiwavelength campaign was organized by the Whole Earth Blazar Telescope (WEBT). Continuous optical, near-IR and radio monitoring was performed in several bands. ToO pointings by the Chandra and INTEGRAL satellites provided additional information at high energies in May 2005. The historical radio and optical light curves show different behaviours. Until about 2001.0 only moderate variability was present in the optical regime, while prominent and long-lasting radio outbursts were visible at the various radio frequencies, with higher-frequency variations preceding the lower-frequency ones. After that date, the optical activity increased and the radio flux is less variable. This suggests that the optical and radio emissions come from two separate and misaligned jet regions, with the inner optical one acquiring a smaller viewing angle during the 2004-2005 outburst. Moreover, the colour-index behaviour (generally redder-when-brighter) during the outburst suggests the presence of a luminous accretion disc. A huge mm outburst followed the optical one, peaking in June-July 2005. The high-frequency (37-43 GHz) radio flux started to increase in early 2005 and reached a maximum at the end of our observing period (end of September 2005). VLBA observations at 43 GHz during the summer confirm theComment: 7 pages, 4 figures, to be published in A&

High genetic diversity at the extreme range edge: nucleotide variation at nuclear loci in Scots pine (Pinus sylvestris L.) in Scotland

Nucleotide polymorphism at 12 nuclear loci was studied in Scots pine populations across an environmental gradient in Scotland, to evaluate the impacts of demographic history and selection on genetic diversity. At eight loci, diversity patterns were compared between Scottish and continental European populations. At these loci, a similar level of diversity (θsil=~0.01) was found in Scottish vs mainland European populations, contrary to expectations for recent colonization, however, less rapid decay of linkage disequilibrium was observed in the former (ρ=0.0086±0.0009, ρ=0.0245±0.0022, respectively). Scottish populations also showed a deficit of rare nucleotide variants (multi-locus Tajima's D=0.316 vs D=−0.379) and differed significantly from mainland populations in allelic frequency and/or haplotype structure at several loci. Within Scotland, western populations showed slightly reduced nucleotide diversity (πtot=0.0068) compared with those from the south and east (0.0079 and 0.0083, respectively) and about three times higher recombination to diversity ratio (ρ/θ=0.71 vs 0.15 and 0.18, respectively). By comparison with results from coalescent simulations, the observed allelic frequency spectrum in the western populations was compatible with a relatively recent bottleneck (0.00175 × 4Ne generations) that reduced the population to about 2% of the present size. However, heterogeneity in the allelic frequency distribution among geographical regions in Scotland suggests that subsequent admixture of populations with different demographic histories may also have played a role

Day-Scale Variability of 3C 279 and Searches for Correlations in Gamma-Ray, X-Ray, and Optical Bands

Light curves of 3C 279 are presented in optical (R-band), X-rays (RXTE/PCA), and gamma rays (CGRO/EGRET) for 1999 Jan-Feb and 2000 Jan-Mar. During both of those epochs the gamma-ray levels were high, and all three observed bands demonstrated substantial variation, on time scales as short as one day. Correlation analyses provided no consistent pattern, although a rather significant optical/gamma-ray correlation was seen in 1999, with a gamma-ray lag of ~2.5 days, and there are other suggestions of correlations in the light curves. For comparison, correlation analysis is also presented for the gamma-ray and X-ray light curves during the large gamma ray flare in 1996 Feb and the two gamma-bright weeks leading up to it; the correlation at that time was strong, with a gamma-ray/X-ray offset of no more than 1 day.Comment: 20 pages, including 7 figures; accepted by The Astrophysical Journa