654 research outputs found
Impact of surface-polish on the angular and wavelength dependence of fiber focal ratio degradation
We present measurements of how multimode fiber focal-ratio degradation (FRD)
and throughput vary with levels of fiber surface polish from 60 to 0.5 micron
grit. Measurements used full-beam and laser injection methods at wavelengths
between 0.4 and 0.8 microns on 17 meter lengths of Polymicro FBP 300 and 400
micron core fiber. Full-beam injection probed input focal-ratios between f/3
and f/13.5, while laser injection allowed us to isolate FRD at discrete
injection angles up to 17 degrees (f/1.6 marginal ray). We find (1) FRD effects
decrease as grit size decreases, with the largest gains in beam quality
occurring at grit sizes above 5 microns; (2) total throughput increases as grit
size decreases, reaching 90% at 790 nm with the finest polishing levels; (3)
total throughput is higher at redder wavelengths for coarser polishing grit,
indicating surface-scattering as the primary source of loss. We also quantify
the angular dependence of FRD as a function of polishing level. Our results
indicate that a commonly adopted micro-bending model for FRD is a poor
descriptor of the observed phenomenon.Comment: 10 pages, 7 figures, presented at SPIE Astronomical Telescopes and
Instrumentation, July 201
HexPak and GradPak: variable-pitch dual-head IFUs for the WIYN 3.5m Telescope Bench Spectrograph
We describe the design, construction, and expected performance of two new
fiber integral field units (IFUs) --- HexPak and GradPak --- for the WIYN 3.5m
Telescope Nasmyth focus and Bench Spectrograph. These are the first IFUs to
provide formatted fiber integral field spectroscopy with simultaneous sampling
of varying angular scales. HexPak and GradPak are in a single cable with a
dual-head design, permitting easy switching between the two different IFU heads
on the telescope without changing the spectrograph feed: the two heads feed a
variable-width double-slit. Each IFU head is comprised of a fixed arrangement
of fibers with a range of fiber diameters. The layout and diameters of the
fibers within each array are scientifically-driven for observations of
galaxies: HexPak is designed to observe face-on spiral or spheroidal galaxies
while GradPak is optimized for edge-on studies of galaxy disks. HexPak is a
hexagonal array of 2.9 arcsec fibers subtending a 40.9 arcsec diameter, with a
high-resolution circular core of 0.94 arcsec fibers subtending 6 arcsec
diameter. GradPak is a 39 by 55 arcsec rectangular array with rows of fibers of
increasing diameter from angular scales of 1.9 arcsec to 5.6 arcsec across the
array. The variable pitch of these IFU heads allows for adequate sampling of
light profile gradients while maintaining the photon limit at different scales.Comment: 10 pages, 4 figures, presented at SPIE, Astronomical Telescopes and
Instrumentation, 1 - 6 July 2012, Amsterdam, Netherland
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THE SYNTHESIS AND CRYSTAL STRUCTURE OF UCp3(C3H3N2). A NEW MODE OF PYRAZOLATE BONDING
Hybrid Sulfur Process for Solar Production of Hydrogen
Lowering dependence on fossil-based fuels has become a major area of focus in research, especially in transportation fuels. One particularly interesting field is that of hydrogen production. Hydrogen is promising because it has the potential to emit no greenhouse gases when used as fuel and is an excellent vessel for energy storage. Because traditional methods for its generation are inefficient and require nonrenewable fuel use, researchers have begun to focus on thermochemical cycles.
Thermochemical cycles are systems that require heat transfer intrinsically and do not consume fossil fuels nor emit greenhouse gases if renewable energy is used for heating. The hybrid sulfur process (HyS) has become a premiere cycle recently, as it is one of the simplest hydrolysis cycles with only two steps in the reaction and just two inputs, sulfuric acid and water, and still provides high purity hydrogen. The first reaction is endothermic, the high-temperature decomposition of sulfuric acid (H2SO4) into sulfur dioxide and water. Two different sources for the heat energy are viable, nuclear and solar power. These products are then fed to an electrolyzer in which sulfuric acid and hydrogen protons are produced at the anode, then the protons are passed across the membrane to form hydrogen. H2 is removed as the desired product and H2SO4 is recycled to the decomposition step5.
The Sandia National Laboratory (SNL) has been focusing research on the reactor needed for the high temperature acid decomposition step of the reaction. In particular, the materials needed to accommodate such high temperatures are difficult to design and implement into the needed equipment. SNL has developed the innovative bayonet decomposition reactor that minimizes these concerns. The reactor consists of two concentric flow paths, one closed and one open tube. High temperatures are applied at the closed end while the sulfuric acid enters in the open end where it is vaporized before passing through a catalyst bed where the decomposition takes place. For the HyS process to be viable, it is very important for the high-temperature reaction step to consume as little thermal energy as possible, therefore increasing thermal efficiency. Previous pinch analyses performed by Savannah River National Laboratory (SRNL) determined a feasible minimum energy requirement of 328.6 kJ/mol H2 based on a feed concentration of 75% sulfuric acid4.
SRNL has been researching the SO2-depolarized electrolyzer (SDE), which applies a potential to the process fluid to separate water into oxygen, hydrogen protons, and electrons, which recombine to form hydrogen gas and reform the sulfuric acid1. Engineers at SRNL have developed a flowsheet for the HyS process integrating the bayonet reactor heat source with the SDE using ASPEN Plus. It was found that the two areas of the process that require heat input are the Bayonet Reactor and the Vacuum Column reboiler, used for feed concentration, at 340.3 kJ/mol H2 and 75.5 kJ/mol H2, respectively. The total amount of electric energy required was found to be 120.9 kJ/mol H2, used primarily by the SDE. Therefore, the total energy requirement of the process is 685.8 kJ/mol H2, with 252.9 kJ/mol H2 rejected to cooling water. Thermal efficiencies were found to be in the range of 33-39%2.
The HyS process can only be a viable option if it has the potential to outperform alternate hydrogen production techniques. Water electrolysis is one established technology with which the HyS must be able to compete. According to the Nernst equation, standard cell potential for the SDE is lower than that of water electrolysis with traditional water at -1.229V and the HyS process at -0.158; therefore, considerably less electricity per mole of hydrogen product is consumed in the HyS process6. The research discussed above has found that the HyS process has the potential to perform at efficiencies higher than that of water electrolysis, making it a promising area of research. The HyS process also has an advantage over other potential thermochemical cycles due to its relatively simple and few reaction steps. The HyS process also has an advantage over natural gas reforming, which currently produces a large amount of hydrogen currently, in that it is a much cleaner energy source and emits no greenhouse gases. However, further research must be performed to greater explore the economics of the process
The Relationship between Institutional, Departmental and Program-Specific Variables and the Academic Performance of Division I FBS Football Programs
This study investigated the connection between the academic evaluation of Division I FBS football programs and the various social settings that influenced these student-athletes. These social settings were classified as: institutional, departmental and program-specific. The experience of the student-athlete is thought to be impacted by all three settings, creating applicability for social identity theory, which provides the theoretical framework of the study
The Fourteenth Data Release of the Sloan Digital Sky Survey: First Spectroscopic Data from the extended Baryon Oscillation Spectroscopic Survey and from the second phase of the Apache Point Observatory Galactic Evolution Experiment
The fourth generation of the Sloan Digital Sky Survey (SDSS-IV) has been in
operation since July 2014. This paper describes the second data release from
this phase, and the fourteenth from SDSS overall (making this, Data Release
Fourteen or DR14). This release makes public data taken by SDSS-IV in its first
two years of operation (July 2014-2016). Like all previous SDSS releases, DR14
is cumulative, including the most recent reductions and calibrations of all
data taken by SDSS since the first phase began operations in 2000. New in DR14
is the first public release of data from the extended Baryon Oscillation
Spectroscopic Survey (eBOSS); the first data from the second phase of the
Apache Point Observatory (APO) Galactic Evolution Experiment (APOGEE-2),
including stellar parameter estimates from an innovative data driven machine
learning algorithm known as "The Cannon"; and almost twice as many data cubes
from the Mapping Nearby Galaxies at APO (MaNGA) survey as were in the previous
release (N = 2812 in total). This paper describes the location and format of
the publicly available data from SDSS-IV surveys. We provide references to the
important technical papers describing how these data have been taken (both
targeting and observation details) and processed for scientific use. The SDSS
website (www.sdss.org) has been updated for this release, and provides links to
data downloads, as well as tutorials and examples of data use. SDSS-IV is
planning to continue to collect astronomical data until 2020, and will be
followed by SDSS-V.Comment: SDSS-IV collaboration alphabetical author data release paper. DR14
happened on 31st July 2017. 19 pages, 5 figures. Accepted by ApJS on 28th Nov
2017 (this is the "post-print" and "post-proofs" version; minor corrections
only from v1, and most of errors found in proofs corrected
A portable RNA sequence whose recognition by a synthetic antibody facilitates structural determination
RNA crystallization and phasing represent major bottlenecks in RNA structure determination. Seeking to exploit antibody fragments as RNA crystallization chaperones, we have used an arginine-enriched synthetic Fab library displayed on phage to obtain Fabs against the class I ligase ribozyme. We solved the structure of a Fab–ligase complex at 3.1-Å resolution using molecular replacement with Fab coordinates, confirming the ribozyme architecture and revealing the chaperone's role in RNA recognition and crystal contacts. The epitope resides in the GAAACAC sequence that caps the P5 helix, and this sequence retains high-affinity Fab binding within the context of other structured RNAs. This portable epitope provides a new RNA crystallization chaperone system that easily can be screened in parallel to the U1A RNA-binding protein, with the advantages of a smaller loop and Fabs′ high molecular weight, large surface area and phasing power.National Institutes of Health (U.S.) (GM61835
Sloan Digital Sky Survey IV: mapping the Milky Way, nearby galaxies, and the distant universe
We describe the Sloan Digital Sky Survey IV (SDSS-IV), a project encompassing three major spectroscopic programs. The Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2) is observing hundreds of thousands of Milky Way stars at high resolution and high signal-to-noise ratios in the near-infrared. The Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey is obtaining spatially resolved spectroscopy for thousands of nearby galaxies (median ). The extended Baryon Oscillation Spectroscopic Survey (eBOSS) is mapping the galaxy, quasar, and neutral gas distributions between and 3.5 to constrain cosmology using baryon acoustic oscillations, redshift space distortions, and the shape of the power spectrum. Within eBOSS, we are conducting two major subprograms: the SPectroscopic IDentification of eROSITA Sources (SPIDERS), investigating X-ray AGNs and galaxies in X-ray clusters, and the Time Domain Spectroscopic Survey (TDSS), obtaining spectra of variable sources. All programs use the 2.5 m Sloan Foundation Telescope at the Apache Point Observatory; observations there began in Summer 2014. APOGEE-2 also operates a second near-infrared spectrograph at the 2.5 m du Pont Telescope at Las Campanas Observatory, with observations beginning in early 2017. Observations at both facilities are scheduled to continue through 2020. In keeping with previous SDSS policy, SDSS-IV provides regularly scheduled public data releases; the first one, Data Release 13, was made available in 2016 July
Sloan Digital Sky Survey IV: Mapping the Milky Way, Nearby Galaxies, and the Distant Universe
We describe the Sloan Digital Sky Survey IV (SDSS-IV), a project encompassing three major spectroscopic programs. The Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2) is observing hundreds of thousands of Milky Way stars at high resolution and high signal-to-noise ratios in the near-infrared. The Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey is obtaining spatially resolved spectroscopy for thousands of nearby galaxies (median ). The extended Baryon Oscillation Spectroscopic Survey (eBOSS) is mapping the galaxy, quasar, and neutral gas distributions between and 3.5 to constrain cosmology using baryon acoustic oscillations, redshift space distortions, and the shape of the power spectrum. Within eBOSS, we are conducting two major subprograms: the SPectroscopic IDentification of eROSITA Sources (SPIDERS), investigating X-ray AGNs and galaxies in X-ray clusters, and the Time Domain Spectroscopic Survey (TDSS), obtaining spectra of variable sources. All programs use the 2.5 m Sloan Foundation Telescope at the Apache Point Observatory; observations there began in Summer 2014. APOGEE-2 also operates a second near-infrared spectrograph at the 2.5 m du Pont Telescope at Las Campanas Observatory, with observations beginning in early 2017. Observations at both facilities are scheduled to continue through 2020. In keeping with previous SDSS policy, SDSS-IV provides regularly scheduled public data releases; the first one, Data Release 13, was made available in 2016 July
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