Effect of the anodization voltage on the porewidening rate of nanoporous anodic alumina

International audienceA detailed study of the pore-widening rate of nanoporous anodic alumina layers as a function of the anodization voltage was carried out. The study focuses on samples produced under the same electrolyte and concentration but different anodization voltages within the self-ordering regime. By means of ellipsometry-based optical characterization, it is shown that in the porewidening process, the porosity increases at a faster rate for lower anodization voltages. This opens the possibility of obtaining three-dimensional nanostructured nanoporous anodic alumina with controlled thickness and refractive index of each layer, and with a refractive index difference of up to 0.24 between layers, for samples produced with oxalic acid electrolytes

Sum decomposition of Mueller-matrix images and spectra of beetle cuticles

International audienceSpectral Mueller matrices measured at multiple angles of incidence as well as Mueller matrix images are recorded on the exoskeletons (cuticles) of the scarab beetles Cetonia aurata and Chrysina argenteola. Cetonia aurata is green whereas Chrysina argenteola is gold-colored. When illuminated with natural (unpolarized) light, both species reflect left-handed and near-circularly polarized light originating from helicoidal structures in their cuticles. These structures are referred to as circular Bragg reflectors. For both species the Mueller matrices are found to be nondiagonal depolarizers. The matrices are Cloude decomposed to a sum of non-depolarizing matrices and it is found that the cuticle optical response, in a first approximation can be described as a sum of Mueller matrices from an ideal mirror and an ideal circular polarizer with relative weights determined by the eigenvalues of the covariance matrices of the measured Mueller matrices. The spectral and image decompositions are consistent with each other. A regression-based decomposition of the spectral and image Mueller matrices is also presented whereby the basic optical components are assumed to be a mirror and a circular polarizer as suggested by the Cloude decomposition. The advantage with a regression decomposition compared to a Cloude decomposition is its better stability as the matrices in the decomposition are determined a priori. The origin of the depolarizing features are discussed but from present data it is not possible to conclude whether the two major components, the mirror and the circular polarizer are laterally separated in domains in the cuticle or if the depolarization originates from the intrinsic properties of the helicoidal structure.-matrix characterization of bee-tle cuticle: polarized and unpolarized reflections from representative architectures," Appl. Opt. 49, 4558–4567 (2010).-induced polarization effects in the cuticle of scarab beetles: 100 years after Michelson," Phil. Mag. 92, 1583–1599 (2012). 4. H. Arwin, T. Berlind, B. Johs, and K. Järrendahl, "Cuticle structure of the scarab beetle Cetonia aurata analyzed by regression analysis of Mueller-matrix ellipsometric data," Opt. Express 21, 22645–22656 (2013). 5. matrices: how to decompose them?," Phys. Status Solidi A 205, 720–727 (2008). 6. S. R. Cloude, "Group theory and polarization algebra," Optik (Stuttgart) 75, 26–36 (1986). 7. S. R. Cloude and E. Pottier, "A review of target decomposition theorems in radar polarimetry," IEEE Trans

Fast and optimal broad-band Stokes/Mueller polarimeter design by the use of a genetic algorithm

A fast multichannel Stokes/Mueller polarimeter with no mechanically moving parts has been designed to have close to optimal performance from 430-2000 nm by applying a genetic algorithm. Stokes (Mueller) polarimeters are characterized by their ability to analyze the full Stokes (Mueller) vector (matrix) of the incident light. This ability is characterized by the condition number, $\kappa$, which directly influences the measurement noise in polarimetric measurements. Due to the spectral dependence of the retardance in birefringent materials, it is not trivial to design a polarimeter using dispersive components. We present here both a method to do this optimization using a genetic algorithm, as well as simulation results. Our results include fast, broad-band polarimeter designs for spectrographic use, based on 2 and 3 Ferroelectric Liquid Crystals, whose material properties are taken from measured values. The results promise to reduce the measurement noise significantly over previous designs, up to a factor of 4.5 for a Mueller polarimeter, in addition to extending the spectral range.Comment: 10 pages, 6 figures, submitted to Optics Expres

Diagnostic techniques for the interaction of non-thermal atmospheric pressure plasmas and targets

The interaction of non-thermal atmospheric pressure plasmas and targets of various properties is an interdisciplinary area of growing interest. The understanding of the interaction mechanisms between a cold atmospheric pressure plasma and the surface of a liquid or a solid target, as well as the modifications induced inside the target, requires in situ study of these phenomena. Techniques for characterizing the plasma above the target are very well developed but on their own they are not sufficient for understanding the interaction with the target because the target itself must be studied while being under direct exposure to the plasma. The topic of this review are the diagnostic techniques for the characterization of the target in a plasma-target system, performed in situ, while under plasma exposure, time-and space- resolved. Examples also include combining the existing gas-phase techniques with the techniques that traditionally characterize the target in absence of plasma. Many approaches stem from plasma science, but also chemistry, material science, mass transport and fluid dynamics. The possibilities and limitations of the in situ characterization techniques for liquid or solid targets are described, with examples of applications to atmospheric pressure non thermal plasma-target systems.</p

Design and fabrication of photonic crystal thin film photovoltaic cells

International audienceWe present the integration of an absorbing planar photonic crystal within a thin film photovoltaic cell. The devices are based on a stack including a hydrogenated amorphous silicon P-i-N junction surrounded by TCO layers, with a back metallic contact. Optical simulations exhibit a significant increase of the integrated absorption in the 300-720nm wavelength range. The global electro-optical characteristics of such a new solar cell, and the impact of surface passivation, are also discussed. Carrier generation rate maps calculated by optical simulations are introduced as input data in a commercial electrical simulation software. The fabrication of such a device is finally addressed, with a specific focus on the use of low cost nanopatterning processes compatible with large areas

Stern-Gerlach experiment with light: separating photons by spin with the method of A. Fresnel

In 1822 A. Fresnel described an experiment to separate a beam of light into its right- and left-circular polarization components using chiral interfaces. Fresnel's experiment combined three crystalline quartz prisms of alternating handedness to achieve a visible macroscopic separation between the two circular components. Such quartz polyprisms were rather popular optical components in XIXth century but today remain as very little known optical devices. This work shows the analogy between Fresnel's experiment and Stern-Gerlach experiment from quantum mechanics since both experiments produce selective deflection of particles (photons in case of Fresnel's method) according to their spin angular momentum. We have studied a historical quartz polyprism with eight chiral interfaces producing a large spatial separation of light by spin. We have also constructed a modified Fresnel biprism to produce smaller separations and we have examined the analogy with Stern-Gerlach apparatus for both strong and weak measurements. The polarimetric analysis of a Fresnel polyprism reveals that it acts as a spin angular momentum analyzer

Increasing signal-to-noise ratio in over-determined Mueller matrices

This work investigates how the signal-to-noise ratio (SNR) of an over-determined Mueller matrix can be improved by changing the method of calculation. Specifically, our investigation focused on comparing SNRs achieved using the vector methodology from the field of partial Mueller polarimetry, and the matrix methodology. We use experimentally derived measurements from an investigation into the time-varying signal produced by the Mueller matrix of an electro-optic Bismuth Silicon Oxide (BSO) crystal undergoing cyclical impact of a Helium plasma ionisation wave. Our findings show that the vector methodology is superior to the matrix methodology, with a maximum SNR of 7.54 versus 4.97. We put forth that the superiority of the vector methodology is due to its greater flexibility, which results in the Mueller matrix being calculated with better condition matrices, and higher levels of SNR in the intensity measurements used for calculation.</p

Towards plasma jet controlled charging of a dielectric target at grounded, biased, and floating potential

Electric field and surface charge measurements are presented to understand the dynamics in the plasma–surface interaction of a plasma jet and a dielectric surface. The ITO coated backside of the dielectric allowed to impose a DC bias and thus compare the influence of a grounded, biased and floating potential. When imposing a controlled potential at the back of the target, the periodical charging is directly dependent on the pulse length, irrespective of that control potential. This is because the plasma plume is sustained throughout the pulse. When uncontrolled and thus with a floating potential surface, charge accumulation and potential build-up prevents a sustained plasma plume. An imposed DC bias also leads to a continuous surface charge to be present accumulated on the plasma side to counteract the bias. This can lead to much higher electric fields (55 kV/cm) and surface charge (200 nC/cm2) than observed previously. When the plasma jet is turned off, the continuous surface charge decreased to half its value in 25 ms. These results have implications for surface treatment applications

Revealing Plasma-Surface Interaction at Atmospheric Pressure: Imaging of Electric Field and Temperature inside the Targeted Material

The plasma-surface interaction is studied for a low temperature helium plasma jet generated at atmospheric pressure using Mueller polarimetry on an electro-optic target. The influence of the AC kHz operating frequency is examined by simultaneously obtaining images of the induced electric field and temperature of the target. The technique offers high sensitivity in the determination of the temperature variation on the level of single degrees. Simultaneously, the evolution of the electric field in the target caused by plasma-driven charge accumulation can be measured with the threshold of the order of 105 V/m. Even though a specific electro-optic crystal is used to obtain the results, they are generally applicable to dielectric targets under exposure of a plasma jet when they are of 0.5 mm thickness, have a dielectric constant greater than 4 and are at floating potential. Other techniques to examine the induced electric field in a target do not exist to the best of our knowledge, making this technique unique and necessary. The influence of the AC kHz operating frequency is important because many plasma jet designs used throughout the world operate at different frequency which changes the time between the ionization waves and hence the leftover species densities and stability of the plasma. Results for our jet show a linear operating regime between 20 and 50 kHz where the ionization waves are stable and the temperature increases linearly by 25 K. The charge deposition and induced electric fields do not increase significantly but the surface area does increase due to an extended surface propagation. Additionally, temperature mapping using a 100 μm GaAs probe of the plasma plume area has revealed a mild heat exchange causing a heating of several degrees of the helium core while the surrounding air slightly cools. This peculiarity is also observed without plasma in the gas plume

Nonideal optical response of liquid crystal variable retarders and its impact on their performance as polarization modulators

Liquid crystal variable retarders (LCVRs) will be used for the first time in a space instrument, the Solar Orbiter mission of the European Space Agency, as polarization states analyzers (PSAs). These devices will determine the Stokes parameters of the light coming from the Sun by temporal polarization modulation, using the so-called modulation matrix O. This is a matrix constituted by the first rows of properly selected PSA Mueller matrices. Calibrating a space instrument, in particular, finding O, is a critical point because in a spacecraft there is no possibility of physical access. Due to the huge difficulty in calibrating the complete instruments in all possible scenarios, a more complete calibration of the individual components has been done in ground in order to make extrapolations to obtain O in-flight. Nevertheless, apart from the individual calibrations, the experimental errors and nonideal effects that inhibit the system to reach the designed and theoretical values must be known. In this work, description and study of these effects have been done, focusing on the nonideal effects of the LCVRs and the azimuthal misalignments between the optical components of the PSA during the mechanical assembly. The Mueller matrix of a representative LCVR has been measured and mathematically decomposed by logarithm decomposition, looking for values of circular birefringence and fast axis angle variations as a function of voltage. These effects, in the absence of other nonidealities, affect the polarimetric performance, reducing the polarimetric efficiencies in some cases until 11%. Nevertheless, in this case, they are negligible if compared to the other nonideality studied, which are the azimuthal misalignments between the PSA optical components. The study presented in this work is key to extrapolate the PSA O matrix if the expected instrumental set-point temperatures are not reached in flight and can be used for the design and implementation of other polarimetric instruments