Review of catalytic systems and thermodynamics for the Guerbet condensation reaction and challenges for biomass valorization

The Guerbet condensation reaction is an alcohol coupling reaction that has been known for more than a century. Because of the increasing availability of bio-based alcohol feedstock, this reaction is of growing importance and interest in terms of value chains of renewable chemical and biofuel production. Due to the specific branching pattern of the alcohol products, the Guerbet reaction has many interesting applications. In comparison to their linear isomers, branched-chain Guerbet alcohols have extremely low melting points and excellent fluidity. This review provides thermodynamic insights and unravels the various mechanistic steps involved. A comprehensive overview of the homogeneous, heterogeneous and combined homogeneous and heterogeneous catalytic systems described in published reports and patents is also given. Technological considerations, challenges and perspectives for the Guerbet chemistry are discussed

Sediment Trapping By Terraced Paddy Field On Slopping Agricultural Land

Terraced paddy field is not only important for rural food security, but also for trapping sediment in the slopping land. The aims of this research were to quantify the amount of incoming and outgoing sediments and to study sediment movement behavior during harrowing and fertilizing under traditional irrigation of terraced paddy field system. This study was carried out at Keji Village, Semarang District, Central Java during two cropping seasons, a wet season 2003/04 and a dry season 2004. A paddy field with eight terraces was selected. The terraces were flat, different in size and descending to the river. Sediment samples were taken at harrowing and fertilizing activities. The results indicated that at harrowing, outgoing sediment was higher than incoming both during the wet and the dry seasons. About 0.53 and 0.27 t ha-1 day-1 of soil were eroded during harrowing in the wet and the dry seasons, respectively. However, a week before and after fertilizing, both in the wet and the dry seasons, the amounts of incoming sediment were higher than the outgoing one. In the wet season, the amounts of incoming sediments were three to four times higher than the outgoing one, both a week before and after fertilizing. During the wet season, about 0.31 and 0.34 t ha-1 day-1 of sediment was yielded a week before and after fertilizing, respectively. During the dry season, the incoming sediments were ten times higher than the outgoing one. On an average the sediment yields were about 0.07 and 0.08 t ha-1 day-1 a week before and after fertilizing, respectively. Terraces having greater areas deposited more sediment than those with smaller sizes. During a week before and after first fertilizing, the total amounts of incoming sediments were 6.44 and 1.19 t ha-1 for the wet and dry seasons, while that of outgoing sediments were 1.89 and 0.14 t ha-1 for the wet and dry seasons, respectively. This indicates that terraced paddy fields are not only producing rice, but also providing environmental service in term of sediment trapping. This external service minimizes sedimentation in the downstream

Modelling water-harvesting systems in the arid south of Tunisia using SWAT

In many arid countries, runoff water-harvesting systems support the livelihood of the rural population. Little is known, however, about the effect of these systems on the water balance components of arid watersheds. The objective of this study was to adapt and evaluate the GIS-based watershed model SWAT (Soil Water Assessment Tool) for simulating the main hydrologic processes in arid environments. The model was applied to the 270-km(2) watershed of wadi Koutine in southeast Tunisia, which receives about 200 mm annual rain. The main adjustment for adapting the model to this dry Mediterranean environment was the inclusion of water-harvesting systems, which capture and use surface runoff for crop production in upstream subbasins, and a modification of the crop growth processes. The adjusted version of the model was named SWAT-WH. Model evaluation was performed based on 38 runoff events recorded at the Koutine station between 1973 and 1985. The model predicted that the average annual watershed rainfall of the 12-year evaluation period (209 mm) was split into ET (72%), groundwater recharge (22%) and outflow (6%). The evaluation coefficients for calibration and validation were, respectively, R-2 (coefficient of determination) 0.77 and 0.44; E (Nash-Sutcliffe coefficient) 0.73 and 0.43; and MAE (Mean Absolute Error) 2.6 mm and 3.0 mm, indicating that the model could reproduce the observed events reasonably well. However, the runoff record was dominated by two extreme events, which had a strong effect on the evaluation criteria. Discrepancies remained mainly due to uncertainties in the observed daily rainfall and runoff data. Recommendations for future research include the installation of additional rainfall and runoff gauges with continuous data logging and the collection of more field data to represent the soils and land use. In addition, crop growth and yield monitoring is needed for a proper evaluation of crop production, to allow an economic assessment of the different water uses in the watershed

Using an inverse modelling approach to evaluate the water retention in a simple water harvesting technique

In arid and semi-arid zones, runoff harvesting techniques are often applied to increase the water retention and infiltration on steep slopes. Additionally, they act as an erosion control measure to reduce land degradation hazards. Nevertheless, few efforts were observed to quantify the water harvesting processes of these techniques and to evaluate their efficiency. In this study, a combination of detailed field measurements and modelling with the HYDRUS-2D software package was used to visualize the effect of an infiltration trench on the soil water content of a bare slope in northern Chile. Rainfall simulations were combined with high spatial and temporal resolution water content monitoring in order to construct a useful dataset for inverse modelling purposes. Initial estimates of model parameters were provided by detailed infiltration and soil water retention measurements. Four different measurement techniques were used to determine the saturated hydraulic conductivity (<I>K</I><sub>sat</sub>) independently. The tension infiltrometer measurements proved a good estimator of the <I>K</I><sub>sat</sub> value and a proxy for those measured under simulated rainfall, whereas the pressure and constant head well infiltrometer measurements showed larger variability. Six different parameter optimization functions were tested as a combination of soil-water content, water retention and cumulative infiltration data. Infiltration data alone proved insufficient to obtain high model accuracy, due to large scatter on the data set, and water content data were needed to obtain optimized effective parameter sets with small confidence intervals. Correlation between the observed soil water content and the simulated values was as high as <I>R</I><sup>2</sup>=0.93 for ten selected observation points used in the model calibration phase, with overall correlation for the 22 observation points equal to 0.85. The model results indicate that the infiltration trench has a significant effect on soil-water storage, especially at the base of the trench

Predicting soil water content at -33 kPa by pedotransfer functions in stoniness 1 soils in northeast Venezuela

Soil water content is a key property in the study of water available for plants, infiltration, drainage, hydraulic conductivity, irrigation, plant water stress and solute movement. However, its measurement consumes time and, in the case of stony soils, the presence of stones difficult to determinate the water content. An alternative is the use of pedotransfer functions (PTFs), as models to predict these properties from readily available data. The present work shows a comparison of different widely used PTFs to estimate water content at-33 kPa (WR - 33kPa ) in high stoniness soils. The work was carried out in the Caramacate River, an area of high interest because the frequent landslides worsen the quality of drinking water. The performance of all evaluated PTFs was compared with a PTF generated for the study area. Results showed that the Urach's PTF presented the best performance in relation to the others and could be used to estimate WR -33kPa in soils of Caramacate River basin. The calculated PTFs had a R2 of 0.65. This was slightly higher than the R2 of the Urach's PTF. The inclusion of the rock fragment volume could have the better results. The weak performance of the other PTFs could be related to the fact that the mountain soils of the basin are rich in 2:1 clay and high stoniness, which were not used as independent variables for PTFs to estimate the WR -33kPa.The authors are grateful to the Abdus Salam International Centre for Theoretical Physics (ICTP), Trieste, Italy, the Venezuelan Organic Law for Science and Technology (LOCTI), and the Council of Scientific and Humanistic Develop- ment (CDCH) of the Universidad Central de Venezuela, the Universidad de Lleida (Catalonia, Spain), and the Brazilian Re- search Council (CNPq) for the scholarships and funding

Increasing compliance with wearing a medical device in children with autism

Health professionals often recommend the use of medical devices to assess the health, monitor the well-being, or improve the quality of life of their patients. Children with autism may present challenges in these situations as their sensory peculiarities may increase refusals to wear such devices. To address this issue, we systematically replicated prior research by examining the effects of differential reinforcement of other behavior (DRO) to increase compliance with wearing a heart rate monitor in 2 children with autism. The intervention increased compliance to 100% for both participants when an edible reinforcer was delivered every 90 s. The results indicate that DRO does not require the implementation of extinction to increase compliance with wearing a medical device. More research is needed to examine whether the reinforcement schedule can be further thinned

ECOPLAN-SE: Ruimtelijke analyse van ecosysteemdiensten in Vlaanderen, een Q-GIS plugin

ECOPLAN-SE is een ruimtelijk expliciete tool (QGIS) voor het beoordelen van de impact van landgebruikveranderingen op de levering van ecosysteemdiensten. De ontwikkeling van deze tool kadert in het het SBO-project “ECOPLAN” (Planning for Ecosystem Services). ECOPLAN ontwikkelt ruimtelijk expliciete informatie en instrumenten voor de beoordeling van ecosysteemdiensten. Het ontwerpt instrumenten voor de evaluatie van functionele ecosystemen als een kostenefficiënte strategie om de landgebruiksefficiëntie en milieukwaliteit te verbeteren. Het ontwikkelt open source eindproducten voor het identificeren, kwantificeren, waarderen, valideren en monitoren van ecosysteemdiensten. Deze producten kunnen door administraties en consultants worden ingezet in projectontwikkeling, kosten-baten analyses, milieueffecten rapportering, etc

SEDIMENT TRAPPING BY TERRACED PADDY FIELD ON SLOPPING AGRICULTURAL LAND

Terraced paddy field is not only important for rural food security, but also for trapping sediment in the slopping land. The aims of this research were to quantify the amount of incoming and outgoing sediments and to study sediment movement behavior during harrowing and fertilizing under traditional irrigation of terraced paddy field system. This study was carried out at Keji Village, Semarang District, Central Java during two cropping seasons, a wet season 2003/04 and a dry season 2004. A paddy field with eight terraces was selected. The terraces were flat, different in size and descending to the river. Sediment samples were taken at harrowing and fertilizing activities. The results indicated that at harrowing, outgoing sediment was higher than incoming both during the wet and the dry seasons. About 0.53 and 0.27 t ha-1 day-1 of soil were eroded during harrowing in the wet and the dry seasons, respectively. However, a week before and after fertilizing, both in the wet and the dry seasons, the amounts of incoming sediment were higher than the outgoing one. In the wet season, the amounts of incoming sediments were three to four times higher than the outgoing one, both a week before and after fertilizing. During the wet season, about 0.31 and 0.34 t ha-1 day-1 of sediment was yielded a week before and after fertilizing, respectively. During the dry season, the incoming sediments were ten times higher than the outgoing one. On an average the sediment yields were about 0.07 and 0.08 t ha-1 day-1 a week before and after fertilizing, respectively. Terraces having greater areas deposited more sediment than those with smaller sizes. During a week before and after first fertilizing, the total amounts of incoming sediments were 6.44 and 1.19 t ha-1 for the wet and dry seasons, while that of outgoing sediments were 1.89 and 0.14 t ha-1 for the wet and dry seasons, respectively. This indicates that terraced paddy fields are not only producing rice, but also providing environmental service in term of sediment trapping. This external service minimizes sedimentation in the downstream.