Optically detected X-ray absorption spectroscopy measurements as a means to monitor corrosion layers on copper

XANES and EXAFS information is conventionally measured in transmission through the energy-dependent absorption of X-rays or by observing X-ray fluorescence, but secondary fluorescence processes, such as the emission of electrons and optical photons (e.g., 200-1000 nm), can also be used as a carrier of the XAS signatures, providing complementary information such as improved surface specificity. Where the near-visible photons have a shorter range in a material, the data will be more surface specific. Moreover, optical radiation may escape more readily than X-rays through liquid in an environmental cell. Here, we describe a first test of optically detected X-ray absorption spectroscopy (ODXAS) for monitoring electrochemical treatments on copper-based alloys, for example, heritage metals. Artificially made corrosion products deposited on a copper substrate were analyzed in air and in a 1% (w/v) sodium sesquicarbonate solution to simulate typical conservation methods for copper-based objects recovered from marine environments. The measurements were made on stations 7.1 and 9.2 MF (SRS Daresbury, UK) using the mobile luminescence end station (MoLES), supplemented by XAS measurements taken on DUBBLE (BM26 A) at the ESRF. The ODXAS spectra usually contain fine structure similar to that of XAS spectra measured in X-ray fluorescence. Importantly, for the compounds examined, the ODXAS is significantly more surface specific, and > 98% characteristic of thin surface layers of 0.5-1.5-mu m thickness in cases where X-ray measurements are dominated by the substrate. However, EXAFS and XANES from broadband optical measurements are superimposed on a high background due to other optical emission modes. This produces statistical fluctuations up to double what would be expected from normal counting statistics because the data retain the absolute statistical fluctuation in the original raw count, while losing up to 70% of their magnitude when background is removed. The problem may be solved in future through optical filtering to isolate the information-containing band, combined with the use of higher input X-ray fluxes available on third-generation light sources

Imaging of buried objects from experimental backscattering time dependent measurements using a globally convergent inverse algorithm

We consider the problem of imaging of objects buried under the ground using backscattering experimental time dependent measurements generated by a single point source or one incident plane wave. In particular, we estimate dielectric constants of those objects using the globally convergent inverse algorithm of Beilina and Klibanov. Our algorithm is tested on experimental data collected using a microwave scattering facility at the University of North Carolina at Charlotte. There are two main challenges working with this type of experimental data: (i) there is a huge misfit between these data and computationally simulated data, and (ii) the signals scattered from the targets may overlap with and be dominated by the reflection from the ground's surface. To overcome these two challenges, we propose new data preprocessing steps to make the experimental data to be approximately the same as the simulated ones, as well as to remove the reflection from the ground's surface. Results of total 25 data sets of both non blind and blind targets indicate a good accuracy.Comment: 34 page

Reconstruction of the refractive index from experimental backscattering data using a globally convergent inverse method

The problem to be studied in this work is within the context of coefficient identification problems for the wave equation. More precisely, we consider the problem of reconstruction of the refractive index (or equivalently, the dielectric constant) of an inhomogeneous medium using one backscattering boundary measurement. The goal of this paper is to analyze the performance of a globally convergent algorithm of Beilina and Klibanov on experimental data acquired in the Microwave Laboratory at University of North Carolina at Charlotte. The main challenge working with experimental data is the the huge misfit between these data and computationally simulated data. We present data pre-processing steps to make the former somehow look similar to the latter. Results of both non-blind and blind targets are shown indicating good reconstructions even for high contrasts between the targets and the background medium.Comment: 25 page

Reconstruction from blind experimental data for an inverse problem for a hyperbolic equation

We consider the problem of reconstruction of dielectrics from blind backscattered experimental data. Experimental data were collected by a device, which was built at University of North Carolina at Charlotte. This device sends electrical pulses into the medium and collects the time resolved backscattered data on a part of a plane. The spatially distributed dielectric constant $\varepsilon_{r}(\mathbf{x}),\mathbf{x}\in \mathbb{R}^{3}$ is the unknown coefficient of a wave-like PDE. This coefficient is reconstructed from those data in blind cases. To do this, a globally convergent numerical method is used.Comment: 27 page

Discrete Charge Dielectric Model of Electrostatic Energy

Studies on nanoscale materials merit careful development of an electrostatics model concerning discrete point charges within dielectrics. The discrete charge dielectric model treats three unique interaction types derived from an external source: Coulomb repulsion among point charges, direct polarization between point charges and their associated surface charge elements, and indirect polarization between point charges and surface charge elements formed by other point charges. The model yields the potential energy, U(N), stored in a general $N$ point charge system differing from conventional integral formulations, $1/2\int{\bm E}\cdot{\bm D}dV$ and $1/2\int\rho\Phi dV$, in a manner significant to the treatment of few electron systems.Comment: 1 figure, 2 parts, ep

Characterization of novel microneme adhesive repeats (MAR) in Eimeria tenella

In this study, we evaluated the binding capacity of Type I MAR domains from novel E. tenella MCPs. Variants of the previously described HxT motif were analysed showing that HxT and VxT variants bind, whereas HxS and YxE variants did not. One of these MCP containing a single MAR (EtMCP2) showed an apical localization when expressed as a fusion with the fluorescent reporter mCherry in transgenic populations and a similar pattern of transcripts per zoite during endogenous development in vitro as the well-characterised microneme protein EtMIC2