Franck-Condon Effect in Central Spin System

We study the quantum transitions of a central spin surrounded by a collective-spin environment. It is found that the influence of the environmental spins on the absorption spectrum of the central spin can be explained with the analog of the Franck-Condon (FC) effect in conventional electron-phonon interaction system. Here, the collective spins of the environment behave as the vibrational mode, which makes the electron to be transitioned mainly with the so-called "vertical transitions" in the conventional FC effect. The "vertical transition" for the central spin in the spin environment manifests as, the certain collective spin states of the environment is favored, which corresponds to the minimal change in the average of the total spin angular momentum.Comment: 8 pages, 8 figure

Use of axial tomography to follow temporal changes of benthic communities in an unstable sedimentary environment (Baie des Ha! Ha!, Saguenay Fjord)

In the upper layer of the sediment column, organic matter recycling is greatly influenced by bioturbation. However, there are many physical changes in the nature of the sediment that may disturb benthic communities and create a biogeochemical imbalance. Following a very heavy rainfall between 26 and 29 July 1996, an intense flash flood in the Saguenay Fjord caused discharges of 6 million cubic metres of sediments into Baie des Ha! Ha!. Unstable sediment deposits located at the top of the delta of the Rivie`re des Ha! Ha! were sporadically exported to the deep basin. After this physical disturbance, meiobenthic and macrobenthic organisms progressively re-colonised the sediment column. To determine the impacts of such sedimentary depositions on benthic fauna, two stations, one at the head and one at the mouth of the Baie des Ha! Ha!, have been monitored since 1996. During this survey, we developed a new method for the quantification of biogenic structures using computer axial tomography (CAT-Scan). Benthic fauna analysis showed that the two stations were characterised by different temporal changes in the benthic dynamics according to their geographic location. Using CAT-Scan analysis of sediment cores, we were able to characterise the stability of the sediment column for the two stations in 1999 and 2000. Scan results suggest that colonisation processes were closely linked with the stability of the sediment column. Erosion and redeposition of surficial sediments caused a succession in the formation of biogenic structures. These variations were characterised for the first time using CAT-Scan, which is a nondestructive, rapid, and precise method. Tomographic analysis showed the importance of the production and destruction rates of biogenic structures and the sedimentation rate for the preservation of burrows and potentially reactive components. This study finally demonstrated that each erosional event could be followed by a rapid formation of biogenic structures, allowing the re-oxidation of old deposits

Détermination de la diffusivité thermique et de l’épaisseur du béton d’enrobage par thermographie infrarouge

29ème rencontre de l’AUGC Tlemcen (29-31 Mai 2011).Ce travail présente une méthode inverse pour déterminer la diffusivité thermique et l’épaisseur du béton d’enrobage de deux poutres expérimentales, l’une en béton et l’autre en mortier. L’armature métallique centrale est sollicitée à l’aide d’un chauffage par induction et l’évolution des températures de surface est mesurée à l’aide d’une caméra infrarouge. Une modélisation numérique mettant en oeuvre un schéma ADI permet de résoudre l’équation de transfert thermique. Il est intégré à une procédure d’identification qui conduit à la détermination des paramètres d’épaisseur et de diffusivité thermique. Une étude de sensibilité montre que ces paramètres peuvent être déterminés simultanément durant la phase de chauffage de la barre

Designs and Implementations in Neural Network-based Video Coding

The past decade has witnessed the huge success of deep learning in well-known artificial intelligence applications such as face recognition, autonomous driving, and large language model like ChatGPT. Recently, the application of deep learning has been extended to a much wider range, with neural network-based video coding being one of them. Neural network-based video coding can be performed at two different levels: embedding neural network-based (NN-based) coding tools into a classical video compression framework or building the entire compression framework upon neural networks. This paper elaborates some of the recent exploration efforts of JVET (Joint Video Experts Team of ITU-T SG 16 WP 3 and ISO/IEC JTC 1/SC29) in the name of neural network-based video coding (NNVC), falling in the former category. Specifically, this paper discusses two major NN-based video coding technologies, i.e. neural network-based intra prediction and neural network-based in-loop filtering, which have been investigated for several meeting cycles in JVET and finally adopted into the reference software of NNVC. Extensive experiments on top of the NNVC have been conducted to evaluate the effectiveness of the proposed techniques. Compared with VTM-11.0_nnvc, the proposed NN-based coding tools in NNVC-4.0 could achieve {11.94%, 21.86%, 22.59%}, {9.18%, 19.76%, 20.92%}, and {10.63%, 21.56%, 23.02%} BD-rate reductions on average for {Y, Cb, Cr} under random-access, low-delay, and all-intra configurations respectively

Corneal Transduction by Intra-Stromal Injection of AAV Vectors In Vivo in the Mouse and Ex Vivo in Human Explants

The cornea is a transparent, avascular tissue that acts as the major refractive surface of the eye. Corneal transparency, assured by the inner stroma, is vital for this role. Disruption in stromal transparency can occur in some inherited or acquired diseases. As a consequence, light entering the eye is blocked or distorted, leading to decreased visual acuity. Possible treatment for restoring transparency could be via viral-based gene therapy. The stroma is particularly amenable to this strategy due to its immunoprivileged nature and low turnover rate. We assayed the potential of AAV vectors to transduce keratocytes following intra-stromal injection in vivo in the mouse cornea and ex vivo in human explants. In murine and human corneas, we transduced the entire stroma using a single injection, preferentially targeted keratocytes and achieved long-term gene transfer (up to 17 months in vivo in mice). Of the serotypes tested, AAV2/8 was the most promising for gene transfer in both mouse and man. Furthermore, transgene expression could be transiently increased following aggression to the cornea

NMR parameters in alkali, alkaline earth and rare earth fluorides from first principle calculations

19F isotropic chemical shifts for alkali, alkaline earth and rare earth of column 3 basic fluorides are measured and the corresponding isotropic chemical shieldings are calculated using the GIPAW method. When using PBE exchange correlation functional for the treatment of the cationic localized empty orbitals of Ca2+, Sc3+ (3d) and La3+ (4f), a correction is needed to accurately calculate 19F chemical shieldings. We show that the correlation between experimental isotropic chemical shifts and calculated isotropic chemical shieldings established for the studied compounds allows to predict 19F NMR spectra of crystalline compounds with a relatively good accuracy. In addition, we experimentally determine the quadrupolar parameters of 25Mg in MgF2 and calculate the electric field gradient of 25Mg in MgF2 and 139La in LaF3 using both PAW and LAPW methods. The orientation of the EFG components in the crystallographic frame, provided by DFT calculations, is analysed in term of electron densities. It is shown that consideration of the quadrupolar charge deformation is essential for the analysis of slightly distorted environments or highly irregular polyhedra.Comment: 18 pages, 8 figures, 4 tables and ES

Genomics illuminates the origin and dispersal of citrus. [W146]

The center of origin of citrus has been matter of discrepancy during almost a century. The elegant but general pioneer visions of Vavilov identified two centers of origin for citrus, the Indo-Burma center (Assam and Burma; oranges, mandarins and citrons), and the Indo-Malayan center (Indochina and the Malay Archipelago; pummelo). This vision was reformulated by Tanaka that in subsequent work concluded that the primary center was placed within northeast India and northern Myanmar, from where citrus dispersed to a secondary center located in Indochina and Southeast China. Our genomic, biogeographic and phylogenetic analyses indicated that the ancestral citrus experienced a relatively fast radiation giving rise to all major citrus species in a short period of time which is consistent with a unique initial area of diversification. Rapid biological radiations in this region have been reported for practically all major groups of organisms including insects, fishes, crabs, amphibians, reptiles, birds, ferns and plants. This information offers solid insights on the origin, dispersal and domestication of citrus, revealing a new evolutionary paradigm for the genus Citrus, the subject of this presentation. (Texte integral