Micro-electroforming metallic bipolar electrodes for mini-DMFC stacks

This paper describes the development of metallic bipolar plate fabrication using micro-electroforming process for mini-DMFC (direct methanol fuel cell) stacks. Ultraviolet (UV) lithography was used to define micro-fluidic channels using a photomask and exposure process. Micro-fluidic channels mold with 300 micrometers thick and 500 micrometers wide were firstly fabricated in a negative photoresist onto a stainless steel plate. Copper micro-electroforming was used to replicate the micro-fluidic channels mold. Following by sputtering silver (Ag) with 1.2 micrometers thick, the metallic bipolar plates were completed. The silver layer is used for corrosive resistance. The completed mini-DMFC stack is a 2x2 cm2 fuel cell stack including a 1.5x1.5 cm2 MEA (membrane electrode assembly). Several MEAs were assembly into mini-DMFC stacks using the completed metallic bipolar plates. All test results showed the metallic bipolar plates suitable for mini-DMFC stacks. The maximum output power density is 9.3mW/cm2 and current density is 100 mA/cm2 when using 8 vol. % methanol as fuel and operated at temperature 30 degrees C. The output power result is similar to other reports by using conventional graphite bipolar plates. However, conventional graphite bipolar plates have certain difficulty to be machined to such micro-fluidic channels. The proposed micro-electroforming metallic bipolar plates are feasible to miniaturize DMFC stacks for further portable 3C applications.Comment: Submitted on behalf of EDA Publishing Association (http://irevues.inist.fr/handle/2042/16838

Abstract Swiss Cheese Space and the Classicalisation of Swiss Cheeses

Swiss cheese sets are compact subsets of the complex plane obtained by deleting a sequence of open disks from a closed disk. Such sets have provided numerous counterexamples in the theory of uniform algebras. In this paper, we introduce a topological space whose elements are what we call "abstract Swiss cheeses". Working within this topological space, we show how to prove the existence of "classical" Swiss cheese sets (as discussed in a paper of Feinstein and Heath from 2010) with various desired properties. We first give a new proof of the Feinstein-Heath classicalisation theorem. We then consider when it is possible to "classicalise" a Swiss cheese while leaving disks which lie outside a given region unchanged. We also consider sets obtained by deleting a sequence of open disks from a closed annulus, and we obtain an analogue of the Feinstein-Heath theorem for these sets. We then discuss regularity for certain uniform algebras. We conclude with an application of these techniques to obtain a classical Swiss cheese set which has the same properties as a non-classical example of O'Farrell (1979).Comment: To appear in the Journal of Mathematical Analysis and Application

Finite-Blocklength Bounds for Wiretap Channels

This paper investigates the maximal secrecy rate over a wiretap channel subject to reliability and secrecy constraints at a given blocklength. New achievability and converse bounds are derived, which are shown to be tighter than existing bounds. The bounds also lead to the tightest second-order coding rate for discrete memoryless and Gaussian wiretap channels.Comment: extended version of a paper submitted to ISIT 201

Mixed H2/H∞ filtering for uncertain systems with regional pole assignment

Copyright [2005] IEEE. This material is posted here with permission of the IEEE. Such permission of the IEEE does not in any way imply IEEE endorsement of any of Brunel University's products or services. Internal or personal use of this material is permitted. However, permission to reprint/republish this material for advertising or promotional purposes or for creating new collective works for resale or redistribution must be obtained from the IEEE by writing to [email protected]. By choosing to view this document, you agree to all provisions of the copyright laws protecting it.The mixed H2/H∞ filtering problem for uncertain linear continuous-time systems with regional pole assignment is considered. The purpose of the problem is to design an uncertainty-independent filter such that, for all admissible parameter uncertainties, the following filtering requirements are simultaneously satisfied: 1) the filtering process is asymptotically stable; 2) the poles of the filtering matrix are located inside a prescribed region that compasses the vertical strips, horizontal strips, disks, or conic sectors; 3) both the H2 norm and the H∞ norm on the respective transfer functions are not more than the specified upper bound constraints. We establish a general framework to solve the addressed multiobjective filtering problem completely. In particular, we derive necessary and sufficient conditions for the solvability of the problem in terms of a set of feasible linear matrix inequalities (LMIs). An illustrative example is given to illustrate the design procedures and performances of the proposed method

Scanning ultrafast electron microscopy

Progress has been made in the development of four-dimensional ultrafast electron microscopy, which enables space-time imaging of structural dynamics in the condensed phase. In ultrafast electron microscopy, the electrons are accelerated, typically to 200 keV, and the microscope operates in the transmission mode. Here, we report the development of scanning ultrafast electron microscopy using a field-emission-source configuration. Scanning of pulses is made in the single-electron mode, for which the pulse contains at most one or a few electrons, thus achieving imaging without the space-charge effect between electrons, and still in ten(s) of seconds. For imaging, the secondary electrons from surface structures are detected, as demonstrated here for material surfaces and biological specimens. By recording backscattered electrons, diffraction patterns from single crystals were also obtained. Scanning pulsed-electron microscopy with the acquired spatiotemporal resolutions, and its efficient heat-dissipation feature, is now poised to provide in situ 4D imaging and with environmental capability

Multiple Timescale Energy Scheduling for Wireless Communication with Energy Harvesting Devices

The primary challenge in wireless communication with energy harvesting devices is to efficiently utilize the harvesting energy such that the data packet transmission could be supported. This challenge stems from not only QoS requirement imposed by the wireless communication application, but also the energy harvesting dynamics and the limited battery capacity. Traditional solar predictable energy harvesting models are perturbed by prediction errors, which could deteriorate the energy management algorithms based on this models. To cope with these issues, we first propose in this paper a non-homogenous Markov chain model based on experimental data, which can accurately describe the solar energy harvesting process in contrast to traditional predictable energy models. Due to different timescale between the energy harvesting process and the wireless data transmission process, we propose a general framework of multiple timescale Markov decision process (MMDP) model to formulate the joint energy scheduling and transmission control problem under different timescales. We then derive the optimal control policies via a joint dynamic programming and value iteration approach. Extensive simulations are carried out to study the performances of the proposed schemes

Spin filling of valley-orbit states in a silicon quantum dot

We report the demonstration of a low-disorder silicon metal-oxide-semiconductor (Si MOS) quantum dot containing a tunable number of electrons from zero to N=27. The observed evolution of addition energies with parallel magnetic field reveals the spin filling of electrons into valley-orbit states. We find a splitting of 0.10 meV between the ground and first excited states, consistent with theory and placing a lower bound on the valley splitting. Our results provide optimism for the realization in the near future of spin qubits based on silicon quantum dots.Comment: 6 pages, 4 figures, to appear in Nanotechnolog