48 research outputs found
The strongest intrinsic meaning of sequential-evaluation convergence
AbstractFor classical Banach sequence spaces c0(X), l∞(X) and lp(X) (0<p<+∞) we have found the strongest intrinsical meanings of their β-duals, and two basic convergence results are established in the β-duals
Length–weight relationship of six endemic fish species in the Qinghai‐Tibet Plateau, China
La<sub>2</sub>CoO<sub>4+<i>δ</i></sub> perovskite-mediated peroxymonosulfate activation for the efficient degradation of bisphenol A
In this study, the removal performance for BPA by PMS activated by the LCFO catalyst in a heterogeneous catalytic system was investigated.</jats:p
Densely Stacked CoCu-MOFs Coated with CuAl/LDH Enhance Sulfamethoxazole Degradation in PMS-Activated Systems
As the most promising techniques for refractory antibiotic degradation in wastewater management, sulfate radical-based advanced oxidation processes (SR-AOPs) have attracted considerable attention. However, systematic studies on potassium peroxymonosulfate (PMS) activation by MOF-derived metal oxides coated with LDH materials are still lacking. In this work, a series of catalysts consisting of CoCu-MOFs coated with CuAl/LDH were synthesized for PMS activation in the removal of sulfamethoxazole (SMX). As expected, CoCu-MOFs coated with CuAl/LDH catalyst showed high SMX removal and stability in PMS activation. In the CoCu/LDH/PMS reaction, the SMX removal was nearly 100% after 60 min, and the mineralization reached 53.7%. The catalyst showed excellent catalytic stability and low metal leaching concentrations (Co: 0.013 mg/L, Cu: 0.313 mg/L), as detected by ICP. Sulfate radicals and hydroxyl radicals were identified as the dominant reactive species in the CoCu/LDH/PMS system. Moreover, the presence of 1O2 in the process revealed the coupling of non-radical and radical processes. The XPS results showed that the layered structure of CoCu/LDH promoted the recycling of metal ions (high and low valence), which facilitated heterogeneous PMS activation. The effects of different reaction conditions and reuse cycles were also determined. The SMX oxidation pathways were proposed based on the intermediates identified by LC/MS. The high activity and stability of CoCu/LDH provide a new mechanistic understanding of PMS activation catalysts and their potential utilization in practical wastewater treatment
Determination of seven pesticide residues in bamboo shoots by high performance liquid chromatography-tandem mass spectrometry coupled with solid-phase extraction
Highly Efficient Copper Doping LaFeO3 Perovskite for Bisphenol A Removal by Activating Peroxymonosulfate
A series of copper doping LaFeO3 perovskite (LaCuxFe1−xO3, LCFO, x = 0.1, 0.4, 0.5, 0.6, 0.9) are successfully synthesized by the sol-gel method under mild conditions. In this study, it is applied for the activation of peroxymonosulfate (PMS) for bisphenol A (BPA) removal. More than 92.6% of BPA was degraded within 30 min at 0.7 g/L of LCFO and 10.0 mM of PMS over a wide pH range with limited leaching of copper and iron ions. The physical–chemical properties of the catalysts were demonstrated by using X-ray diffraction (XRD), N2 adsorption–desorption isotherms, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Furthermore, the effects of catalyst dosage, PMS concentration, initial pH value, and inorganic anions on the LCFO/PMS system were fully investigated. Quenching experiments were performed to verify the formation of reactive oxidant species, which showed that the radical reaction and mechanisms play a great role in the catalytic degradation of BPA. The perovskite LCFO is considered a stable, easy to synthesize, and efficient catalyst for the activation of PMS for wastewater treatment.</jats:p
Experimental Investigation on the Performance of the Scroll Expander under Various Driving Cycles
Energy storage is considered a crucial unit in utilizing renewable energy sources, and compressed air energy storage (CAES) provides a cost-effective solution. It offers the benefits of zero pollution, a long lifespan, low maintenance costs, and minimal environmental impact. In order to increase the possibilities of compressed air energy storage for vehicle power, the performance of the expander needs to be studied. First, a CAES unit test bench is established. Then, the volumetric flow rate, rotational speed, torque, and output power are examined. Additionally, the isentropic exhaust temperature, pressure, and gas consumption rate of the scroll expander are analyzed. Finally, analyzing the economic feasibility of the CAES unit entails running the unit under varied driving conditions. Results reveal that the pressure of the input expander is high, which will lead to greater torque, greater peak power, and a greater temperature drop, but the gas in the air tank will also run out quickly. The peak power of the scroll expander does not occur at the maximum volume flow rate, rotation speed, and torque. The basic investment of the CAES unit mainly depends on the peak output power
Highly Efficient Copper Doping LaFeO3 Perovskite for Bisphenol A Removal by Activating Peroxymonosulfate
A series of copper doping LaFeO3 perovskite (LaCuxFe1−xO3, LCFO, x = 0.1, 0.4, 0.5, 0.6, 0.9) are successfully synthesized by the sol-gel method under mild conditions. In this study, it is applied for the activation of peroxymonosulfate (PMS) for bisphenol A (BPA) removal. More than 92.6% of BPA was degraded within 30 min at 0.7 g/L of LCFO and 10.0 mM of PMS over a wide pH range with limited leaching of copper and iron ions. The physical–chemical properties of the catalysts were demonstrated by using X-ray diffraction (XRD), N2 adsorption–desorption isotherms, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Furthermore, the effects of catalyst dosage, PMS concentration, initial pH value, and inorganic anions on the LCFO/PMS system were fully investigated. Quenching experiments were performed to verify the formation of reactive oxidant species, which showed that the radical reaction and mechanisms play a great role in the catalytic degradation of BPA. The perovskite LCFO is considered a stable, easy to synthesize, and efficient catalyst for the activation of PMS for wastewater treatment
