Hyperfine transitions of 13CN from pre-protostellar sources

Recent quantum mechanical calculations of rate coefficients for collisional transfer of population between the hyperfine states of 13CN enable their population densities to be determined. We have computed the relative populations of the hyperfine states of the N = 0, 1, 2 rotational states for kinetic temperatures 5 $\le$ T $\le$ 20 K and molecular hydrogen densities 1 $\le$ n(H2) $\le$10 10 cm --3. Spontaneous and induced radiative transitions were taken into account. Our calculations show that, if the lines are optically thin, the populations of the hyperfine states, F, within a given rotational manifold are proportional to their statistical weights, (2F + 1) -- i.e. in local thermodynamic equilibrium -- over the entire range of densities. We have re-analysed IRAM 30 m telescope observations of 13CN hyperfine transitions (N = 1 $\rightarrow$ 0) in four starless cores. A comparison of these observations with our calculations confirms that the hyperfine states are statistically populated in these sources.Comment: MNRAS, Oxford University press, 2015, http://mnras.oxfordjournals.org/content/452/1/19.full?keytype=ref\&ijkey=CCx468pl8lXgoXx. \<10.1093/mnras/stv1322\&gt

Making meaning and meaning making: memory, postmemory and narrative in Holocaust literature

This paper explores links between narration and memory in Holocaust literature and examines ways in which individuals construct memory and postmemory. Based on the premise that ‘All authors mediate reality through their writing...’ and taking into consideration that what we remember and how we remember is likely to have a significant impact on the narratives that we construct, this article considers the reliability of memory. It argues that whilst there is, at times, a blurring of boundaries between fact and fiction in Holocaust literature, this has little or no impact on the validity and authenticity of the narratives. In an attempt to address these issues more fully, this paper explores the notions of making meaning and meaning making, whilst considering the effects of positionality, time and trauma on memory. Key texts referred to in this discussion include Night (1958) by Elie Wiesel, All Rivers Run to the Sea (1996) by Elie Wiesel, In My Brother’s Shadow (2005) by Uwe Timm and The Dark Room (2001) by Rachel Seiffert. These texts have been chosen in order to highlight the subjectivity of memory and postmemory and to demonstrate the role that narrative plays in their construction and representation

Dynamic Euler Diagram Drawing

In this paper we describe a method to lay out a graph enhanced Euler diagram so that it looks similar to a previously drawn graph enhanced Euler diagram. This task is non-trivial when the underlying structures of the diagrams differ. In particular, if a structural change is made to an existing drawn diagram, our work enables the presentation of the new diagram with minor disruption to the user's mental map. As the new diagram can be generated from an abstract representation, its initial embedding may be very different from that of the original. We have developed comparison measures for Euler diagrams, integrated into a multicriteria optimizer, and applied a force model for associated graphs that attempts to move nodes towards their positions in the original layout. To further enhance the usability of the system, the transition between diagrams can be animated

Some Results for Drawing Area Proportional Venn3 With Convex Curves

Many data sets are visualized effectively with area proportional Venn diagrams, where the area of the regions is in proportion to a defined specification. In particular, Venn diagrams with three intersecting curves are considered useful for visualizing data in many applications, including bioscience, ecology and medicine. To ease the understanding of such diagrams, using restricted nice shapes for the curves is considered beneficial. Many research questions on the use of such diagrams are still open. For instance, a general solution to the question of when given area specifications can be represented by Venn3 using convex curves is still unknown. In this paper we study symmetric Venn3 drawn with convex curves and show that there is a symmetric area specification that cannot be represented with such a diagram. In addition, by using symmetric diagrams drawn with polygons, we show that, if area specifications are restricted so that the double intersection areas are no greater than the triple intersection area then the specification can be drawn with convex curves. We also propose a construction that allows the representation of some area specifications when the double intersection areas are greater than the triple intersection area. Finally, we present some open questions on the topic

Formation Pumping of Molecular Hydrogen in Dark Clouds

Many theoretical and laboratory studies predict H2 to be formed in highly excited ro-vibrational states. The consequent relaxation of excited levels via a cascade of infrared transitions might be observable in emission from suitable interstellar regions. In this work, we model H2 formation pumping in standard dense clouds, taking into account the H/H2 transition zone, through an accurate description of chemistry and radiative transfer. The model includes recent laboratory data on H2 formation, as well as the effects of the interstellar UV field, predicting the populations of gas-phase H2 molecules and their IR emission spectra. Calculations suggest that some vibrationally excited states of H2 might be detectable towards lines of sight where significant destruction of H2 occurs, such as X-ray sources, and provide a possible explanation as to why observational attempts resulted in no detections reported to date.Comment: 32 pages, 8 figures, 5 table

Drawing Area-Proportional Euler Diagrams Representing Up To Three Sets

Area-proportional Euler diagrams representing three sets are commonly used to visualize the results of medical experiments, business data, and information from other applications where statistical results are best shown using interlinking curves. Currently, there is no tool that will reliably visualize exact area-proportional diagrams for up to three sets. Limited success, in terms of diagram accuracy, has been achieved for a small number of cases, such as Venn-2 and Venn-3 where all intersections between the sets must be represented. Euler diagrams do not have to include all intersections and so permit the visualization of cases where some intersections have a zero value. This paper describes a general, implemented, method for visualizing all 40 Euler-3 diagrams in an area-proportional manner. We provide techniques for generating the curves with circles and convex polygons, analyze the drawability of data with these shapes, and give a mechanism for deciding whether such data can be drawn with circles. For the cases where non-convex curves are necessary, our method draws an appropriate diagram using non-convex polygons. Thus, we are now always able to automatically visualize data for up to three sets

Close-coupling calculations of rotational energy transfer in p-H2+HD

We report quantum-mechanical close-coupling calculations for rotational state resolved cross sections for p-H2+HD collisions. The low temperature limit of p-H2+HD is investigated, which is of significant astrophysical interest in regard to the cooling of primordial gas and the interstellar media. Sharp resonances have been reproduced in the cross sections of some transition states at very low kinetic energies, E< 0.00001 eV.Comment: 10 pages, 6 figure

Benchmarking pKa prediction

Background: pKa values are a measure of the protonation of ionizable groups in proteins. Ionizable groups are involved in intra-protein, protein-solvent and protein-ligand interactions as well as solubility, protein folding and catalytic activity. The pKa shift of a group from its intrinsic value is determined by the perturbation of the residue by the environment and can be calculated from three-dimensional structural data. Results: Here we use a large dataset of experimentally-determined pKas to analyse the performance of different prediction techniques. Our work provides a benchmark of available software implementations: MCCE, MEAD, PROPKA and UHBD. Combinatorial and regression analysis is also used in an attempt to find a consensus approach towards pKa prediction. The tendency of individual programs to over- or underpredict the pKa value is related to the underlying methodology of the individual programs. Conclusion: Overall, PROPKA is more accurate than the other three programs. Key to developing accurate predictive software will be a complete sampling of conformations accessible to protein structures

A personal perspective on four decades of paleolimnology and environmental change research

A personal summary of paleolimnological research activities in the UK and elswehere since the mid 1970s

Investigation of global lightning and the ionosphere using high frequency induction coils

In June 2012, the British Geological Survey Geomagnetism team installed two high frequency (100 Hz) induction coil magnetometers at the Eskdalemuir Observatory, in the Scottish Borders of the United Kingdom. The induction coils permit us to measure the very rapid changes of the magnetic field. The Eskdalemuir Observatory is one of the longest running geophysical sites in the UK (beginning operation in 1904) and is located in a rural valley with a quiet magnetic environment. The data output from the induction coils are digitized and logged onsite before being collected once per hour and sent to the Edinburgh office via the Internet. We intend to run the coils as a long term experiment. We present results from our analysis of the Madden-Julian Oscillation and highlight some of the interesting spectral features visible in the induction coil data set