1,044 research outputs found

    Globalisation and Difference: Cosmopolitanism Before the Nation-State

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    In this paper, I have tried to reflect on what cosmopolitanism might mean in a very different era of globalisation than the present. Although cosmopolitanism, as an expansive and sociable vision, is often contrasted with the geographically limited perspective and claustrophobic affinities of nationalism, the term originates in a historical period before the rise of nationalism in Europe. I argue that the residents of the civilisations around the Indian Ocean in the medieval and early modern world were cosmopolitan even by the standards of the high modernist meaning of the term. Not only did a range of people transact and translate across different languages, but they also knew how to conduct themselves in different cultural settings with people of different religious beliefs, while respecting the disparate religious, social, and cultural practices of their neighbours

    Phase formation, thermal stability and magnetic moment of cobalt nitride thin films

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    Cobalt nitride (Co-N) thin films prepared using a reactive magnetron sputtering process by varying the relative nitrogen gas flow (\pn) are studied in this work. As \pn~increases, Co(N), \tcn, Co3_3N and CoN phases are formed. An incremental increase in \pn, after emergence of \tcn~phase at \pn=10\p, results in a continuous expansion in the lattice constant (aa) of \tcn. For \pn=30\p, aa maximizes and becomes comparable to its theoretical value. An expansion in aa of \tcn, results in an enhancement of magnetic moment, to the extent that it becomes even larger than pure Co. Though such higher (than pure metal) magnetic moment for Fe4_4N thin films have been theoretically predicted and evidenced experimentally, higher (than pure Co) magnetic moment are evidenced in this work and explained in terms of large-volume high-moment model for tetra metal nitrides.Comment: 4 pages, 4 figure

    Fe and N self-diffusion in non-magnetic Fe:N

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    Fe and N self-diffusion in non-magnetic FeN has been studied using neutron reflectivity. The isotope labelled multilayers, FeN/57Fe:N and Fe:N/Fe:15N were prepared using magnetron sputtering. It was remarkable to observe that N diffusion was slower compared to Fe while the atomic size of Fe is larger compared to N. An attempt has been made to understand the diffusion of Fe and N in non-magnetic Fe:N

    Formation of iron nitride thin films with Al and Ti additives

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    In this work we investigate the process of iron nitride (Fe-N) phase formation using 2 at.% Al or 2 at.% Ti as additives. The samples were prepared with a magnetron sputtering technique using different amount of nitrogen during the deposition process. The nitrogen partial pressure (\pn) was varied between 0-50% (rest Argon) and the targets of pure Fe, [Fe+Ti] and [Fe+Al] were sputtered. The addition of small amount of Ti or Al results in improved soft-magnetic properties when sputtered using \pn \leq 10\p. When \pn is increased to 50\p non-magnetic Fe-N phases are formed. We found that iron mononitride (FeN) phases (N at% \sim50) are formed with Al or Ti addition at \pn =50% whereas in absence of such addition \eFeN phases (N\pat\sim30) are formed. It was found that the overall nitrogen content can be increased significantly with Al or Ti additions. On the basis of obtained result we propose a mechanism describing formation of Fe-N phases Al and Ti additives.Comment: 9 Pages, 7 Figure

    Effect of dopants on thermal stability and self-diffusion in iron nitride thin films

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    We studied the effect of dopants (Al, Ti, Zr) on the thermal stability of iron nitride thin films prepared using a dc magnetron sputtering technique. Structure and magnetic characterization of deposited samples reveal that the thermal stability together with soft magnetic properties of iron nitride thin films get significantly improved with doping. To understand the observed results, detailed Fe and N self-diffusion measurements were performed. It was observed that N self-diffusion gets suppressed with Al doping whereas Ti or Zr doping results in somewhat faster N diffusion. On the other hand Fe self-diffusion seems to get suppressed with any dopant of which heat of nitride formation is significantly smaller than that of iron nitride. Importantly, it was observed that N self-diffusion plays only a trivial role, as compared to Fe self-diffusion, in affecting the thermal stability of iron nitride thin films. Based on the obtained results effect of dopants on self-diffusion process is discussed.Comment: 10 pages, 9 fig

    Potent intracellular knock down of hepatitis B virus X RNA by catalytic hammerhead ribozymes or DNA-Enzymes with antisense DNA-oligonucleotides or 10-23 DNA-Enzymes that powerfully augment in vitro sequence-specific cleavage activities

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    Novel antiviral approaches are needed to control Hepatitis B virus infection worldwide. X protein of this virus activates various promoters and is strongly associated with hepatocellular carcinoma. Although several groups, including ours, reported sequence-specific cleavage of X RNA by either ribozymes (Rzs) or DNA-enzymes (Dzs) earlier, but none of these studies reported 100% in vitro cleavage of the full-length X RNA. We reasoned that by melting the secondary structures near the Rz/Dz cleavage site with specific antisense DNA oligonucleotides (ODNs) or 10-23 Dz, it may be possible to achieve this objective. Hammerhead motif containing Rz-170 specific for X RNA was constructed by recombinant techniques and Dz-237 was synthesized using the 10-23 catalytic motif. When specific ODNs or 10-23 Dzs were included in the cleavage reaction with either Rz-170 or Dz-237, increased cleavage was observed in a dose-dependent manner which often resulted in almost complete in vitro cleavage of the target RNA. Rz-170 in combination with specific ODNs caused potent intracellular reduction of HBx RNA. Thus, the cleavage activity of catalytic nucleic acids (Rzs or Dzs) can be increased significantly by specific ODNs or Dzs and this treatment also results in potent intracellular target RNA reduction. These findings have important therapeutic implications
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