Initiation and stagnation of room temperature grain coarsening in cyclically strained gold films

Despite the large number of experiments demonstrating that grains in a metallic material can grow at room temperature due to applied mechanical load, the mechanisms and the driving forces responsible for mechanically induced grain coarsening are still not understood. Here we present a systematic study of room temperature grain coarsening induced by cyclic strain in thin polymer-supported gold films. By means of detailed electron backscatter diffraction analysis we were able to capture both the growth of individual grains and the evolution of the whole microstructure on the basis of statistical data over thousands of grains. The experimental data are reported for three film thicknesses with slightly different microstructures and three different amplitudes of cyclic mechanical loading. Although different kinds of grain size evolution with increasing cycle number are observed depending on film thickness and strain amplitude, a single model based on a thermodynamic driving force is shown to be capable to explain initiation and stagnation of grain coarsening in all cases. The main implication of the model is that the grains having lower individual yield stress are coarsening preferentially. Besides, it is demonstrated that the existence of local shear stresses imposed on a grain boundary is not a necessary requirement for room-temperature grain coarsening

Seven ways to make a hypertext project fail

Hypertext is an exciting concept, but designing and developing hypertext applications of practical scale is hard. To make a project feasible and successful 'hypertext engineers' must overcome the following problems: (1) developing realistic expectations in the face of hypertext hype; (2) assembling a multidisciplinary project team; (3) establishing and following design guidelines; (4) dealing with installed base constraints; (5) obtaining usable source files; (6) finding appropriate software technology and methods; and (7) overcoming legal uncertainties about intellectual property concerns

Research into defectiveness of welded joints of steam pipes operated over a long time

Проведено аналіз пошкоджуваності металу зварних з'єднань паропроводів із Cr–Mo–V теплостійких перлітних сталей, які тривалий час експлуатуються в умовах повзучості та малоциклової втоми. Наведені зварні з'єднання пошкоджуються одночасно порами повзучості та тріщинами втоми. Розглянуто фактори, які викликають пошкоджуваність, а також залежність пошкоджуваності від структури зварних з'єднань і умов експлуатації. Їх пошкоджуваність переважно має крихкий характер

Metastable phases and "metastable" phase diagrams

The work discusses specifics of phase transitions for metastable states of substances. The objects of condensed media physics are primarily equilibrium states of substances with metastable phases viewed as an exception, while the overwhelming majority of organic substances investigated in chemistry are metastable. It turns out that at normal pressure many of simple molecular compounds based on light elements (these include: most hydrocarbons; nitrogen oxides, hydrates, and carbides; carbon oxide (CO); alcohols, glycerin etc) are metastable substances too, i.e. they do not match the Gibbs' free energy minimum for a given chemical composition. At moderate temperatures and pressures, the phase transitions for given metastable phases throughout the entire experimentally accessible time range are reversible with the equilibrium thermodynamics laws obeyed. At sufficiently high pressures (1-10 GPa), most of molecular phases irreversibly transform to more energy efficient polymerized phases, both stable and metastable. These transformations are not consistent with the equality of the Gibbs' free energies between the phases before and after the transition, i.e. they are not phase transitions in "classical" meaning. The resulting polymeric phases at normal pressure can exist at temperatures above the melting one for the initial metastable molecular phase. Striking examples of such polymers are polyethylene and a polymerized modification of CO. Many of energy-intermediate polymeric phases can apparently be synthesized by the "classical" chemistry techniques at normal pressure.Comment: 5 pages, 4 figure