Technologies for Deep Biogas Purification and Use in Zero-Emission Fuel Cells Systems

A proper exploitation of biogas is key to recovering energy from biowaste in the framework of a circular economy and environmental sustainability of the energy sector. The main obstacle to widespread and efficient utilization of biogas is posed by some trace compounds (mainly sulfides and siloxanes), which can have a detrimental effect on downstream gas users (e.g., combustion engines, fuel cells, upgrading, and grid injection). Several purification technologies have been designed throughout the years. The following work reviews the main commercially available technologies along with the new concepts of cryogenic separation. This analysis aims to define a summary of the main technological aspects of the clean-up and upgrading technologies. Therefore, the work highlights which benefits and criticalities can emerge according to the intended final biogas application, and how they can be mitigated according to boundary conditions specific to the plant site (e.g., freshwater availability in WWTPs or energy recovery)

Experimental Analysis and Model Validation on the Performance of Impregnated Activated Carbons for the Removal of Hydrogen Sulfide (H2S) from Sewage Biogas

Organic waste exploitation is crucial for waste emissions restraint in air, soil and water. This type of waste can be exploited to produce biogas, a valuable fuel exploitable for energy purposes. A circular approach for energy production is much cleaner and more sustainable than the traditional linear approach. In this work, organic waste was used for biogas production to feed a highly efficient solid oxide fuel cell power generator, which requires an ultra-purified fuel. Commercial sorbents were experimentally studied in conjunction with a dynamic adsorption model to predict the breakthrough time and organize the material change-over. In the presence of 0.1% oxygen in the gas mixture, AirDep® CKC showed a marked increase in the adsorption capacity (from 3.91 to 84.87 mg/g), overcoming SulfaTrap® R8G (49.91 mg/g). The effect of several operating parameters on adsorption capacity was evaluated: inlet H2S concentration, filter geometry and gas mixture velocity. Experimental data revealed that adsorption capacity increases with initial H2S concentration, following the typical trend of the Langmuir isotherm. Model simulations were in good agreement compared to experimental results, with an average relative error lower than 7%. A sensitivity analysis on the adsorption capacity was accomplished considering parameters from operational and empirical correlations

Optimal design of PV-based grid-connected hydrogen production systems

A cost-optimal design of power-to-hydrogen (PtH) systems is crucial to produce hydrogen at the lowest specific cost. New challenges arise when it comes to ensuring a reliable and cost-effective hydrogen supply in the presence of variable renewable energy sources. In this context, the aim of this analysis is to investigate the optimal design of PV-based grid-connected hydrogen production systems under different scenarios. To this end, an optimisation framework based on the mixed integer linear programming (MILP) technique is developed. Results are presented by employing a set of techno-economic and environmental indicators to provide general guidance on how to optimally size PtH systems, going beyond the analysis of a specific case study. The analysis is applied to Italy and particular attention is paid to exploring the impact of the price of grid electricity. The results indicate that the price of grid electricity strongly affects the optimal design of PtH systems. Specifically, in scenarios with high electricity prices, it is economically convenient to significantly oversize the PV plant and the electrolyser. The optimal PV ratio, representing the ratio between the PV size and the electrolyser size, increases from 1.6 to 2.7 as the electricity price rises from 50 to 300 euro/MWh. Additionally, when electricity prices exceed approximately 120 euro/MWh, the optimal electrolyser size (in terms of hydrogen production under rated conditions) becomes almost three times larger than the average hydrogen demand. By comparing gridconnected and off-grid scenarios, the importance of the electrical grid is also highlighted: even when poorly used, it plays a crucial role in limiting the size of the hydrogen storage. The levelised cost of hydrogen for the optimal PtH configuration falls within the range of 3.5-7 euro/kg (depending on the price of grid electricity) and increases to 8.2 euro/kg when the system operates off-grid. Finally, the hydrogen carbon footprint, quantified as kgCO2,e/kgH2, is also explored. Considering the current price and carbon intensity of grid electricity, t

Carbon recovery from biogas through upgrading and methanation: A techno-economic and environmental assessment

Reducing the use of fossil fuels is an essential measure to counteract the rise in greenhouse gas emissions. In this context, biofuels and e-fuels make an important contribution to achieving climate neutrality targets, especially if their distribution can take place within existing infrastructure, as in the case of methane. The aim of this work is to carry out a techno-economic and environmental assessment of the combined production of biological and synthetic methane in a wastewater treatment plant (WWTP). Methane yield from biogas, usually associated only with biogas upgrading, is enhanced by recovering CO2 to produce additional synthetic natural gas (SNG) through a methanation process. The analysis is applied to a medium-sized WWTP in Italy, whose biogas production profile is known throughout the year. In the current scenario, SNG is not competitive on the gas market. The investment costs of the technologies and the electricity price are then varied in order to better investigate the profitability of SNG production. The results show that, considering long-term cost projections and an electricity price of about 50 €/MWh, SNG can become competitive, with a production cost of 1.4 €/Sm3. Finally, the environmental competitiveness of SNG (direct and indirect CO2 emissions) with respect to fossil natural gas is investigated: results are shown as a function of the carbon intensity of grid electricity and the share of local renewable energy. To make SNG environmentally sustainable, the renewable share must increase to 46% or, alternatively, the carbon intensity of grid electricity must decrease to 187 gCO2eq/kWh

A Circular Approach for Making Fischer–Tropsch E-fuels and E-chemicals From Biogas Plants in Europe

In a mature circular economy model of carbon material, no fossil compound is extracted from the underground. Hence, the C1 molecule from non-fossil sources such as biogas, biomass, or carbon dioxide captured from the air represents the raw material to produce various value-added products through carbon capture and utilization routes. Accordingly, the present work investigates the utilization of the full potential of biogas and digestate waste streams derived from anaerobic digestion processes available at the European level to generate synthetic Fischer–Tropsch products focusing on the wax fraction. This study estimates a total amount of available carbon dioxide of 33.9 MtCO2/y from the two above-mentioned sources. Of this potential, 10.95 MtCO2/y is ready-to-use as separated CO2 from operating biogas-upgrading plants. Similarly, the total amount of ready-to-use wet digestate corresponds to 29.1 Mtdig/y. Moreover, the potential out-take of Fischer–Tropsch feedstock was evaluated based on process model results. Utilizing the full biogas plants’ carbon potential available in Europe, a total of 10.1 Mt/h of Fischer–Tropsch fuels and 3.86 Mt/h of Fischer–Tropsch waxes can be produced, covering up to 79% of the global wax demand. Utilizing only the streams derived from biomethane plants (installed in Europe), 136 ton/h of FT liquids and 48 ton/h of FT wax can be generated, corresponding to about 8% of the global wax demand. Finally, optimal locations for cost-effective Fischer–Tropsch wax production were also identified

Fuel cell cogeneration for building sector: European status

The advantages of fuel cell based micro-cogeneration systems are the high electrical and total efficiency coupled with zero pollutants emission, which makes them good candidates for distributed generation in the building sector. The status of installations, worldwide and European initiatives and the available supporting schemes in Europe are presented

Trace contaminants in biogas: Biomass sources, variability and implications for technology applications

Biogas represents a renewable and controllable energy source. Although predominantly composed of methane and carbon dioxide, it also contains various trace contaminants that can be detrimental to the technologies used for its conversion. The aim of this work is to comprehensively explore trace contaminants in biogas. The assessment employs a two-level approach: an extensive literature review on biogas trace contaminants, complemented with on-site analyses from real-scale biogas plants to enhance and validate the literature findings. The biogas contaminants – sulphur compounds, siloxanes, halocarbons and aromatic compounds – are quantified and categorised into four distinct groups: landfill gas, agricultural gas, gas derived from the organic fraction of municipal solid waste (OFMSW), and gas from wastewater (WWTP). This study also provides contaminant effects and required thresholds for different biogas conversion technologies, including internal combustion engines, upgrading to biomethane, and innovative solid oxide fuel cells (SOFCs). The two-level analysis reveals significant variability in contaminant levels across different biogas sources, with H2S being the most prevalent contaminant, averaging between 181 (WWTP) and 901 ppm (landfill gas). Other sulphur compounds show the highest average concentration in biogas from OFMSW (98 ppm), followed by agricultural and landfill gases. Siloxanes are typically more abundant in biogas from WWTP (2.55 ppm), while landfill gas exhibits the highest average concentrations of halocarbons and aromatic compounds (6 ppm and 109 ppm, respectively). Moreover, this study highlights the need for in-depth measurements of contaminants for highly sensitive technologies, such as SOFCs, to properly design tailored contaminant removal solutions

Design of hydrogen production systems powered by solar and wind energy: An insight into the optimal size ratios

Green hydrogen is expected to play a crucial role in the future energy landscape, particularly in the pursuit of deep decarbonisation strategies within hard-to-abate sectors, such as the chemical and steel industries and heavy-duty transport. However, competitive production costs are vital to unlock the full potential of green hydrogen. In the case of green hydrogen produced via water electrolysis powered by fluctuating renewable energy sources, the design of the plant plays a pivotal role in achieving market-competitive production costs. The present work investigates the optimal design of power-to-hydrogen systems powered by renewable sources (solar and wind energy). A detailed model of a power-to-hydrogen system is developed: an energy simulation framework, coupled with an economic assessment, provides the hydrogen production cost as a function of the component sizes. By spanning a wide range of size ratios, namely the ratio between the size of the renewable generator and the size of the electrolyser, the cost-optimal design point (minimum hydrogen production cost) is identified. This investigation is carried out for three plant configurations: solar-only, wind-only and hybrid. The objective is to extend beyond the analysis of a specific case study and provide broadly applicable considerations for the optimal design of green hydrogen production systems. In particular, the rationale behind the cost-optimal size ratio is unveiled and discussed through energy (utilisation factors) and economic (hydrogen production cost) indicators. A sensitivity analysis on investment costs for the power-to-hydrogen technologies is also conducted to explore various technological learning paths from today to 2050. The optimal size ratio is found to be a trade-off between the utilisation factors of the electrolyser and the renewable generator, which exhibit opposite trends. Moreover, the costs of the power-to-hydrogen technologies are a key factor in determining the optimal size ratio: depending on these costs, the optimal solution tends to improve one of the two utilization factors at the expense of the other. Finally, the optimal size ratio is foreseen to decrease in the upcoming years, primarily due to the reduction in the investment cost of the electrolyser

Energy and environmental performance from field operation of commercial-scale SOFC systems

Solid Oxide Fuel Cells (SOFCs) are capable of generating electrical and thermal power with very high conversion efficiency and almost no pollutant emissions into the atmosphere. Despite extensive literature on SOFC-based energy system models and experimental testing at the cell and short-stack level, there is currently a lack of performance data for SOFC modules under actual field conditions. To fill this gap, the present work investigates the energy and environmental performance of six SOFC modules, ranging in size from 10 to 60 kW, over thousands of hours of operation. These systems, supplied by the three leading SOFC manufacturers in Europe, have been installed and operated in different non-residential buildings worldwide, as part of the European Comsos project. The aim of this study is to establish a comprehensive set of field operation data to characterise commercial-scale SOFC systems. Specifically, raw data are processed to derived electrical and thermal efficiency maps, degradation rates and pollutant emissions, including particulate matter (PM), nitrogen oxides (NOx) and carbon monoxide (CO). A comparison with competing technologies is also provided to better highlight the potential benefits of adopting SOFC-based cogeneration systems. Values in the range of 51–61% were found for the system-level electrical efficiency under rated conditions. The electrical efficiency also remained consistently high across a wide modulation range (between 50% and 100% of rated power), with peak values reaching 65%. In addition, promising results were obtained for the average percentage loss in electrical efficiency, with a minimum value of 0.7%/1000 h. Regarding the environmental analysis, NOx and CO emissions were analysed at both constant and variable power output, proving to be impressively low across the entire modulation range. The same applies to PM concentrations, which were below ambient level. Overall, SOFCs demonstrated to be one of the best cogeneration solutions for commercial-scale systems (tens to hundreds of kW in size), from both an energy and environmental perspective. However, further reductions in costs and dedicated financial schemes are necessary for a widespread market penetration