Analyses of pyrimidine and purine bases by a combination of paper chromatography and time of flight mass spectrometry

Paper chromatography and mass spectrometry for analyses of pyrimidine and purine base

Four-electron shell structures and an interacting two-electron system in carbon nanotube quantum dots

Low-temperature transport measurements have been carried out on single-wall carbon nanotube quantum dots in a weakly coupled regime in magnetic fields up to 8 Tesla. Four-electron shell filling was observed, and the magnetic field evolution of each Coulomb peak was investigated, in which magnetic field induced spin flip and resulting spin polarization were observed. Excitation spectroscopy measurements have revealed Zeeman splitting of single particle states for one electron in the shell, and demonstrated singlet and triplet states with direct observation of the exchange splitting at zero-magnetic field for two electrons in the shell, the simplest example of the Hund's rule. The latter indicates the direct analogy to an artificial He atom.Comment: 4 pages, 3 figures, submitted to Physical Review Letter

Superconductor-insulator transition in nanowires and nanowire arrays

Superconducting nanowires are the dual elements to Josephson junctions, with quantum phase-slip processes replacing the tunneling of Cooper pairs. When the quantum phase-slip amplitude ES is much smaller than the inductive energy EL, the nanowire responds as a superconducting inductor. When the inductive energy is small, the response is capacitive. The crossover at low temperatures as a function of ES/EL is discussed and compared with earlier experimental results. For one-dimensional and two-dimensional arrays of nanowires quantum phase transitions are expected as a function of ES/EL. They can be tuned by a homogeneous magnetic frustration.Comment: 15 pages, 10 figure

Heavy-Electron Formation and Bipolaronic Transition in the Anharmonic Holstein Model

The emergence of the bipolaronic phase and the formation of the heavy-electron state in the anharmonic Holstein model are investigated using the dynamical mean-field theory in combination with the exact diagonalization method. For a weak anharmonicity, it is confirmed that the first-order polaron-bipolaron transition occurs from the observation of a discontinuity in the behavior of several physical quantities. When the anharmonicity is gradually increased, the polaron-bipolaron transition temperature is reduced as well as the critical values of the electron-phonon coupling constant for polaron-bipolaron transition. For a strong anharmonicity, the polaron-bipolaron transition eventually changes to a crossover behavior. The effect of anharmonicity on the formation of the heavy-electron state near the polaron-bipolaron transition and the crossover region is discussed in detail.Comment: 11 pages, 13 figure

Outburst of Comet 17P/Holmes Observed With The Solar Mass Ejection Imager

We present time-resolved photometric observations of Jupiter family comet 17P/Holmes during its dramatic outburst of 2007. The observations, from the orbiting Solar Mass Ejection Imager (SMEI), provide the most complete measure of the whole-coma brightness, free from the effects of instrumental saturation and with a time-resolution well-matched to the rapid brightening of the comet. The lightcurve is divided into two distinct parts. A rapid rise between the first SMEI observation on UT 2007 October 24 06h 37m (mid-integration) and UT 2007 October 25, is followed by a slow decline until the last SMEI observation on UT 2008 April 6 22h 16m (mid-integration). We find that the rate of change of the brightness is reasonably well-described by a Gaussian function having a central time of UT 2007 October 24.54+/-0.01 and a full-width-at-half-maximum 0.44+/-0.02 days. The maximum rate of brightening occurs some 1.2 days after the onset of activity. At the peak the scattering cross-section grows at 1070+/-40 km^2/s while the (model-dependent) mass loss rates inferred from the lightcurve reach a maximum at 3+/-10^5 kg/s. The integrated mass in the coma lies in the range (2 to 90)x10^10 kg, corresponding to 0.2% to 10% of the nucleus mass, while the kinetic energy of the ejecta is (0.6 to 30) MTonnes TNT. The particulate coma mass could be contained within a shell on the nucleus of thickness ~1.5 to 60 m. This is comparable to the distance traveled by conducted heat in the century since the previous outburst of 17P/Holmes. This coincidence is consistent with, but does not prove, the idea that the outburst was triggered by the action of conducted heat, possibly through the crystallization of buried amorphous ice.Comment: 27 pages, 8 figures; http://www2.ess.ucla.edu/~jingli/Holmes_SMEI/17P_Holmes.htm

Strong-Coupling Theory of Rattling-Induced Superconductivity

In order to clarify the mechanism of the enhancement of superconducting transition temperature $T_{\rm c}$ due to anharmonic local oscillation of a guest ion in a cage composed of host atoms, i.e., {\it rattling}, we analyze the anharmonic Holstein model by applying the Migdal-Eliashberg theory. From the evaluation of the normal-state electron-phonon coupling constant, it is found that the strong coupling state is developed, when the bottom of a potential for the guest ion becomes wide and flat. Then, $T_{\rm c}$ is enhanced with the increase of the anharmonicity in the potential, although $T_{\rm c}$ is rather decreased when the potential becomes a double-well type due to very strong anharmonicity. From these results, we propose a scenario of anharmonicity-controlled strong-coupling tendency for superconductivity induced by rattling. We briefly discuss possible relevance of the present scenario with superconductivity in $\beta$-pyrochlore oxides.Comment: 8 pages, 6 figure

Light Lambda-Lambda Hypernuclei and the Onset of Stability for Lambda-Xi Hypernuclei

New Faddeev-Yakubovsky calculations for light Lambda-Lambda hypernuclei are presented in order to assess the self consistency of the Lambda-Lambda hypernuclear binding-energy world data and the implied strength of the Lambda-Lambda interaction, in the wake of recent experimental reports on Lambda-Lambda-4H and Lambda-Lambda-6He. Using Gaussian soft-core simulations of Nijmegen one-boson-exchange model interactions, the Nijmegen soft-core model NSC97 simulations are found close to reproducing the recently reported binding energy of Lambda-Lambda-6He, but not those of other species. For stranger systems, Faddeev calculations of light Lambda-Xi hypernuclei, using a simulation of the strongly attractive Lambda-Xi interactions due to the same model, suggest that Lambda-Xi-6He marks the onset of nuclear stability for Xi hyperons.Comment: 5 pages, 3 postscript figures; fig.2 replaced, minor changes, accepted as Rapid Communication in PR

Faddeev calculations for the A=5,6 Lambda-Lambda hypernuclei

Faddev calculations are reported for Lambda-Lambda-5H, Lambda-Lambda-5He and Lambda-Lambda-6He in terms of two Lambda hyperons plus the respective nuclear clusters, using Lambda-Lambda central potentials considered in past non-Faddeev calculations of Lambda-Lambda-6He. The convergence with respect to the partial-wave expansion is studied, and comparison is made with some of these Lambda-Lambda hypernuclear calculations. The Lambda-Lambda Xi-N mixing effect is briefly discussed.Comment: submitted for publicatio

Measurement of the π−\pi^- decay width of Λ5^5_\LambdaHe

We have precisely measured $\Lambda \to p\pi^-$ decay width of \5LHe and demonstrated significantly larger $\alpha$ -$\Lambda$ overlap than expected from the central repulsion $\alpha$-$\Lambda$ potential, which is derived from YNG \Lambda$-nucleon interaction.Comment: 4 pages, 3 figure

Theoretical Investigation of the Circularly Polarized Luminescence of a Chiral Boron Dipyrromethene (BODIPY) Dye

Over the last decade, molecules capable of emitting circularly polarized light have attracted growing attention for potential technological and biological applications. The efficiency of such devices depend on multiple parameters, in particular the magnitude and wavelength of the peak of emitted light, and also on the dissymmetry factor for chiral applications. In light of these considerations, molecular systems with tunable optical properties, preferably in the visible spectral region, are particularly appealing. This is the case of boron dipyrromethene (BODIPY) dyes, which exhibit large molecular absorption coefficients, have high fluorescence yields, are very stable, both thermally and photochemically, and can be easily functionalized. The latter property has been extensively exploited in the literature to produce chromophores with a wide range of optical properties. Nevertheless, only a few chiral BODIPYs have been synthetized and investigated so far. Using a recently reported axially chiral BODIPY derivative where an axially chiral BINOL unit has been attached to the chromophore unit, we present a comprehensive computational protocol to predict and interpret the one-photon absorption and emission spectra, together with their chiroptical counterparts. From the physico-chemical properties of this molecule, it will be possible to understand the origin of the circularly polarized luminescence better, thus helping to fine-tune the properties of interest. The sensitivity of such processes require accurate results, which can be achieved through a proper account of the vibrational structure in optical spectra. Methodologies to compute vibrationally-resolved electronic spectra can now be applied on relatively large chromophores, such as BODIPYs, but require more extensive computational protocols. For this reason, particular attention is paid in the description of the different steps of the protocol, and the potential pitfalls. Finally, we show how, by means of appropriate tools and approaches, data from intermediate steps of the simulation of the final spectra can be used to obtain further insights into the properties of the molecular system under investigation and the origin of the visible bands