Effect of graphene oxide fibre surface modification on low-velocity impact and fatigue performance of flax fibre reinforced composites

Fatigue and impact resistance are essential performance indicators in structural biocomposites. Integrating multilayer and oxygen-rich graphene oxide (GO) crystals as a fibre surface modification or reinforcing agent in polymer matrix systems have been shown to enhance the interfacial strength and toughness of natural fibre composites. However, the state-of-the-art literature on the GO-modification of composites has focused mainly on their microscale and quasi-static mechanical performance. Here, the fatigue testing results showed that surface modification of flax fibres with GO reduces the slope of the S-N curve by 17% and promotes fibre pull-outs upon failure. Based on the in-situ impact damage analysis, the GO-modification delayed the impact damage initiation and prolonged the stable damage progression phase. The impact perforation energy was similar for modified and unmodified specimens. At kinetic energies below the perforation limit, the GO-modification suppressed the extent of fibre failure and endowed flax-epoxy specimens with better damping performance

Modulating impact resistance of flax epoxy composites with thermoplastic interfacial toughening

The application of natural flax fibre/epoxy composites is growing in the automotive sector due to their good stiffness and damping properties. However, the impact damage resistance of flax/epoxy composites is limited due to the brittle nature of both epoxy and flax fibres and strong fibre/matrix adhesion. Here, biobased thermoplastic cellulose acetate (CA) is deployed as a fibre treatment to alter the damage development of flax/epoxy composites subjected to low-velocity impact. The perforation threshold energy and the perforation energy of unmodified cross-ply composites increased respectively by 66% and 42% with CA-treated flax fibres. The CA-modification modestly decreased the transverse tensile strength and in-plane tensile shear strength of the composites. However, it altered the brittle nature of flax/epoxy laminates in quasi-static tests into ductile failure with clearly increased fibre–matrix debonding.publishedVersionPeer reviewe

Effect of graphene oxide surface treatment on the interfacial adhesion and the tensile performance of flax epoxy composites

The high stiffness and damping properties of flax fibres promote the integration of biocomposites in structural applications. However, the strength of flax/epoxy composites is still limited compared to glass/epoxy composites. Graphene oxide (GO) has proved to be a promising building block for nanocomposites due to its high toughness, stiffness and tunable interfacial interactions with polymers. This study aims to understand the potential of GO-based surface treatment of flax fibres to modify the interfacial adhesion and tensile performance of flax fibre/epoxy composites. GO-modification improves the interfacial shear strength of elementary flax fibre/epoxy by 43%. The interfacial improvement is also established by the 40% higher transverse bending strength compared to untreated flax/epoxy composites. The tensile moduli of GO-modified flax/epoxy composites are on average 2 GPa higher than for untreated flax fibre/epoxy composites in all strain ranges. The quasi-static longitudinal tensile strength of unidirectional composites is not affected by GO-modification.publishedVersionPeer reviewe