Characterization and Comparative Study of Energy Efficient Mechanochemically Induced NASICON Sodium Solid Electrolyte Synthesis

In recent years, there is growing interest in solid-state electrolytes due to their many promising properties, making them key to the future of battery technology. This future depends among other things on easy processing technologies for the solid electrolyte. The sodium superionic conductor (NASICON) Na3Zr2Si2PO12 is a promising sodium solid electrolyte; however, reported methods of synthesis are time consuming. To this effect, attempt was made to develop a simple time efficient alternative processing route. Firstly, a comparative study between a new method and commonly reported methods was carried out to gain a clear insight into the mechanism of formation of sodium superionic conductors (NASICON). It was observed that through a careful selection of precursors, and the use of high-energy milling (HEM) the NASICON conversion process was enhanced and optimized, this reduces the processing time and required energy, opening up a new alternative route for synthesis. The obtained solid electrolyte was stable during Na cycling vs. Na-metal at 1 mA cm−1, and a room temperature conductivity of 1.8 mS cm−1 was attained

Synthesis and Characterization of a Multication Doped Mn Spinel, LiNi0.3_{0.3}Cu0.1_{0.1}Fe0.2_{0.2}Mn1.4_{1.4}O4_{4}, as 5 V Positive Electrode Material

The suitability of multication doping to stabilize the disordered Fd3̅m structure in a spinel is reported here. In this work, LiNi$_{0.3}$Cu$_{0.1}$Fe$_{0.2}$Mn$_{1.4}$O$_{4}$ was synthesized via a sol–gel route at a calcination temperature of 850 °C. LiNi$_{0.3}$Cu$_{0.1}$Fe$_{0.2}$Mn$_{1.4}$O$_{4}$ is evaluated as positive electrode material in a voltage range between 3.5 and 5.3 V (vs Li$^{+}$/Li) with an initial specific discharge capacity of 126 mAh g$^{-1}$ at a rate of C/2. This material shows good cycling stability with a capacity retention of 89% after 200 cycles and an excellent rate capability with the discharge capacity reaching 78 mAh g$^{-1}$ at a rate of 20C. In operando X-ray diffraction (XRD) measurements with a laboratory X-ray source between 3.5 and 5.3 V at a rate of C/10 reveal that the (de)lithiation occurs via a solid-solution mechanism where a local variation of lithium content is observed. A simplified estimation based on the in operando XRD analysis suggests that around 17–31 mAh g$^{-1}$ of discharge capacity in the first cycle is used for a reductive parasitic reaction, hindering a full lithiation of the positive electrode at the end of the first discharge

The Multisensor Array Based on Grown-On-Chip Zinc Oxide Nanorod Network for Selective Discrimination of Alcohol Vapors at Sub-ppm Range

We discuss the fabrication of gas-analytical multisensor arrays based on ZnO nanorods grown via a hydrothermal route directly on a multielectrode chip. The protocol to deposit the nanorods over the chip includes the primary formation of ZnO nano-clusters over the surface and secondly the oxide hydrothermal growth in a solution that facilitates the appearance of ZnO nanorods in the high aspect ratio which comprise a network. We have tested the proof-of-concept prototype of the ZnO nanorod network-based chip heated up to 400 °C versus three alcohol vapors, ethanol, isopropanol and butanol, at approx. 0.2–5 ppm concentrations when mixed with dry air. The results indicate that the developed chip is highly sensitive to these analytes with a detection limit down to the sub-ppm range. Due to the pristine differences in ZnO nanorod network density the chip yields a vector signal which enables the discrimination of various alcohols at a reasonable degree via processing by linear discriminant analysis even at a sub-ppm concentration range suitable for practical applications

A Multifunctional Nanostructured Hydrogel as a Platform for Deciphering Niche Interactions of Hematopoietic Stem and Progenitor Cells

For over half a century, hematopoietic stem cells (HSCs) have been used for transplantation therapy to treat severe hematologic diseases. Successful outcomes depend on collecting sufficient donor HSCs as well as ensuring efficient engraftment. These processes are influenced by dynamic interactions of HSCs with the bone marrow niche, which can be revealed by artificial niche models. Here, a multifunctional nanostructured hydrogel is presented as a 2D platform to investigate how the interdependencies of cytokine binding and nanopatterned adhesive ligands influence the behavior of human hematopoietic stem and progenitor cells (HSPCs). The results indicate that the degree of HSPC polarization and motility, observed when cultured on gels presenting the chemokine SDF-1α and a nanoscale-defined density of a cellular (IDSP) or extracellular matrix (LDV) α4β1 integrin binding motif, are differently influenced on hydrogels functionalized with the different ligand types. Further, SDF-1α promotes cell polarization but not motility. Strikingly, the degree of differentiation correlates negatively with the nanoparticle spacing, which determines ligand density, but only for the cellular-derived IDSP motif. This mechanism potentially offers a means of predictably regulating early HSC fate decisions. Consequently, the innovative multifunctional hydrogel holds promise for deciphering dynamic HSPC-niche interactions and refining transplantation therapy protocols