Performance analysis of a Cold Asphalt Concrete Binder Course Containing High Calcium Fly Ash Utilizing Waste Material

It has been established that cold bituminous emulsion mixtures (CBEMs) have a comparatively low initial strength in comparison to hot mix asphalt (HMA), however its superior performance with regard to carbon emissions, is a significant driver regarding its manufacture. In this research, high calcium fly ash (HCFA) together with a fluid catalytic cracking catalyst (FCC) - a rich silica-alumina waste material - have been incorporated to develop a new cold asphalt concrete binder course (CACB) bituminous emulsion mixture. HCFA was used as a substitute for traditional limestone filler while FCC was the additive used to activate the HCFA. The mixtures’ performance was assessed using the indirect tensile stiffness modulus test (ITSM), assessment of resistance against permanent deformation, temperature and water sensitivity tests. Surface morphology was tested using a scanning electron microscopy (SEM). A considerable improvement was identified by the ITSM test in addition to a substantial enhancement in rutting resistance, temperature susceptibility and water sensitivity. It was also established that the addition of FCC to CACB mixtures was found to improve early strength as well as long-term strength, rutting resistance, temperature sensitivity and durability

Laboratory Studies to Examine the Properties of a Novel Cold-Asphalt Concrete Binder Course Mixture Containing Binary Blended Cementitious Filler (BBCF)

Conventional hot asphalt mixtures have an impact on global warming and CO2 emissions contributing to debates on environmental issues which have been raised in recent years. As an alternative, cold emulsion asphalt mixtures (CBEMs) provide considerable benefits such as eco-friendliness, energy efficiency and cost effectiveness connected with safety. However, their weak early strength along with the need for longer curing times (usually 2-24 months) and higher moisture susceptibility compared to hot asphalt mixtures, have been cited as obstacles to their wider application. That said, the incorporation of waste materials in CBEM mixtures enhances sustainability by decreasing the amount of industrial waste materials needed and conserving natural resources. A new binary blended cement filler (BBCF) material generated from high calcium fly ash (HCFA) and fluid catalytic cracking catalyst (FC3R) was found to be very effective in providing microstructural integrity with a novel fast-curing cold asphalt concrete for the binder course (CACB) mixture. Laboratory performance tests included the stiffness modulus test by indirect tension to cylindrical samples, wheel-tracking tests and water sensitivity. Regarding environmental issues, a toxicity characteristic leaching procedure (TCLP) test was performed to analyse the leachate from various specimens comprising concentrations of heavy metal. The findings of these tests have demonstrated that CACB performs extremely well compared to traditional hot mixtures. The stiffness modulus of the BBCF treated mixture – 3730 MPa after 3 days – is higher than the traditional hot mixture (100/150 pen). In addition, the BBCF treated mixture offered a superior performance regarding rutting resistance, fatigue resistance and water susceptibility as well as revealing a considerably lower thermal sensitivity. More significantly, the BBCF treated mixture was found comparable to the traditional asphalt concrete binder course after a very short curing time (1 day). Finally, the concentration of heavy metals in the specimens incorporating the BBCF was observed to be less than the regulatory levels determined for hazardous materials and so requirements were satisfied. Consequently, this BBCF treated mixture has significant potential with reference to its application as a binder course in asphalt pavement

High-sensitivity diamond magnetometer with nanoscale resolution

We present a novel approach to the detection of weak magnetic fields that takes advantage of recently developed techniques for the coherent control of solid-state electron spin quantum bits. Specifically, we investigate a magnetic sensor based on Nitrogen-Vacancy centers in room-temperature diamond. We discuss two important applications of this technique: a nanoscale magnetometer that could potentially detect precession of single nuclear spins and an optical magnetic field imager combining spatial resolution ranging from micrometers to millimeters with a sensitivity approaching few femtotesla/Hz$^{1/2}$.Comment: 29 pages, 4 figure

Subduction controls the distribution and fragmentation of Earth’s tectonic plates

International audienceThe theory of plate tectonics describes how the surface of the Earth is split into an organized jigsaw of seven large plates 1 of similar sizes and a population of smaller plates, whose areas follow a fractal distribution 2,3. The reconstruction of global tectonics during the past 200 My 4 suggests that this layout is probably a long-term feature of our planet, but the forces governing it are unknown. Previous studies 3,5,6 , primarily based on statistical properties of plate distributions, were unable to resolve how the size of plates is determined by lithosphere properties and/or underlying mantle convection. Here, we demonstrate that the plate layout of the Earth is produced by a dynamic feedback between mantle convection and the strength of the lithosphere. Using 3D spherical models of mantle convection with plate-like behaviour that match the plate size-frequency distribution observed for Earth, we show that subduction geometry drives the tectonic fragmentation that generates plates. The spacing between slabs controls the layout of large plates, and the stresses caused by the bending of trenches, break plates into smaller fragments. Our results explain why the fast evolution in small back-arc plates 7,8 reflects the dramatic changes in plate motions during times of major reorganizations. Our study opens the way to use convection simulations with plate-like behaviour to unravel how global tectonics and mantle convection are dynamically connected

Elevated CO2 degassing rates prevented the return of Snowball Earth during the Phanerozoic

The Cryogenian period (~720–635 Ma) is marked by extensive Snowball Earth glaciations. These have previously been linked to CO₂ draw-down, but the severe cold climates of the Cryogenian have never been replicated during the Phanerozoic despite similar, and sometimes more dramatic changes to carbon sinks. Here we quantify the total CO₂ input rate, both by measuring the global length of subduction zones in plate tectonic reconstructions, and by sea-level inversion. Our results indicate that degassing rates were anomalously low during the Late Neoproterozoic, roughly doubled by the Early Phanerozoic, and remained comparatively high until the Cenozoic. Our carbon cycle modelling identifies the Cryogenian as a unique period during which low surface temperature was more easily achieved, and shows that the shift towards greater CO₂ input rates after the Cryogenian helped prevent severe glaciation during the Phanerozoic. Such a shift appears essential for the development of complex animal life

The patriotism of gentlemen with red hair: European Jews and the liberal state, 1789–1939

European Jewish history from 1789–1939 supports the view that construction of national identities even in secular liberal states was determined not only by modern considerations alone but also by ancient patterns of thought, behaviour and prejudice. Emancipation stimulated unprecedented patriotism, especially in wartime, as Jews strove to prove loyalty to their countries of citizenship. During World War I, even Zionists split along national lines, as did families and friends. Jewish patriotism was interchangeable with nationalism inasmuch as Jews identified themselves with national cultures. Although emancipation implied acceptance and an end to anti-Jewish prejudice in the modern liberal state, the kaleidoscopic variety of Jewish patriotism throughout Europe inadvertently undermined the idea of national identity and often provoked anti-Semitism. Even as loyal citizens of separate states, the Jews, however scattered, disunited and diverse, were made to feel, often unwillingly, that they were one people in exile

High performance cold asphalt concrete mixture for binder course using alkali-activated binary blended cementitious filler

A slow rate of curing and the long time necessary to achieve full strength has led cold asphalt mixes (CAM) to be considered poorer in comparison to hot mix asphalt over the last decades. This piece of research aimed to develop a new fast-curing and environmentally friendly cold asphalt concrete for binder courses mixture (CACB). It has the same gradation as that of traditional hot asphalt concrete mixtures but incorporates a binary blended cementitious filler (BBCF) containing waste, high calcium fly ash (HCFA) and fluid catalytic cracking catalyst residue (FC3R) activated by a waste alkaline NaOH solution. The research concludes that incorporating an alkali activated binary blended cementitious filler (ABBCF) with CACB significantly improves the mechanical properties and water susceptibility. In addition, the high performance ABBCF mixture has a substantial lower thermal sensitivity than traditional hot asphalt concrete binder course mixtures. SEM analysis revealed that the main crystallisation had taken place at an early stage of the new ABBCF. More significantly, the new CACB mixture has a comparable stiffness modulus with the traditional asphalt concrete binder course after a very short curing time (less than one day)

Simulated Effects of Recruitment Variability, Exploitation, and Reduced Habitat Area on the Muskellunge Population in Shoepack Lake, Voyageurs National Park, Minnesota

The genetically unique population of muskellunge Esox masquinongy inhabiting Shoepack Lake in Voyageurs National Park, Minnesota, is potentially at risk for loss of genetic variability and long-term viability. Shoepack Lake has been subject to dramatic surface area changes from the construction of an outlet dam by beavers Castor canadensis and its subsequent failure. We simulated the long-term dynamics of this population in response to recruitment variation, increased exploitation, and reduced habitat area. We then estimated the effective population size of the simulated population and evaluated potential threats to long-term viability, based on which we recommend management actions to help preserve the long-term viability of the population. Simulations based on the population size and habitat area at the beginning of a companion study resulted in an effective population size that was generally above the threshold level for risk of loss of genetic variability, except when fishing mortality was increased. Simulations based on the reduced habitat area after the beaver dam failure and our assumption of a proportional reduction in population size resulted in an effective population size that was generally below the threshold level for risk of loss of genetic variability. Our results identified two potential threats to the long-term viability of the Shoepack Lake muskellunge population, reduction in habitat area and exploitation. Increased exploitation can be prevented through traditional fishery management approaches such as the adoption of no-kill, barbless hook, and limited entry regulations. Maintenance of the greatest possible habitat area and prevention of future habitat area reductions will require maintenance of the outlet dam built by beavers. Our study should enhance the long-term viability of the Shoepack Lake muskellunge population and illustrates a useful approach for other unique populations