Zur Polymorphie von TbCl3

3 different modifications of TbCl3 were synthesized. TbCl3 (UCl3type). probably in a metastable state, crystallizes in space group P63/m with a = 737.63(2) pm, c = 405.71(2) pm and Z = 2. TbCl3(PuBr3-type) crystallizes in space group Cmcm with a = 384.71(6) pm, b = 1177.37(7) pm, c = 851.77(4) pm and Z = 4. h-TbCl3, the high temperature phase being stable above 790 K, crystallizes in space group P42/mnm with a = 642.51(4) pm, c = 1177.14(18) pm and Z = 4. © 1988, Walter de Gruyter. All rights reserved

Die Struktur des PrCl3 bei verschiedenen Temperaturen

Structural investigations on PrCl3 were performed from room temperature down to 40 K (powder) and from room temperature down to 83 K (single crystal). Special interest was focussed on the changes of the coordination geometry of the Pr3+-ion

Free Discontinuity Design: With an Application to the Economic Effects of Internet Shutdowns

Thresholds in treatment assignments can produce discontinuities in outcomes, revealing causal insights. In many contexts, like geographic settings, these thresholds are unknown and multivariate. We propose a non-parametric method to estimate the resulting discontinuities by segmenting the regression surface into smooth and discontinuous parts. This estimator uses a convex relaxation of the Mumford-Shah functional, for which we establish identification and convergence. Using our method, we estimate that an internet shutdown in India resulted in a reduction of economic activity by over 50%, greatly surpassing previous estimates and shedding new light on the true cost of such shutdowns for digital economies globally.Comment: 29 pages, 7 figures; authors listed alphabetically; code available at https://github.com/Davidvandijcke/fd

Return to Office and the Tenure Distribution

With the official end of the COVID-19 pandemic, debates about the return to office have taken center stage among companies and employees. Despite their ubiquity, the economic implications of return to office policies are not fully understood. Using 260 million resumes matched to company data, we analyze the causal effects of such policies on employees' tenure and seniority levels at three of the largest US tech companies: Microsoft, SpaceX, and Apple. Our estimation procedure is nonparametric and captures the full heterogeneity of tenure and seniority of employees in a distributional synthetic controls framework. We estimate a reduction in counterfactual tenure that increases for employees with longer tenure. Similarly, we document a leftward shift in the seniority distribution towards positions below the senior level. These shifts appear to be driven by employees leaving to larger firms that are direct competitors. Our results suggest that return to office policies can lead to an outflow of senior employees, posing a potential threat to the productivity, innovation, and competitiveness of the wider firm.Comment: 6 figures, 3 tables, 18 page