Properties and influence of microstructure and crystal defects in Fe2_2VAl modified by laser surface remelting

Laser surface remelting can be used to manipulate the microstructure of cast material. Here, we present a detailed analysis of the microstructure of Fe$_2$VAl following laser surface remelting. Within the melt pool, elongated grains grow nearly epitaxially from the heat-affected zone. These grains are separated by low-angle grain boundaries with 1{\deg}-5{\deg} misorientations. Segregation of vanadium, carbon, and nitrogen at grain boundaries and dislocations is observed using atom probe tomography. The local electrical resistivity was measured by an in-situ four-point-probe technique. A smaller increase in electrical resistivity is observed at these low-angle grain boundaries compared to high-angle grain boundaries in a cast sample. This indicates that grain boundary engineering could potentially be used to manipulate thermoelectric properties

Bottom-up effects of plant diversity on multitrophic interactions in a biodiversity experiment

Biodiversity is rapidly declining1, and this may negatively affect ecosystem processes, including economically important ecosystem services. Previous studies have shown that biodiversity has positive effects on organisms and processes4 across trophic levels. However, only a few studies have so far incorporated an explicit food-web perspective. In an eight-year biodiversity experiment, we studied an unprecedented range of above- and below-ground organisms and multitrophic interactions. A multitrophic data set originating from a single long-term experiment allows mechanistic insights that would not be gained from meta-analysis of different experiments. Here we show that plant diversity effects dampen with increasing trophic level and degree of omnivory. This was true both for abundance and species richness of organisms. Furthermore, we present comprehensive above-ground/below-ground biodiversity food webs. Both above ground and below ground, herbivores responded more strongly to changes in plant diversity than did carnivores or omnivores. Density and richness of carnivorous taxa was independent of vegetation structure. Below-ground responses to plant diversity were consistently weaker than above-ground responses. Responses to increasing plant diversity were generally positive, but were negative for biological invasion, pathogen infestation and hyperparasitism. Our results suggest that plant diversity has strong bottom-up effects on multitrophic interaction networks, with particularly strong effects on lower trophic levels. Effects on higher trophic levels are indirectly mediated through bottom-up trophic cascades

Chemical and structural characterization of the native oxide scale on a Mg-based alloy

In this study, the structure and composition of the native oxide forming on the basal plane (0001) of Mg-2Al-0.1Ca is investigated by a correlative approach, combining scanning transmission electron microscopy (STEM) and atom probe tomography (APT). Atom probe specimens were prepared conventionally in a Ga focused ion beam (FIB) as well as a Xe plasma FIB in a cryogenic setup and subsequently cleaned in the atom probe to remove surface contamination before oxidation. While thermal energy input from the laser and longer atmospheric exposure time increased the measured hydrogen content in the specimen's apex region, cryo preparation revealed, that the hydrogen uptake in magnesium is independent of the employment of conventional or cryogenic FIB preparation. TEM measurements demonstrated the growth of a (111) MgO oxide layer with 3-4 nm thickness on the basal (0001) plane of the Mg atom probe specimen. APT data further revealed the formation of an aluminum-rich region between bulk Mg and the native oxide. The aluminum enrichment of up to ~20 at.% at the interface is consistent with an inward growth of the oxide scale

The political geography of religious radicalism. A compendium of selected case studies from around the globe

Religion has neither gone away nor remained irrelevant in our world today. There is no day that we do not hear news about religion in the media. The news we hear about religion and violence, however, appears to dominate the headlines. Although the history of religions and violence is not a new one, since September 11, 2001 there has been a growing concern about religious extremism and terrorism. At the same time, there is a corresponding interest in the subject of religion and violence among many disciplines. In the course GEO-83 “Political Geography of Religious Radicalism”, we offered students an excursion into the ambivalent world of religion and conflict through an exploration of different theoretical perspectives and approaches, case studies, seminal and class discussions and extensive literature review. The unique angle of interrogation that political geography offers in terms of the spatial dimensions and the power relations between different actors as well as the discursive aspects of interreligious conflicts and extremism has proved very valuable in generating insights on this subject matter. This volume is an attempt by students of the M.A. “Human Geography – Global Studies” programme of the University of Tübingen to demonstrate acquaintance with the approach of political geography to the study of religious violence and extremism. The students took on some of the most challenging conflicts and religious insurgencies confronting the world and offered insights using diverse theoretical and analytical frameworks. The analysis contained in each chapter was based on secondary data. Thus, limitations are set based on the availability of and access to data. Given the contested nature of religious conflicts and extremism, the reader is invited to consider all the articles in this volume as primarily an academic exercise with no intention to promote a certain narrative or to take sides. Knowledge is always incremental. Therefore, what is presented here is intended to increase our understanding of the phenomenon and to stimulate further research and efforts at finding solutions to the various conflicts. No doubt, this exercise has exposed the students to the rigour of scientific writing. This experience will remain invaluable to them in their continuing academic pursuit as well as in their future endeavours. The lecturers also found this experience to be highly rewarding. The process was quite daunting, but the commitment and the dedication of the students paid off

A comparison of the strength of biodiversity effects across multiple functions

In order to predict which ecosystem functions are most at risk from biodiversity loss, meta-analyses have generalised results from biodiversity experiments over different sites and ecosystem types. In contrast, comparing the strength of biodiversity effects across a large number of ecosystem processes measured in a single experiment permits more direct comparisons. Here, we present an analysis of 418 separate measures of 38 ecosystem processes. Overall, 45% of processes were significantly affected by plant species richness, suggesting that, while diversity affects a large number of processes not all respond to biodiversity. We therefore compared the strength of plant diversity effects between different categories of ecosystem processes, grouping processes according to the year of measurement, their biogeochemical cycle, trophic level and compartment (above- or belowground) and according to whether they were measures of biodiversity or other ecosystem processes, biotic or abiotic and static or dynamic. Overall, and for several individual processes, we found that biodiversity effects became stronger over time. Measures of the carbon cycle were also affected more strongly by plant species richness than were the measures associated with the nitrogen cycle. Further, we found greater plant species richness effects on measures of biodiversity than on other processes. The differential effects of plant diversity on the various types of ecosystem processes indicate that future research and political effort should shift from a general debate about whether biodiversity loss impairs ecosystem functions to focussing on the specific functions of interest and ways to preserve them individually or in combinatio

Ignition and Combustion of Heavy Hydrocarbons Using an Aerosol Shock-Tube Approach

Results from a heterogeneous shock-tube approach recently demonstrated at Texas A&amp;M University, wherein a hydrocarbon fuel is introduced in liquid phase with gaseous oxidizer, are presented. The shock tube has been designed for controlled measurement of ignition delay times, sooting phenomena, radical species concentrations, time-dependent species profiles, and nanoparticle-aided combustion using heavy hydrocarbons which are difficult to study using the traditional shock tube approach. Aerosol is generated in a high-vacuum manifold positioned 4-m from the endwall where optical and pressure-based diagnostics are stationed. The approach reduces the propensity for fuel-film deposition near the endwall avoiding optical and/or kinetic disturbances that could result. The aerosol enters the shock tube initially as a two-phase flow of liquid fuel and gaseous oxidizer/inert gas. Liquid droplets partially evaporate while resident in the shock tube, prior to shock wave generation, and are then completely vaporized behind the incident shock wave. Behind the reflected shock wave, then, resides a pure gas-phase fuel and oxidizer mixture. The primary benefit of the aerosol shock tube approach is the ability to inject fuels of low vapor pressure at high or low concentrations. The classic shock-tube approach introduces gas-phase constituents only, and has difficulty accommodating low vapor-pressure liquids, except when component partial pressures are much lower than what is usually required. In the present work, n-heptane aerosol (C7H16, Pvap, 20 °C ∼ 35 torr), was generated with O2/Ar carrier gas and dispersed in the shock tube in a uniform manner. Stoichiometric ignition delay times with temperature varied from 1240 K to 1600 K and pressure maintained near 2.0 atm are compared to gas-phase data at similar conditions and a chemical kinetic model for heptane combustion. Excellent agreement was found between the two-phase aerosol approach and the classical method involving vapor-phase n-heptane and pre-mixed gases. The measured activation energy for the stoichiometric mixture at 2.0 atm (EA = 42.3 kcal /mol), obtained with the two-phase technique, compares well with the literature value.</jats:p

Experimental estimates of the energy budget of hydrothermal eruptions; application to 2012 Upper Te Maari eruption, New Zealand

AbstractSudden hydrothermal eruptions occur in many volcanic settings and may include high-energy explosive phases. Ballistics launched by such events, together with ash plumes and pyroclastic density currents, generate deadly proximal hazards. The violence of hydrothermal eruptions (or explosive power) depends on the energy available within the driving-fluids (gas or liquid), which also influences the explosive mechanisms, volumes, durations, and products of these eruptions. Experimental studies in addition to analytical modeling were used here to elucidate the fragmentation mechanism and aspects of energy balance within hydrothermal eruptions. We present results from a detailed study of recent event that occurred on the 6th of August 2012 at Upper Te Maari within the Tongariro volcanic complex (New Zealand). The eruption was triggered by a landslide from this area, which set off a rapid stepwise decompression of the hydrothermal system. Explosive blasts were directed both westward and eastward of the collapsed area, with a vertical ash plume sourced from an adjacent existing crater. All explosions ejected blocks on ballistic trajectories, hundreds of which impacted New Zealand's most popular hiking trail and a mountain lodge, 1.4 km from the explosion locus. We have employed rocks representative of the eruption source area to perform rapid decompression experiments under controlled laboratory conditions that mimic hydrothermal explosions under controlled laboratory conditions. An experimental apparatus for 34 by 70 mm cylindrical samples was built to reduce the influence of large lithic enclaves (up to 30 mm in diameter) within the rock. The experiments were conducted in a temperature range of 250 °C–300 °C and applied pressure between 4 MPa and 6.5 MPa, which span the range of expected conditions below the Te Maari crater. Within this range we tested rapid decompression of pre-saturated samples from both liquid-dominated conditions and the vapor-dominated field. Further, we tested dry samples at the same pressure and temperature conditions. Results showed that host rock lithology and state of the interstitial fluid was a major influence on the fragmentation and ejection processes, as well as the energy partitioning. Clasts were ejected with velocities of up to 160 m/s as recorded by high-speed camera. In addition to rare large clasts (analogous to ballistics), a large amount of fine and very fine (<63 μm) ash was produced in all experiments. The efficiency of transformation of the total explosive energy into fragmentation energy was estimated between 10 to 15%, depending on the host rock lithology, while less than 0.1% of this was converted into kinetic energy. Our results suggest that liquid-to-vapor (flashing) expansion provides an order of magnitude higher energy release than steam expansion, which best explains the dynamics of the westward (and most energetic) directed blast at Te Maari. Considering the steam flashing as the primary energy source, the experiments suggested that a minimum explosive energy of 7×1010 to 2×1012 J was involved in the Te Maari blast.Experimental studies under controlled conditions, compared closely to a field example are thus highly useful in providing new insights into the energy release and hazards associated with eruptions in hydrothermal areas

Grain boundaries control lithiation of solid solution substrates in lithium metal batteries

The development of sustainable transportation and communication systems requires an increase in both energy density and capacity retention of Li-batteries. Using substrates forming a solid solution with body centered cubic Li enhances the cycle stability of anode-less batteries. However, it remains unclear how the substrate microstructure affects the lithiation behavior. Here, we deploy a correlative, near-atomic scale probing approach through combined ion- and electron-microscopy to examine the distribution of Li in Li-Ag diffusion couples as model system. We reveal that Li regions with over 93.8% at.% nucleate within Ag at random high angle grain boundaries, whereas grain interiors are not lithiated. We evidence the role of kinetics and mechanical constraint from the microstructure over equilibrium thermodynamics in dictating the lithiation process. The findings suggest that grain size and grain boundary character are critical to enhance the electrochemical performance of interlayers/electrodes, particularly for improving lithiation kinetics and hence reducing dendrite formation