Impact of environmental moisture on C(3)A polymorphs in the absence and presence of CaSO4 center dot 0.5 H2O

The phenomenon of water vapour sorption by anhydrous C3A polymorphs both in the absence and in the presence of CaSO4·0·5 H2O was studied utilising dynamic and static sorption methods. It was found that orthorhombic C3A starts to sorb water at 55% relative humidity (RH) and cubic C3A at 80% RH. Also, C3Ao sorbs a higher amount of water which is predominantly physically bound, whereas C3Ac preferentially interacts with water by chemical reaction. In the presence of calcium sulfate hemihydrate, ettringite was observed as the predominant pre-hydration product for both C3A modifications: that is, ion transport had occurred between C3A and sulfate. Environmental scanning electron microscopic imaging revealed that in a moist atmosphere, a liquid water film condenses on the surface of the phases as a consequence of capillary condensation between the particles. C3A and sulfate can then dissolve and react with each other. Seemingly, pre-hydration is mainly facilitated through capillary condensation and less through surface interaction with gaseous water molecules

Compared to conventional, ecological intensive management promotes beneficial proteolytic soil microbial communities for agro-ecosystem functioning under climate change-induced rain regimes

Projected climate change and rainfall variability will affect soil microbial communities, biogeochemical cycling and agriculture. Nitrogen (N) is the most limiting nutrient in agroecosystems and its cycling and availability is highly dependent on microbial driven processes. In agroecosystems, hydrolysis of organic nitrogen (N) is an important step in controlling soil N availability. We analyzed the effect of management (ecological intensive vs. conventional intensive) on N-cycling processes and involved microbial communities under climate change-induced rain regimes. Terrestrial model ecosystems originating from agroecosystems across Europe were subjected to four different rain regimes for 263 days. Using structural equation modelling we identified direct impacts of rain regimes on N-cycling processes, whereas N-related microbial communities were more resistant. In addition to rain regimes, management indirectly affected N-cycling processes via modifications of N-related microbial community composition. Ecological intensive management promoted a beneficial N-related microbial community composition involved in N-cycling processes under climate change-induced rain regimes. Exploratory analyses identified phosphorus-associated litter properties as possible drivers for the observed management effects on N-related microbial community composition. This work provides novel insights into mechanisms controlling agro-ecosystem functioning under climate change

Enthalpy of formation of ye’elimite and ternesite

Calcium sulfoaluminate clinkers containing ye’elimite (Ca4Al6O12(SO4)) and ternesite (Ca5(SiO4)2SO4) are being widely investigated as components of calcium sulfoaluminate cement clinkers. These may become low energy replacements for Portland cement. Conditional thermodynamic data for ye’elimite and ternesite (enthalpy of formation) have been determined experimentally using a combination of techniques: isothermal conduction calorimetry, X-ray powder diffraction and thermogravimetric analysis. The enthalpies of formation of ye’elimite and ternesite at 25 °C were determined to be − 8523 and − 5993 kJ mol−1, respectively

Time‐spatial variability observed in velocity of propagation of the internal bore in the Strait of Gibraltar

Some aspects of the time‐spatial variability of the phase speed of the internal bore generated almost every tidal cycle in Camarinal Sill, are revised using a set of high resolution experimental data collected in two different positions of the Strait during May 2003. This variability is mainly driven by the intense tidal currents, comparable with the intrinsic propagation velocity of the first mode baroclinic bore. It is shown that the importance of the diurnal tide in the Strait of Gibraltar induces a considerable diurnal inequality on the bore velocity, with an observed maximum difference of 0.7 ms−1 between the speed of two consecutives bores propagating along the eastern part of the Strait. A regularly spatial pattern has been also found: the internal bore reaches its maximum velocity in Tarifa Narrows. A theoretical estimation predicts an extreme phase speed of 2.6 ms−1 during our period of study

Liderazgo femenino en los diarios digitales El Comercio y El Universo de Ecuador

Last couple of years, female presence has increased in Ecuadorian political institutions. However, the visibility of women in the public media continues to be limited. In this context, we investigate how these women are represented by the digital media. We conducted a descriptive study of the socio-demographic characterization of women in published opinion in the digital newspapers El Universo and El Comercio. We identify to what extent these media take women as a reference in their publications, and what are the female profiles in this regard. Through a number of 2,203 press-releases published between 2010 and 2015, we analyze the frequency of appearance of 78 women referred as sources of news. In general, we observe that women consulted as journalistic sources in digital newspapers fluctuate between 35 and 50 years of age, more than 50% identify themselves as mestizas, and most of them have university studies.FGW – Publications without University Leiden contrac

Progression of Wave Breaker Types on a Plane Impermeable Slope, Depending on Experimental Design

M. V. Moragues was supported by the research group TEP-209 (Junta de Andalucia) and by the following projects: "Protection of coastal urban fronts against global warming-PROTOCOL" (917PTE0538), "Integrated verification of the hydrodynamic and structural behavior of a breakwater and its implications on the investment project-VIVALDI" (BIA2015-65598-P). This work was funded by the projects PCI2019-103565-SUSME and PID2019-107509GB-I00-ROMPEOLAS (SRA (State Research Agency)/10.13039/501100011033). M. A. Losada was partially funded by the emeritus professorship mentoring program of the University of Granada. We would like to thank the three reviewers for providing helpful comments on earlier drafts of the manuscript.The objective of this research was to analyze the progression of breaker types on plane impermeable slopes. This study used dimensional analysis to demonstrate the relative water depth is a key explanatory quantity. The dominant breaker types depend on the incident wave characteristics at the foot of the slope. Accordingly, it is possible to combine values of H, T, and m. The physical experiments of Galvin, recent numerical results, and new experiments, performed on an impermeable 1:10 slope, were used to verify the result. It was thus possible to obtain the progression of breaker types in different sequences of pairs of combined wave H and T values. Once a sequence is defined, the expected progression of breaker types is predictable, and is well approximated by the log-transform of the alternate similarity parameter. Since the classification of breaker types is discontinuous, the data assigned to each type were placed in horizontal lines, based on the value of log(chi). Given that the breaking of a wave train on a slope should be considered a continuous process, the location of some data was corrected to satisfy this assumption. There is thus a functional relationship between the sets of the experimental space and of the breaker types. This research also derives the non-dimensional energy dissipation on the slope, considering the wave-reflected energy flux on the slope. It is proportional to a dimensionless bulk dissipation coefficient which depends on the breaker type and, therefore, on the value of chi at the toe of the slope.Junta de Andalucia 917PTE0538 BIA2015-65598-Pemeritus professorship mentoring program of the University of GranadaPCI2019-103565-SUSMEPID2019-107509GB-I00-ROMPEOLAS10.13039/50110001103

Increasing the number of stressors reduces soil ecosystem services worldwide

Increasing the number of environmental stressors could decrease ecosystem functioning in soils. Yet this relationship has never been globally assessed outside laboratory experiments. Here, using two independent global standardized field surveys, and a range of natural and human factors, we test the relationship between the number of environmental stressors exceeding different critical thresholds and the maintenance of multiple ecosystem services across biomes. Our analysis shows that, multiple stressors, from medium levels (>50%), negatively and significantly correlates with impacts on ecosystem services, and that multiple stressors crossing a high-level critical threshold (over 75% of maximum observed levels), reduces soil biodiversity and functioning globally. The number of environmental stressors >75% threshold was consistently seen as an important predictor of multiple ecosystem services, therefore improving prediction of ecosystem functioning. Our findings highlight the need to reduce the dimensionality of the human footprint on ecosystems to conserve biodiversity and function

Frontiers in soil ecology—Insights from the World Biodiversity Forum 2022

Global change is affecting soil biodiversity and functioning across all terrestrial ecosystems. Still, much is unknown about how soil biodiversity and function will change in the future in response to simultaneous alterations in climate and land use, as well as other environmental drivers. It is crucial to understand the direct, indirect and interactive effects of global change drivers on soil communities and ecosystems across environmental contexts, not only today but also in the near future. This is particularly relevant for international efforts to tackle climate change like the Paris Agreement, and considering the failure to achieve the 2020 biodiversity targets, especially the target of halting soil degradation. Here, we outline the main frontiers related to soil ecology that were presented and discussed at the thematic sessions of the World Biodiversity Forum 2022 in Davos, Switzerland. We highlight multiple frontiers of knowledge associated with data integration, causal inference, soil biodiversity and function scenarios, critical soil biodiversity facets, underrepresented drivers, global collaboration, knowledge application and transdisciplinarity, as well as policy and public communication. These identified research priorities are not only of immediate interest to the scientific community but may also be considered in research priority programmes and calls for funding

Induction of Foxp3-Expressing Regulatory T-Cells by Donor Blood Transfusion Is Required for Tolerance to Rat Liver Allografts

BACKGROUND:Donor-specific blood transfusion (DST) prior to solid organ transplantation has been shown to induce long-term allograft survival in the absence of immunosuppressive therapy. Although the mechanisms underlying DST-induced allograft tolerance are not well defined, there is evidence to suggest DST induces one or more populations of antigen-specific regulatory cells that suppress allograft rejection. However, neither the identity nor the regulatory properties of these tolerogenic lymphocytes have been reported. Therefore, the objective of this study was to define the kinetics, phenotype and suppressive function of the regulatory cells induced by DST alone or in combination with liver allograft transplantation (LTx). METHODOLOGY/PRINCIPAL FINDINGS:Tolerance to Dark Agouti (DA; RT1(a)) rat liver allografts was induced by injection (iv) of 1 ml of heparinized DA blood to naïve Lewis (LEW; RT1(l)) rats once per week for 4 weeks prior to LTx. We found that preoperative DST alone generates CD4(+) T-cells that when transferred into naïve LEW recipients are capable of suppressing DA liver allograft rejection and promoting long-term survival of the graft and recipient. However, these DST-generated T-cells did not express the regulatory T-cell (Treg) transcription factor Foxp3 nor did they suppress alloantigen (DA)-induced activation of LEW T-cells in vitro suggesting that these lymphocytes are not fully functional regulatory Tregs. We did observe that DST+LTx (but not DST alone) induced the time-dependent formation of CD4(+)Foxp3(+) Tregs that potently suppressed alloantigen-induced activation of naïve LEW T-cells in vitro and liver allograft rejection in vivo. Finally, we present data demonstrating that virtually all of the Foxp3-expressing Tregs reside within the CD4(+)CD45RC(-) population whereas in which approximately 50% of these Tregs express CD25. CONCLUSIONS/SIGNIFICANCE:We conclude that preoperative DST, in the absence of liver allograft transplantation, induces the formation of CD4(+) T-cells that are not themselves Tregs but give rise directly or indirectly to fully functional CD4(+)CD45RC(-)Foxp3(+)Tregs when transferred into MHC mismatched recipients prior to LTx. These Tregs possess potent suppressive activity and are capable of suppressing acute liver allograft rejection. Understanding the mechanisms by which preoperative DST induces the generation of tolerogenic Tregs in the presence of alloantigens may lead to the development of novel antigen-specific immunological therapies for the treatment of solid organ rejection